Process for the preparation of polyisocyanates addition products
containing carboxylate groups
    1.
    发明授权
    Process for the preparation of polyisocyanates addition products containing carboxylate groups 失效
    制备含羧酸酯基团的多异氰酸酯加成产物的方法

    公开(公告)号:US4172191A

    公开(公告)日:1979-10-23

    申请号:US916403

    申请日:1978-06-16

    摘要: The present disclosure is concerned with a process for the preparation of carboxylate containing polyurethane and the polymers so produced. Hydroxyl bearing components are reacted with tri- or tetra-carboxylic acid monoanhydrides so as to incorporate free carboxyl groups into the component, a proportion of the carboxyl groups are neutralized to ionic salts and hydroxyl component is then reacted with polyisocyanates and simultaneously or subsequently with chain extending agents. The polymer may be obtained as a dispersion in water and the chain lengthening agent may be water, formaldehyde or water soluble amines or hydrazines.

    摘要翻译: 本公开涉及制备含羧酸盐的聚氨酯和如此制备的聚合物的方法。 羟基担载组分与三羧酸或四羧酸单酸酐反应,以将游离羧基引入组分中,一部分羧基被中和成离子盐,然后羟基组分与多异氰酸酯反应,同时或随后与链 扩展代理。 聚合物可以作为水中的分散体获得,并且链延长剂可以是水,甲醛或水溶性胺或肼。

    Anionic cellulose nitrate derivatives and aqueous dispersions thereof
    2.
    发明授权
    Anionic cellulose nitrate derivatives and aqueous dispersions thereof 失效
    阴离子硝酸纤维素衍生物及其水分散体

    公开(公告)号:US07071326B2

    公开(公告)日:2006-07-04

    申请号:US11290193

    申请日:2005-11-30

    IPC分类号: C08B7/00 C09D101/20

    摘要: An anionic cellulose nitrate derivative is described, which has: (i) a degree of acid group substitution (DS (acid)) in the range of 0.01 to 0.2; and (ii) a nitrogen content of 10.7 wt. % to 12.3 wt. %, based on the weight of cellulose nitrate derivative. The anionic cellulose nitrate derivative is prepared by a process which includes esterifying cellulose nitrate feed material with at least one dicarboxylic acid anhydride (e.g., maleic anhydride). Aqueous dispersions according to the present invention include: (a) at least on anionic cellulose nitrate derivative according to the present invention; and (b) at least one base.

    摘要翻译: 描述了一种阴离子硝酸纤维素衍生物,其具有:(i)酸基置换度(DS(酸))在0.01至0.2的范围内; 和(ii)10.7重量%的氮含量。 %〜12.3重量% %,基于硝酸纤维素衍生物的重量。 通过包括用至少一种二羧酸酐(例如马来酸酐)将硝酸纤维素原料酯化的方法制备阴离子硝酸纤维素衍生物。 根据本发明的水分散体包括:(a)至少一种根据本发明的阴离子硝酸纤维素衍生物; 和(b)至少一个碱基。

    Process for the preparation of cellulose derivatives containing amino groups
    3.
    发明申请
    Process for the preparation of cellulose derivatives containing amino groups 审中-公开
    制备含氨基的纤维素衍生物的方法

    公开(公告)号:US20060041117A1

    公开(公告)日:2006-02-23

    申请号:US11184093

    申请日:2005-07-19

    IPC分类号: C08B11/00

    摘要: A process is described for the preparation of cellulose derivatives containing amino groups that involves reacting, in the presents of water as a reaction medium, alkali cellulose or alkali cellulose derivatives with reagents represented by the following formula, X—(CH2)n—NR1R2 in which: X is selected from the group consisting of chlorine, bromine, iodine and a sulfonic acid radical R′SO3, in which R′ is an aromatic radical or an aliphatic radical; n is at least 2; and R1 and R2 independently of each other are selected from the group consisting of aliphatic substituents, branched alkyl substituents, cyclic alkyl substituents, aryl substituents, aryl substituents substituted by heteroatoms, H, and R1 and R2 together form a ring with the nitrogen. In the process, the mole ratio of cellulose to water, of said reaction medium, is 1:5 to 1:40 mol water per mol of anhydroglucose unit (AGU). Amino functional cellulose derivatives prepared in accordance with the method of the present invention are useful in cosmetic formulations and aqueous paper treatment compositions.

    摘要翻译: 描述了制备含有氨基的纤维素衍生物的方法,该方法包括在作为反应介质的水的存在下,将碱纤维素或碱性纤维素衍生物与下式表示的试剂反应:<?在线配方说明= “In-line Formulas”end =“lead”?> X-(CH 2)n - NR 1 R 2 - 其中:X选自氯,溴,碘和磺酸基R'SO 2,其中:X选自氯,溴,碘,磺酸根R' 其中R'是芳族基团或脂族基团; n至少为2; R 1和R 2彼此独立地选自脂族取代基,支链烷基取代基,环烷基取代基,芳基取代基,被杂原子取代的芳基取代基 ,H和R 1和R 2一起与氮一起形成环。 在该过程中,所述反应介质的纤维素与水的摩尔比为每摩尔脱水葡萄糖单元(AGU)为1:5至1:40摩尔水。 根据本发明的方法制备的氨基官能纤维素衍生物可用于化妆品制剂和水性纸处理组合物中。

    Process for the production of combinations of organic polyisocyanates
and at least partly blocked polyamines, the combinations obtainable by
this process and their use for the production of lacquers, coating or
sealing compositions
    8.
    发明授权
    Process for the production of combinations of organic polyisocyanates and at least partly blocked polyamines, the combinations obtainable by this process and their use for the production of lacquers, coating or sealing compositions 失效
    用于生产有机多异氰酸酯和至少部分封闭的多胺的组合的方法,可通过该方法获得的组合及其用于生产漆,涂料或密封组合物的用途

    公开(公告)号:US4481345A

    公开(公告)日:1984-11-06

    申请号:US583918

    申请日:1984-02-27

    CPC分类号: C08G18/3256 C08G18/10

    摘要: Process for the production of water-hardenable compositions of organic polyisocyanates and polyamines containing at least partly blocked amino groups present as ketimines, the combinations essentially representing mixtures and optionally reaction products containing urea groups by mixing the organic polyisocyanates with the polyamines in such quantities that the equivalent ratio of isocyanate groups to blocked and free amino groups is between about 0.9:1 and 4:1 and reacting any free amino groups present with some of the isocyanate groups in the polyisocyanate to form ureas, characterized in that the polyamines containing at least partly blocked amino groups used are mixtures comprising(a) from about 50 to 95 amine equivalent percent of organic compounds which are free from primary and secondary amino groups and which contain at least two ketimine groups corresponding to the following formula ##STR1## in which R.sup.1 represents an alkyl or cycloalkyl radical and R.sup.2 represents hydrogen or an alkyl or cycloalkyl radical or in which R.sup.1 and R.sup.2 form a cycloaliphatic hydrocarbon radical together with the two carbon atoms of the ketimine group and(b) from about 5 to 40 amine equivalent percent of organic compounds which are free from primary and secondary amino groups and which contain at least two ketimine groups of which one corresponds to the formula ##STR2## in which R.sup.1 and R.sup.2 are as defined above, the other ketimine group(s) present correspond(s) to the formula shown in (a).

    摘要翻译: 用于生产有机多异氰酸酯和含有至少部分封闭的胺基的多胺的水可硬化组合物作为酮亚胺存在的方法,所述组合基本上代表混合物和任选的含有尿素基团的反应产物,通过将有机多异氰酸酯与多胺混合, 异氰酸酯基与封端和游离氨基的当量比为约0.9:1至4:1,并使与多异氰酸酯中存在的一些异氰酸酯基团存在的任何游离氨基反应形成脲,其特征在于,含有至少部分 使用的封闭氨基是包含(a)约50至95胺当量百分比的不含伯和仲氨基并且含有至少两个对应于下式的酮亚胺基的有机化合物的混合物:其中R 1表示 烷基或环烷基,R 2表示氢或a n烷基或环烷基,或其中R1和R2与酮亚胺基团的两个碳原子一起形成脂环族烃基,和(b)约5至40胺当量百分比的不含伯和仲氨基的有机化合物 并且其包含至少两个酮亚胺基,其中一个对应于式(Ia)其中R 1和R 2如上所定义的式“IMAGE”,其它酮亚胺基与(a)所示的式表示。

    Polyurethanes which are dispersible or soluble in water and a process
for their preparation
    9.
    发明授权
    Polyurethanes which are dispersible or soluble in water and a process for their preparation 失效
    可分散或溶于水的聚氨酯及其制备方法

    公开(公告)号:US4303774A

    公开(公告)日:1981-12-01

    申请号:US30600

    申请日:1979-04-16

    摘要: The present invention relates to water soluble or water dispersible polyurethane elastomers which have a substantially linear molecular structure and which contain both ethylene oxide units incorporated in polyether chains and sulphonate groups, characterized in that they contain from about 0.5 to 20% by weight of ethylene oxide units of the formula --CH.sub.2 --CH.sub.2 --O-- arranged within polyether chains and from about 0.1 to 25 milliequivalents, per 100 g of solid, of sulphonate groups of the formula --SO.sub.3.sup..crclbar. in the form of structural units of the formula--O--X--Rarranged in end positions and/or side positions, whereinX represents a polyalkylene oxide chain having from 5 to 90 chain members, at least about 40% of which chain members constitute ethylene oxide units andR represents a monovalent hydrocarbon group having from 3 to 18 carbon atoms containing at least one sulphonate group --SO.sub.3.sup..crclbar. andto a process for their production.

    摘要翻译: 本发明涉及水溶性或水分散性聚氨酯弹性体,其具有基本上线性的分子结构,并且其包含掺入聚醚链和磺酸盐基团的环氧乙烷单元,其特征在于它们含有约0.5-20重量%的环氧乙烷 式-CH 2 -CH 2 -O-的单元,其配置在聚醚链内,约0.1至25毫当量,每100g固体式-SO 3( - )磺酸盐基团,其结构单元为式 - OXR排列在末端位置和/或侧位,其中X表示具有5-90个链成员的聚环氧烷链,至少约40%的链成员构成环氧乙烷单元,R表示一价烃基,其具有3至 含有至少一个磺酸酯基-SO 3( - )的18个碳原子及其制备方法。