公开(公告)号：US5268091A

公开(公告)日：1993-12-07

申请号：US700120

申请日：1991-05-10

申请人： Jean P. Boitiaux ,  Philippe Courty ,  Patrick Sarrazin

发明人： Jean P. Boitiaux ,  Philippe Courty ,  Patrick Sarrazin

IPC分类号： C10G25/00 ,  C10G17/02

CPC分类号： C10G25/00

摘要： A method for removing arsenic and/or phosphorus from a petroleum charge with a retaining material comprising:(a) from 60 to 97% of a carrier containing, by weight, from 1.5 to 60% of oxide of at least one metal A selected from the group consisting of Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Cu and Zn, dissolved in alumina in the form of aluminate, and from 40 to 98.5% of at least one alumina,(b) from 3 to 40% of nickel oxide, with which the carrier is impregnated by exchange or depositing, and(c) possibly from 0 to 1% of platinum and/or palladium oxide with which the carrier is impregnated.

摘要翻译： 一种从具有保留材料的石油装料中除去砷和/或磷的方法，包括：（a）60至97％的载体，其含有至少一种选自以下的金属的氧化物的1.5至60重量％ 以铝酸盐形式溶解在氧化铝中的Mg，Ca，Sr，Ba，Mn，Fe，Co，Ni，Cu和Zn组成的组和40至98.5％的至少一种氧化铝，（b）3 至40％的氧化镍，载体通过其交换或沉积而浸渍，和（c）可能含有0至1％的载体浸渍的铂和/或氧化钯。

公开(公告)号：US5245106A

公开(公告)日：1993-09-14

申请号：US785111

申请日：1991-10-30

申请人： Charles Cameron ,  Philippe Courty ,  Jean-Paul Boitiaux ,  Philipe Varin ,  Gerard Leger

发明人： Charles Cameron ,  Philippe Courty ,  Jean-Paul Boitiaux ,  Philipe Varin ,  Gerard Leger

IPC分类号： B01D53/14 ,  B01D53/46 ,  B01D53/64 ,  B01J20/02 ,  B01J20/30 ,  C01G13/00 ,  C01G28/00 ,  C02F1/28

CPC分类号： C02F1/285 ,  B01D53/64 ,  B01J20/0237 ,  B01J20/0285 ,  B01J20/3078 ,  C02F1/288

摘要： The invention relates to a method of eliminating mercury or arsenic from a fluid in the presence of a solid mass for the recovery of mercury and/or arsenic. The said mass contains copper and sulphur at least partly in the form of copper sulphide and results (a) from the incorporation of a copper compound other than a sulphide into a solid mineral support, (b) possible calcination of the product obtained in stage (a), and from bringing the product obtained previously into contact with elementary sulphur and (d) a heat treatment.

摘要翻译： 本发明涉及在用于回收汞和/或砷的固体物质存在下从流体中除去汞或砷的方法。 所述物质含有至少部分为硫化铜形式的铜和硫，并且（a）从固体矿物载体中引入除硫化物以外的铜化合物，（b）可能煅烧阶段 a），并将先前获得的产品与基本硫接触，（d）进行热处理。

公开(公告)号：US4780481A

公开(公告)日：1988-10-25

申请号：US26493

申请日：1987-03-16

申请人： Philippe Courty ,  Patrick Chaumette ,  Daniel Durand ,  Catherine Verdon

发明人： Philippe Courty ,  Patrick Chaumette ,  Daniel Durand ,  Catherine Verdon

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/80 ,  B01J23/89 ,  C07C27/00 ,  C07C29/153 ,  C07C29/154 ,  C07C29/156 ,  C07C29/157 ,  C07C29/158 ,  C07C29/16 ,  C07C31/02 ,  C07C67/00 ,  C07C27/06

CPC分类号： C07C29/156 ,  Y02P20/52

摘要： A process for manufacturing a mixture of saturated primary alcohols by reacting carbon oxides with hydrogen in the presence of a catalyst formed essentially of the following elements: copper, cobalt, zinc, at least one metal A selected from the group consisting of alkali and alkaline earth metals and optionally zirconium and/or at least one metal M selected from the group formed of scandium, yttrium and rare earth metals and/or at least one metal N selected from group VIII noble metals, the proportion by weight of each metal element being: copper: 15-55%, colbalt: 5-25%, zinc: 15-70%, metal A: 0.01-5%, zinconium: 0-55%, metal M: 0-20%, metal N: 0-1%, the total amount by weight of zinc and zirconium in percent by weight of all the metals being from 15 to 70% and the atomic ratios between these metals being: Cu/Co: 0.2:1 to 5:1 and Zn/(Zn+Zr): 0.05:1 to 1:1 and (Zn+Zr)/Co: 0.5:1 to 8:1.The catalyst may be prepared by complexing or by coprecipitating catalytic elements.

摘要翻译： 一种在主要由以下元素形成的催化剂存在下使碳氧化物与氢气反应来制造饱和伯醇的混合物的方法：铜，钴，锌，至少一种选自碱金属和碱土金属的金属 金属和任选的锆和/或至少一种选自钪，钇和稀土金属的金属和/或至少一种选自VIII族贵金属的金属，金属元素的重量比例为： 铜：15-55％，钴：5-25％，锌：15-70％，金属A：0.01-5％，锌银：0-55％，金属M：0-20％，金属N：0-1 ％，所有金属的重量百分比为15〜70％的锌和锆的总量，这些金属的原子比为Cu / Co:0.2:1〜5:1，Zn /（Zn + Zr）：0.05:1〜1:1，（Zn + Zr）/ Co:0.5:1〜8:1。 催化剂可以通过络合或通过共沉淀催化元素来制备。

公开(公告)号：US4675343A

公开(公告)日：1987-06-23

申请号：US863283

申请日：1986-05-15

申请人： Philippe Courty ,  Daniel Durand ,  Alain Forestiere ,  Pierre Grandvallet

发明人： Philippe Courty ,  Daniel Durand ,  Alain Forestiere ,  Pierre Grandvallet

IPC分类号： C07C29/15 ,  B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/156 ,  C07C31/02 ,  C07C67/00 ,  C07C27/06

CPC分类号： C07C29/156 ,  Y02P20/52

摘要： The present invention concerns a process of use of a copper and cobalt-containing catalyst for synthesizing saturated primary aliphatic alcohols. This process comprises a first step consisting in at least one catalyst prereduction by means of a gas mixture containing a reducing compound, a second step wherein the prereduced catalyst is contacted with a mixture of hydrogen and carbon oxides (CO, CO.sub.2) for at least 10 hours, so as to produce a mixture of alcohols; a third step wherein the catalyst obtained in the second step is subjected to a treatment with a gas mixture containing a single reducing gas, during about 1 to 400 hours and a fourth step of synthesizing saturated primary aliphatic alcohols from a mixture containing hydrogen and carbon oxides.Optionally the process also comprises an additional step consisting of subjecting the catalyst, whose activity and/or selectivity has been partially lost, to a new treatment according to the procedure defined for the third step.The process according to the invention is particularly applicable to catalysts containing copper, cobalt and optionally aluminum and/or zinc and/or sodium.

摘要翻译： 本发明涉及使用含铜和钴的催化剂合成饱和伯脂肪醇的方法。 该方法包括通过含有还原化合物的气体混合物进行至少一种催化剂预还原的第一步骤，其中将预还原的催化剂与氢和碳氧化物（CO，CO 2）的混合物接触至少10 小时，以产生醇的混合物; 第三步骤，其中将第二步中得到的催化剂在含有单一还原气体的气体混合物中进行约1-4小时的处理，以及从含有氢和碳氧化物的混合物中合成饱和伯脂肪醇的第四步骤 。 任选地，该方法还包括另外的步骤，该方法包括将其活性和/或选择性已被部分丧失的催化剂按照根据第三步所定义的方法进行新的处理。 根据本发明的方法特别适用于含有铜，钴和任选的铝和/或锌和/或钠的催化剂。

公开(公告)号：US4141861A

公开(公告)日：1979-02-27

申请号：US678306

申请日：1976-04-19

申请人： Philippe Courty ,  Hubert Ajot ,  Bernard Delmon

发明人： Philippe Courty ,  Hubert Ajot ,  Bernard Delmon

IPC分类号： B01J23/88 ,  B01J37/03 ,  C01G49/00 ,  G02B5/22 ,  B01J23/10

CPC分类号： B01J23/8871 ,  B01J23/8877 ,  B01J23/8878 ,  B01J37/036 ,  C01G49/009 ,  G02B5/22 ,  C01P2002/02 ,  C01P2002/32 ,  C01P2002/82 ,  C01P2006/12 ,  C01P2006/60

摘要： An amorphous solid gel containing molybdenum and iron contains (a) ions of a ferric salt and ions from at least one salt containing, as simple cations, a metal M, in an atomic ratio M/ (Fe+M) from 0 to 0.5:1 (b) ions from a molybdic compound and ions from at least one salt containing, as oxygenated ions, a metal N, in an atomic ration N/ (Mo+N) from 0 to 0.5:1; and (c) water, wherein M is Co, Ni, Mn, Cr, Sc, Y or a rare earth metal, N is Cr, W, Mn, or V and (Mo+N) / (Fe+M) is 0.4:1 to 5:1.

摘要翻译： 含有钼和铁的无定形固体凝胶含有（a）铁盐离子和至少一种盐的离子，所述盐含有作为简单阳离子的金属M，原子比为M /（Fe + M）为0至0.5： 1（b）来自钼化合物的离子和来自至少一种盐的离子，所述盐以0至0.5:1的原子比N /（Mo + N）作为氧化离子含有金属N; 和（c）水，其中M为Co，Ni，Mn，Cr，Sc，Y或稀土金属，N为Cr，W，Mn或V，（Mo + N）/（Fe + M）为0.4 ：1〜5：1。

公开(公告)号：US4134858A

公开(公告)日：1979-01-16

申请号：US863002

申请日：1977-12-21

申请人： Philippe Courty

发明人： Philippe Courty

IPC分类号： B01J23/86 ,  B01J37/00 ,  C07C5/32 ,  B01J29/06 ,  B01J29/00 ,  B01J29/10

CPC分类号： B01J23/862 ,  B01J37/0009 ,  C07C5/322

摘要： Catalyst for dehydrogenating hydrocarbons, as manufactured by the process comprising:Admixing one or more iron compounds, chromium compounds and potassium compounds, in a definite range of relative proportions,Moistening and malaxing the resulting mixture while adding thereto a clayish material in such an amount as to obtain by reaction with the potassium compound, a proportion of 3 to 55% b.w. of potassium alumino-silicate in the final catalyst,Shaping the homogeneized resulting paste, drying and roasting it at about 870 - 1050.degree. C, the potassium compound being used in an amount greater than that liable to combine with the clayish material.

摘要翻译： 用于使烃脱氢的催化剂，由如下方法制造，包括：

公开(公告)号：US06977273B2

公开(公告)日：2005-12-20

申请号：US10075235

申请日：2002-02-15

申请人： Magalie Roy-Auberger ,  Philippe Courty ,  Renaud Revel ,  Roberto Zennaro

发明人： Magalie Roy-Auberger ,  Philippe Courty ,  Renaud Revel ,  Roberto Zennaro

IPC分类号： B01J21/12 ,  B01J23/40 ,  B01J23/74 ,  B01J23/75 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  C10G2/00 ,  C07C27/00 ,  B01J21/04 ,  B01J21/08 ,  B01J23/00

CPC分类号： C10G2/331 ,  B01J21/12 ,  B01J23/40 ,  B01J23/74 ,  B01J23/75 ,  B01J35/1019 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/08 ,  C10G2/332 ,  C10G2/333

摘要： A process is described for synthesizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours so that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.

摘要翻译： 描述了一种方法，用于在包含一氧化碳和氢气的混合物的存在下，在包含至少一种负载在二氧化硅 - 氧化铝上的第Ⅷ族金属的存在下合成烃，所述Ⅷ族金属通过共沉淀和在约500℃的温度下煅烧 约1200℃至少6小时，使得所述二氧化硅 - 氧化铝的比表面积小于260平方米/克。 所述催化剂用于固定床或悬浮在三相反应器的液相中。

公开(公告)号：US06582796B1

公开(公告)日：2003-06-24

申请号：US09621345

申请日：2000-07-21

申请人： Jean Pierre Joulin ,  Fabienne Pourchet ,  Philippe Courty ,  Jean-Baptiste Dementhon

发明人： Jean Pierre Joulin ,  Fabienne Pourchet ,  Philippe Courty ,  Jean-Baptiste Dementhon

IPC分类号： B32B312

CPC分类号： F01N3/0222 ,  C04B38/0006 ,  C04B2111/00793 ,  F01N2330/06 ,  Y02T10/20 ,  Y10T428/24149 ,  Y10T428/24628 ,  Y10T428/24744 ,  Y10T428/252 ,  Y10T428/26 ,  C04B35/565 ,  C04B35/6303 ,  C04B38/0054

摘要： A monolithic honeycomb-type structure useful in particular as a particle filter for exhaust gases from diesel engines has a number of passages that empty into the end faces of said monolith, but are alternately open and sealed. The monolith consists of a porous refractory material that comprises: 70 to 97% by mass of &agr; and/or &bgr; crystallographic-type silicon carbide that has at least one particle size and preferably at least two particle sizes, and 3 to 30% by mass of at least one bonding ceramic phase in the form of a micronic powder or particles that are obtained by atomization, comprising at least one simple oxide, for example, B2O3, Al2O3, SiO2, MgO, K2O, Li2O, Na2O, CaO, BaO, TiO, ZrO2 and Fe2O3 and/or at least one mixed oxide, for example, the alkaline aluminosilicates (of Li, Na, or K) or alkaline-earth aluminosilicates (of Mg, Ca, Sr or Ba), clays, bentonite, feldspars or other natural silico-aluminous materials. The production of the monolith comprises a calcination stage under an oxygen-containing atmosphere at a temperature up to 1650° C., but less than 1550° C.

摘要翻译： 特别是作为来自柴油发动机的废气的颗粒过滤器的整体式蜂窝型结构具有多个通向所述整体料的端面的通道，而是交替地开放和密封。 整料由多孔耐火材料组成，其包括：具有至少一个粒度，优选至少两个粒度的70和97质量％的α和/或β晶型碳化硅，和3至30质量％ 至少一种微晶粉末形式的结合陶瓷相或通过雾化获得的颗粒，其包含至少一种简单的氧化物，例如B2O3，Al2O3，SiO2，MgO，K2O，Li2O，Na2O，CaO，BaO， TiO，ZrO 2和Fe 2 O 3和/或至少一种混合氧化物，例如碱性硅铝酸盐（Li，Na或K）或碱土金属硅酸盐（Mg，Ca，Sr或Ba），粘土，膨润土，长石 或其他天然硅铝质材料。 整料的生产包括在含氧气氛下在高达1650℃但小于1550℃的温度下的煅烧阶段

公开(公告)号：US06132597A

公开(公告)日：2000-10-17

申请号：US95008

申请日：1998-06-10

申请人： Virginie Harle ,  Slavik Kazstelan ,  Frederic Morel ,  Stephane Kressmann ,  Philippe Courty

发明人： Virginie Harle ,  Slavik Kazstelan ,  Frederic Morel ,  Stephane Kressmann ,  Philippe Courty

IPC分类号： B01J23/88 ,  B01J21/04 ,  B01J23/28 ,  B01J23/85 ,  B01J23/883 ,  B01J35/10 ,  B01J37/00 ,  C10G45/04 ,  C10G45/08 ,  C10G49/04 ,  C10G45/06 ,  C10G47/02

CPC分类号： B01J23/883 ,  B01J21/04 ,  B01J23/28 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C10G2300/107

摘要： The present invention relates to the use of a catalyst comprising an extruded essentially alumina-based support, constituted by a plurality of juxtaposed agglomerates and partially in the form of packs of flakes and partially in the form of needles, and optionally comprising at least one catalytic metal or a compound of a catalytic metal from group VIB, and/or optionally at least one catalytic metal or compound of a catalytic metal from group VIII, in an ebullating bed process and for hydrorefining and hydroconverting hydrocarbon feeds.

摘要翻译： 本发明涉及催化剂的用途，该催化剂包括挤出的基本上为氧化铝的载体，其由多个并置的附聚物构成，并且部分为片状包装形式，部分为针状，并任选地包含至少一种催化剂 金属或来自组VIB的催化金属的化合物，和/或任选的至少一种催化金属或来自VIII族的催化金属的化合物，在沸腾床方法中，以及用于加氢精制和加氢转化烃进料。

公开(公告)号：US5578196A

公开(公告)日：1996-11-26

申请号：US365927

申请日：1994-12-29

申请人： Christine Travers ,  Philippe Courty ,  Patrick Sarrazin

发明人： Christine Travers ,  Philippe Courty ,  Patrick Sarrazin

IPC分类号： B01J21/04 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/755 ,  B01J23/78 ,  B01J27/128 ,  B01J27/13 ,  C07B61/00 ,  C07C5/13 ,  C07C9/00 ,  C10G35/04 ,  C10G45/60 ,  C10G65/08 ,  C10G69/02 ,  C10G69/08 ,  C10G45/00

CPC分类号： C10G69/08 ,  B01J23/40 ,  B01J23/78 ,  C10G65/08 ,  Y02P20/52

摘要： The invention concerns a process for reducing the benzene content of petrol fractions, in which hydrogenation is carried out on a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., followed by isomerisation of the effluent from the hydrogenation step, mixing said feed and/or said effluent with a C.sub.5 -C.sub.6 cut; said process being characterised in that an isomerisation catalyst is used which contains chlorine and at least one group VIII metal deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina.

摘要翻译： 本发明涉及一种降低汽油馏分苯含量的方法，其中对具有以下重量组成的进料进行氢化：40％至80％的链烷烃，0.5％至7％的环状烃和6％ 45％的芳族化合物，并且最高蒸馏温度在70℃至90℃之间，随后将来自氢化步骤的流出物异构化，将所述进料和/或所述流出物与C5-C6馏分混合; 所述方法的特征在于使用异构化催化剂，其含有氯和沉积在由特定比例的氧化铝和γ氧化铝的混合物组成的载体上的至少一种第Ⅷ族金属。