Multi-Stage Polymer Composition and Films Made Therefrom
    31.
    发明申请
    Multi-Stage Polymer Composition and Films Made Therefrom 审中-公开
    多级聚合物组合物和薄膜

    公开(公告)号:US20150183944A1

    公开(公告)日:2015-07-02

    申请号:US14418521

    申请日:2013-08-05

    Abstract: A multi-stage polymer composition comprising a crosslinked core having a Tg of from −85 to −10° C.; an intermediate region which comprises one or more intermediate layers, wherein each of the intermediate layers comprises from 88.5 to 99.9 weight percent of units derived from a one or more monomers selected from the group consisting of alkyl(meth)acrylate monomers, from 0 to 5 weight percent of units derived from a cross-linking monomer, a graft-linking monomer, or a combination of two or more thereof, optionally from 0 to 2 weight percent units derived from one or more chain transfer agents; wherein there is a compositional gradient between the intermediate layers such that the Tg transitions from −30° C. to 70° C. over the width of the intermediate region, and an outermost layer which has a Tg of from 40° C. to 110° C. is provided.

    Abstract translation: 一种多级聚合物组合物,其包含Tg为-85至-10℃的交联核心; 中间区域,其包含一个或多个中间层,其中每个中间层包含88.5-99.9重量%的衍生自一种或多种选自(甲基)丙烯酸烷基酯单体,0-5个 衍生自交联单体的单元的重量百分比,接枝单体或其两种或多种的组合,任选地0至2重量%的衍生自一种或多种链转移剂的单元; 其中在中间层之间存在组成梯度,使得Tg在中间区域的宽度上从-30℃至70℃变化,并且Tg为40℃至110℃的最外层 °C。

    Polymerizing silicone and acrylic monomers

    公开(公告)号:US12043685B2

    公开(公告)日:2024-07-23

    申请号:US17259635

    申请日:2019-07-26

    CPC classification number: C08F290/148 C08K5/41

    Abstract: A method of making a collection of polymer particles comprising



    (A) performing free radical polymerization (A) on an emulsion (E1) that comprises a collection of droplets dispersed in an aqueous medium, wherein the droplets comprise

    (i) one or more Si-containing monomers;
    (ii) one or more monovinyl acrylic monomers; and
    (iii) one or more graftlinkers that have no silicon atoms;
    to form a dispersion (D1) of core polymer particles in the aqueous medium;


    (B) in the presence of the dispersion (D1) of core polymer particles, performing aqueous emulsion polymerization (B) on one or more acrylic monomers.

    Modified styrene-acrylonitrile
    33.
    发明授权

    公开(公告)号:US11981804B2

    公开(公告)日:2024-05-14

    申请号:US16980591

    申请日:2019-03-04

    Abstract: Provided is a polymeric composition comprising a continuous phase that comprises a matrix polymer and a dispersed phase comprising polymer particles, wherein the polymer particles comprise:



    (a) 30% to 85% by weight, based on the dry weight of the polymer particles, a core polymer having Tg of −35° C. or lower;
    (b) 15% to 50% by weight, based on the dry weight of the polymer particles, an intermediate polymer having Tg that is 20° C. or lower and that is higher than the Tg of the core polymer by 10° C. or more; and
    (c) 5% to 30% by weight, based on the dry weight of the polymer particles, a shell polymer having Tg of 50° C. or higher;

    wherein the shell polymer comprises polymerized units of all vinyl aromatic monomers in an amount of 1% or less, by weight based on the weight of the shell polymer. Also provided is a method of making the composition.

    PVC COMPOSITION, POLYMER COMPOSITE ARTICLE FORMED THEREWITH, AND METHOD OF PREPARING SAME

    公开(公告)号:US20220275188A1

    公开(公告)日:2022-09-01

    申请号:US17630282

    申请日:2020-08-06

    Abstract: A polyvinyl chloride (PVC) composition and a method for preparing a polymer composite article. The composition comprises (A) a mineral filler in an amount of from 7.5 to 75 wt. %. The composition also comprises (B) a polyvinyl chloride polymer in an amount of from 20 to 92 wt. %. Further, the composition comprises (C) a polydiorganosiloxane in an amount of from greater than 0 to 5 wt. %; the (C) polydiorganosiloxane being a compound of formula (I): where each R is an independently selected monovalent hydrocarbon group of 1 to 18 carbon atoms that is free of aliphatic unsaturation, and subscript x has a value sufficient to give the (C) polydiorganosiloxane a viscosity of greater than 350 mPa·s to 100,000 mPa·s measured at 25° C. at 0.1 RPM to 50 RPM on a Brookfield DV-III cone & plate viscometer with #CP-52 spindle. The ranges for components (A)-(C) are based on the total weight of components (A), (B) and (C) in the composition.

    MODIFIED STYRENE-ACRYLONITRILE
    36.
    发明申请

    公开(公告)号:US20210246293A1

    公开(公告)日:2021-08-12

    申请号:US16980591

    申请日:2019-03-04

    Abstract: Provided is a polymeric composition comprising a continuous phase that comprises a matrix polymer and a dispersed phase comprising polymer particles, wherein the polymer particles comprise: (a) 30% to 85% by weight, based on the dry weight of the polymer particles, a core polymer having Tg of −35° C. or lower; (b) 15% to 50% by weight, based on the dry weight of the polymer particles, an intermediate polymer having Tg that is 20° C. or lower and that is higher than the Tg of the core polymer by 10° C. or more; and (c) 5% to 30% by weight, based on the dry weight of the polymer particles, a shell polymer having Tg of 50° C. or higher; wherein the shell polymer comprises polymerized units of all vinyl aromatic monomers in an amount of 1% or less, by weight based on the weight of the shell polymer. Also provided is a method of making the composition.

    Multi-stage polymer composition and films made therefrom

    公开(公告)号:US10920060B2

    公开(公告)日:2021-02-16

    申请号:US16096743

    申请日:2017-05-18

    Inventor: Hailan Guo

    Abstract: Provided are multi-stage polymer compositions comprising (a) cross-linked core comprising polymerized units derived from (i) alkyl(meth)acrylate monomers, and (ii) one or more cross-linking monomers, graft-linking monomers, and combinations thereof, (b) a first intermediate layer comprising polymerized units derived from (i) one or more alkyl(meth)acrylate monomers, and (ii) cross-linking monomers, graft-linking monomers, and combinations thereof, (c) a second intermediate layer comprising polymerized units derived from (i) one or more alkyl(meth)acrylate monomers, styrenic monomers, and combinations thereof, and (ii) one or more chain transfer agents, and (d) a shell comprising polymerized units derived from (i) alkyl(meth)acrylate monomers, styrenic monomers, and combinations thereof, (ii) one or more monomers selected from the group consisting of acid functionalized monomers, hydroxyl-functionalized monomers, and combinations thereof, and (iii) optionally, of one or more chain transfer agents.

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