公开(公告)号：US20090137757A1

公开(公告)日：2009-05-28

申请号：US12153003

申请日：2008-05-12

申请人： Junichi Imuta ,  Norio Kashiwa ,  Seiji Ota ,  Satoru Moriya ,  Tadahito Nobori ,  Kazumi Mizutani

发明人： Junichi Imuta ,  Norio Kashiwa ,  Seiji Ota ,  Satoru Moriya ,  Tadahito Nobori ,  Kazumi Mizutani

IPC分类号： C08F4/44

CPC分类号： C08F297/02 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08J5/18 ,  C08J2351/06 ,  C08J2371/02 ,  C08J2387/00 ,  C08L53/00 ,  C08L2666/02 ,  C09J153/00 ,  C08F4/65927 ,  C08F222/06 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/09 ,  C08F216/00

摘要： A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

摘要翻译： 含有金属或极性树脂的粘合性优异的极性基团的烯烃共聚物，与其相容性优异的共聚物的制备方法，含有共聚物的热塑性树脂组合物及其用途。 含有极性基团的烯烃共聚物包含衍生自2〜20个碳原子的α-烯烃的结构单元，以及衍生自具有极性基团的直链，支链或环状极性基团单体的结构单元 例如羟基或环氧基和/或衍生自大分子单体的结构单元，其末端具有通过阴离子聚合，开环聚合或缩聚获得的聚合物链段。 含极性基团的烯烃共聚物可以通过在金属茂催化剂的存在下将α-烯烃与含极性基团的单体和/或大分子单体进行聚合来制备。 含有极性基团的烯烃共聚物和含有共聚物的热塑性树脂组合物用于薄膜，片材，改性剂，建筑/土木工程材料，汽车外饰件，电气/电子部件，涂料基料，相容剂等。

公开(公告)号：US20080318767A1

公开(公告)日：2008-12-25

申请号：US11631286

申请日：2005-06-28

申请人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Kazumi Mizutani ,  Isao Hara ,  Takaomi Hayashi ,  Tadahito Nobori ,  Yoshihiro Yamamoto ,  Miyuki Konno ,  Yoshihisa Inoue ,  Akira Matsuura ,  Tuneyuki Ohkubo

发明人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Kazumi Mizutani ,  Isao Hara ,  Takaomi Hayashi ,  Tadahito Nobori ,  Yoshihiro Yamamoto ,  Miyuki Konno ,  Yoshihisa Inoue ,  Akira Matsuura ,  Tuneyuki Ohkubo

IPC分类号： C07F9/06 ,  B01J31/02

CPC分类号： C08G63/823 ,  B01J31/0265 ,  B01J2231/12 ,  C07F9/065 ,  C07F9/224

摘要： A phosphazene-supported catalyst in which a support is bonded to a group represented by the general formula (1): wherein n, Zn−, a, b, c, d, R, R1 and D are all defined. The phosphazene-supported catalyst is highly effective to catalyze various organic reactions, and further has no reduction of activity even after recovery and reuse of the catalyst, thus it being economically advantageous. In addition, the polymerization of cyclic monomers, substitution of substituents, carbon-carbon bond forming reactions and the like can be conducted with extremely high efficiency.

摘要翻译： 载体与由通式（1）表示的基团键合的磷腈担载催化剂：其中n，Zn-，a，b，c，d，R，R1和D全部定义。 磷腈担载的催化剂对于催化各种有机反应是非常有效的，即使在回收和再利用催化剂之后也不会降低活性，因此在经济上是有利的。 此外，可以极高效率进行环状单体的聚合，取代基的取代，碳 - 碳键形成反应等。

公开(公告)号：US06762259B2

公开(公告)日：2004-07-13

申请号：US10149381

申请日：2002-06-12

申请人： Tadahito Nobori ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Makoto Suzuki ,  Kazumi Mizutani ,  Hiromi Jouyama ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Setsuko Fujiyoshi ,  Hiroyuki Sakayama ,  Mitsuyuki Mizoguchi ,  Tsuyoshi Matsumoto ,  Yoshiharu Hirose

发明人： Tadahito Nobori ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Makoto Suzuki ,  Kazumi Mizutani ,  Hiromi Jouyama ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Setsuko Fujiyoshi ,  Hiroyuki Sakayama ,  Mitsuyuki Mizoguchi ,  Tsuyoshi Matsumoto ,  Yoshiharu Hirose

IPC分类号： C08F446

CPC分类号： C09D129/12 ,  C08F2/38 ,  C08F4/00 ,  C09D125/00 ,  C09D133/04 ,  C09D135/06 ,  C09D139/00

摘要： The purpose of the present invention is to provide polymerization catalyst which can produce quite efficiently (co)polymer having number average molecular weight and number of molecules which are accurately controlled in producing method of (co)polymer by the polymerization of polar unsaturated compound, and provide living polymerized (co)polymer obtained according to the producing method. For the purpose, polymerization catalyst composition which comprises the composition comprising organic oxysalt compound and hydroxycarbonyl compound having at least both an alcoholic hydroxyl group and a carbonyl group in the same molecule is provided and the polar unsaturated compound is polymerized by using the polymerization catalyst composition. The composition containing the obtained (co)polymer were able to provide thermosetting powder coating composition having particularly excellent characteristics.

摘要翻译： 本发明的目的是提供聚合催化剂，其可以产生具有数均分子量和分子数的非常有效的（共）聚合物，其通过极性不饱和化合物的聚合制备（共）聚合物的方法被精确控制，以及 提供根据制造方法获得的活性聚合（共）聚合物。 为此，提供了包含含有有机氧化锡化合物和在同一分子中至少具有醇羟基和羰基两者的羟基羰基化合物的组合物的聚合催化剂组合物，并且通过使用聚合催化剂组合物聚合极性不饱和化合物。 含有所得（共）聚合物的组合物能够提供具有特别优异特性的热固性粉末涂料组合物。

公开(公告)号：US06469224B1

公开(公告)日：2002-10-22

申请号：US10018424

申请日：2001-12-20

申请人： Tadahito Nobori ,  Setsuko Fujiyoshi ,  Isao Hara ,  Takaomi Hayashi ,  Atsushi Shibahara ,  Katsuhiko Funaki ,  Kazumi Mizutani ,  Shinji Kiyono

发明人： Tadahito Nobori ,  Setsuko Fujiyoshi ,  Isao Hara ,  Takaomi Hayashi ,  Atsushi Shibahara ,  Katsuhiko Funaki ,  Kazumi Mizutani ,  Shinji Kiyono

IPC分类号： C07B3900

CPC分类号： B01J31/0265 ,  B01J2531/98 ,  C07B39/00 ,  C07B41/00 ,  C07C17/202 ,  C07C17/208 ,  C07C41/16 ,  C07C45/63 ,  C07C67/11 ,  C07C201/12 ,  C07C209/10 ,  C07C253/14 ,  C07C319/14 ,  C07D209/08 ,  C07D213/61 ,  C07C25/13 ,  C07C49/813 ,  C07C321/28 ,  C07C321/30 ,  C07C255/50 ,  C07C211/50 ,  C07C205/12 ,  C07C205/38 ,  C07C43/205 ,  C07C43/225 ,  C07C69/78

摘要： A substituted aromatic compound substituted with Q is obtained by reacting a phosphazenium compound represented by formula (1) (in the formula, Q− represents an anion in a form derived by elimination of a proton from an inorganic acid, or an active hydrogen compound having an active hydrogen on an oxygen atom, a nitrogen atom or a sulfur atom; a, b, c and d, each independently, is 0 or 1, but all of them are not 0 simultaneously; and R groups represent the same or different hydrocarbon groups having 1 to 10 carbon atoms, or two Rs on each common nitrogen atom may be bonded together to form a ring structure) with a halogenated aromatic compound having halogen atoms; whereby, at least one halogen atom in the halogenated aromatic compound is substituted with Q (where, Q represents an inorganic group or an organic group in a form derived by elimination of one electron from Q− in formula (1)).

摘要翻译： 被Q取代的取代芳香族化合物是通过使式（1）表示的磷氮烯基鏻化合物（式中的Q表示以无机酸除去质子衍生的阴离子，或具有式 氧原子，氮原子或硫原子上的活性氢; a，b，c和d各自独立地为0或1，但它们全部不同时为0; R基表示相同或不同的烃 具有1至10个碳原子的基团，或每个常见氮原子上的两个R可以结合在一起形成环结构）与具有卤素原子的卤代芳族化合物; 由此，卤代芳香族化合物中的至少一个卤素原子被Q取代（其中，Q表示通过在式（1）中从Q-中除去一个电子而得到的无机基团或有机基团）。

公开(公告)号：US5308848A

公开(公告)日：1994-05-03

申请号：US927738

申请日：1992-08-12

申请人： Michihiko Miyamoto ,  Tsutomu Katakami ,  Nobuya Kawauchi ,  Tadahito Nobori ,  Joji Kamiya ,  Masaaki Ishii

发明人： Michihiko Miyamoto ,  Tsutomu Katakami ,  Nobuya Kawauchi ,  Tadahito Nobori ,  Joji Kamiya ,  Masaaki Ishii

IPC分类号： C07D239/54 ,  C07D239/545 ,  C07D401/12 ,  A61K31/505 ,  C07D239/10

CPC分类号： C07D239/545 ,  C07D401/12

摘要： A pyrimidinedione derivative compound has a basic backbone in which a phenyl group part and a pyrimidinedione part are linked by a linking structure comprising an alkyl chain containing two nitrogen atoms. This linking structure is represented by ##STR1## [wherein A is --(CH.sub.2).sub.n --, --CO-- or --O--(CH.sub.2).sub.m --; each of R.sup.1 and R.sup.2 is independently a hydrogen atom or a lower alkyl group which may be substituted by a hydroxyl group, or R.sup.1 and R.sup.2 may be so linked with each other as to make an alkylene chain and thus form a heterocyclic structure; R.sup.5 is a halogen atom, a hydroxyl group, a lower alkyloxycarbonyl group, a lower alkyloxy group which may be substituted by a lower alkyloxy group, or a lower alkyl group which may be substituted by a hydroxyl group, or R.sup.5 may be so linked with R.sup.1 as to make an alkylene chain and thus form a heterocyclic structure; n is 0, 1, 2 or 3 (when R.sup.5 is the hydroxyl group, n.noteq.0); m is 0, 1, 2 or 3; and k is 0, 1, 2 or 3 (however, a compound in which A is --O--(CH.sub.2).sub.m -- and R.sup.5 is the hydroxyl group is excluded from the pyrimidinedione derivative)]. The pyrimidinedione derivative and its acid addition salt are useful for a medical treatment of cardiac arrhythmias.

摘要翻译： 嘧啶二酮衍生物化合物具有其中苯基部分和嘧啶二酮部分通过包含含有两个氮原子的烷基链的连接结构连接的碱性主链。 该连接结构由表示，其中A是 - （CH 2）n - ， - CO-或-O-（CH 2）m - ; R 1和R 2各自独立地为氢原子或可以被羟基取代的低级烷基，或者R 1和R 2可以相互连接形成亚烷基链，从而形成杂环结构; R5是卤素原子，羟基，低级烷氧基羰基，可被低级烷氧基取代的低级烷氧基或可被羟基取代的低级烷基，或R5可以与 R1形成亚烷基链，从而形成杂环结构; n是0,1,2或3（当R5是羟基时，n是等于0）; m为0,1,2或3; 并且k为0,1,2或3（然而，其中A为-O-（CH 2）m - 且R 5为羟基的化合物不包括在嘧啶二酮衍生物中]]。 嘧啶二酮衍生物及其酸加成盐可用于治疗心律失常。

公开(公告)号：US5008267A

公开(公告)日：1991-04-16

申请号：US425730

申请日：1989-10-24

申请人： Tsutomu Katakami ,  Tatsuro Yokoyama ,  Michihiko Miyamoto ,  Haruki Mori ,  Nobuya Kawauchi ,  Tadahito Nobori ,  Kunio Sannohe ,  Joji Kamiya ,  Masaaki Ishii ,  Kanji Yoshihara

发明人： Tsutomu Katakami ,  Tatsuro Yokoyama ,  Michihiko Miyamoto ,  Haruki Mori ,  Nobuya Kawauchi ,  Tadahito Nobori ,  Kunio Sannohe ,  Joji Kamiya ,  Masaaki Ishii ,  Kanji Yoshihara

IPC分类号： C07D239/54 ,  C07D239/545 ,  C07D401/12 ,  C07D403/12

CPC分类号： C07D239/545 ,  C07D401/12 ,  C07D403/12 ,  Y10S514/821

摘要： A pyrimidinedione derivative compound has a basic backbone in which a phenyl group part and a pyrimidinedione part are linked by a structure comprising an alkyl chain containing at least two nitrogen atoms. The pyrimidinedione derivative is useful for a medical treatment of cardiac arrhythmias.

摘要翻译： 嘧啶二酮衍生物化合物具有碱性主链，其中苯基部分和嘧啶二酮部分通过包含至少两个氮原子的烷基链的结构连接。 嘧啶二酮衍生物可用于治疗心律失常。