公开(公告)号：US08869514B2

公开(公告)日：2014-10-28

申请号：US13634334

申请日：2010-11-03

Applicant: Jan Pietraszek ,  Tue Johannessen

Inventor： Jan Pietraszek ,  Tue Johannessen

IPC: F01N3/00 ,  B01D53/90 ,  F01N3/20 ,  F16K17/00 ,  B01D53/94

CPC classification number: F16K17/00 ,  B01D53/90 ,  B01D53/9495 ,  B01D2251/2062 ,  B01D2253/102 ,  B01D2253/108 ,  B01D2253/204 ,  B01D2257/404 ,  B01D2258/01 ,  B01D2259/12 ,  F01N3/208 ,  F01N2610/02 ,  F01N2610/06 ,  F01N2610/10 ,  F01N2610/14 ,  F17C11/00 ,  Y02A50/2325 ,  Y02T10/24

Abstract: A method for controlled dosing of a gas with fluctuating supply pressure (PSupply). Dosing of the gas through a valve (6) is performed while a valve (5) is closed, and the decrease in control-volume pressure (PCV) is recorded. The control-volume pressure (PCV) is raised by closing dosing valve (6) and opening the valve (5). The amount of the dosed gas is calculated based on the known volume (VCV) of the control volume (4) and at least one of the change in control-volume pressure (PCV) and control-volume temperature (TCV) in the period where valve (5) is closed. The amount of dosed gas is compared with a target or set-point to adjust or regulate the subsequent dosing period or dosing event.

Abstract translation: 用于控制供给压力供给压力的方法（PSupply）。 在阀（5）关闭的同时执行通过阀（6）的气体的加注，并且记录控制体积压力（PCV）的降低。 通过关闭计量阀（6）并打开阀（5）来提高控制体积压力（PCV）。 计量的气体量基于控制体积（4）的已知体积（VCV）和控制体积压力（PCV）和控制体积温度（TCV）的变化中的至少一个来计算，其中 阀（5）关闭。 将剂量的气体与目标或设定点进行比较，以调整或调节随后的给药时间或给药事件。

公开(公告)号：US08680006B2

公开(公告)日：2014-03-25

申请号：US13061561

申请日：2009-09-07

Applicant: Jakob Svagin ,  Ulrich Quaade ,  Ryan Bradley ,  Johnny Johansen ,  Henning Schmidt ,  Tue Johannessen

Inventor： Jakob Svagin ,  Ulrich Quaade ,  Ryan Bradley ,  Johnny Johansen ,  Henning Schmidt ,  Tue Johannessen

IPC: B01J20/00

CPC classification number: F17C11/00 ,  C01C1/006 ,  C01F11/24 ,  F25B17/08

Abstract: A method of saturating reversible ammonia storage materials inside a container for the purpose of achieving high volumetric ammonia storage capacity and containers filled with the materials are disclosed.

Abstract translation: 公开了一种使可逆氨储存材料在容器内饱和以达到高体积氨储存能力和装满材料的容器的方法。

公开(公告)号：US08551219B2

公开(公告)日：2013-10-08

申请号：US13257195

申请日：2010-03-18

Applicant: Tue Johannessen ,  Ulrich Quaade

Inventor： Tue Johannessen ,  Ulrich Quaade

IPC: F17C11/00

CPC classification number: F01N3/2066 ,  B01D53/90 ,  B01D53/9495 ,  B01D2251/2062 ,  B01D2257/402 ,  C01C1/006 ,  F01N3/206 ,  F01N13/009 ,  F01N13/011 ,  F01N2610/06 ,  F01N2610/10 ,  F01N2610/1406 ,  Y02C20/10 ,  Y02P20/129 ,  Y02P20/153 ,  Y02T10/24

Abstract: In a method of storing and releasing gaseous ammonia from solid storage materials a first solid storage material (14) capable of releasing ammonia by desorption in a first container (10) and a second solid storage material (24) capable of ad- or absorbing ammonia reversibly and having a higher affinity for ammonia than the first storage material (14) in a second container (20) smaller than said first container (10) are in fluid communication. The pressure in at least the first container (10) is kept below the equilibrium pressure between ammonia and the storage material contained therein by means of a pump (28). When the pressure in the first container (10) is below a pressure threshold where the first storage material (14) does not release an amount of ammonia required by an ammonia consuming device connected with the containers via the vacuum pump (28), the second storage material (24) is heated such that the ammonia pressure of the second material (24) is higher than the ammonia pressure of the first material (14). The ammonia released by the second material (24) is continuously pumped off so as to deliver sufficient ammonia to said ammonia consuming unit. A device for carrying out the method is also described.

Abstract translation: 在从固体储存材料储存和释放气态氨的方法中，能够通过在第一容器（10）中解吸而释放氨的第一固体储存材料（14）和能够吸附或吸收氨的第二固态储存材料（24）的方法 在比第一容器（10）小的第二容器（20）中可逆地并且具有比第一存储材料（14）更高的氨的亲和力是流体连通的。 至少第一容器（10）中的压力通过泵（28）保持在氨和容纳在其中的储存材料之间的平衡压力以下。 当第一容器（10）中的压力低于第一储存材料（14）不经由真空泵（28）释放与容器连接的氨消耗装置所需的氨的量的压力阈值时，第二容器 储存材料（24）被加热，使得第二材料（24）的氨压力高于第一材料（14）的氨压力。 由第二材料（24）释放的氨被连续泵送，以便向氨消耗单元输送足够的氨。 还描述了用于执行该方法的装置。

公开(公告)号：US20110284121A1

公开(公告)日：2011-11-24

申请号：US12899667

申请日：2010-10-07

Applicant: Tue Johannessen ,  Ulrich Joachim Quaade ,  Johnny Johansen ,  Henrik Wagner-Pedersen

Inventor： Tue Johannessen ,  Ulrich Joachim Quaade ,  Johnny Johansen ,  Henrik Wagner-Pedersen

IPC: B65B31/00

CPC classification number: B01D53/0454 ,  B01D53/0438 ,  B01D2257/406 ,  B01D2259/4525 ,  C01C1/006 ,  F17C11/00

Abstract: A method for saturating or re-saturating ammonia storage material (1) capable of reversibly absorbing and desorbing ammonia in one or more storage containers (2), wherein said material is partly or fully depleted of ammonia, with ammonia to a predetermined saturation degree comprises a. placing the storage container(s) (2) in direct or indirect contact with a thermostatting medium (4) at a temperature level TT≦ about 65° C.; and b. connecting the storage container(s) (2) to a source of gaseous ammonia wherein at least during a part of the method the gaseous ammonia during saturating or re-saturation of the ammonia storage material (1) is at a pressure PS≦ about PT, wherein PS is the ammonia pressure during saturating or re-saturating of the ammonia storage material (1) and PT is the equilibrium vapor pressure of liquid ammonia at the temperature level TT.

Abstract translation: 一种用于使氨储存材料（1）饱和或再饱和的方法，其能够在一个或多个储存容器（2）中可逆地吸收和解吸氨，其中所述材料部分或全部耗尽氨，氨与预定的饱和度包括 一个。 将储存容器（2）放置在温度等级TT＆amp; NlE下与恒温介质（4）直接或间接接触; 约65°C。 和b。 将所述储存容器（2）连接到气态氨源，其中至少在所述方法的一部分期间，所述氨储存材料（1）的饱和或再饱和期间的气态氨处于压力PS＆amp; 关于PT，其中PS是在氨储存材料（1）的饱和或再饱和期间的氨压力，PT是在温度水平TT下的液氨的平衡蒸气压。

公开(公告)号：US07964163B2

公开(公告)日：2011-06-21

申请号：US12577921

申请日：2009-10-13

Applicant: Tue Johannessen ,  Christensen Claus Hviid ,  Norskov Jens Kehlet ,  Sorensen Rasmus Zink ,  Quaade Ulrich

Inventor： Tue Johannessen ,  Christensen Claus Hviid ,  Norskov Jens Kehlet ,  Sorensen Rasmus Zink ,  Quaade Ulrich

IPC: B01J8/02 ,  B01D53/34 ,  B01D53/58

CPC classification number: C01G3/14 ,  B01D53/56 ,  B01D53/79 ,  B01D53/8625 ,  B01D53/90 ,  B01D53/9409 ,  B01J20/046 ,  B01J20/28011 ,  B01J20/28014 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/3042 ,  C01C1/006 ,  C01F11/24 ,  F01N2610/02 ,  F01N2610/06 ,  F17C11/00 ,  Y02E60/364

Abstract: A solid ammonia storage and delivery material comprising an ammonia absorbing/desorbing solid material, said storage and delivery material having been compacted to a density above 50% of the theoretic skeleton density provides a solid ammonia storage material which is easy to produce and handle and has a very high density of stored ammonia which is readily released under controlled conditions even though the porosity of the material is very low, and which storage material is safe for storage and transport of ammonia without special safety measures.

Abstract translation: 包含氨吸收/解吸固体材料的固体氨储存和输送材料，所述储存和输送材料已压实至理论骨架密度的50％以上的密度，提供了易于生产和处理的固体氨储存材料，并具有 尽管材料的孔隙率非常低，但在受控条件下容易释放的非常高密度的储存氨，并且哪些储存材料在没有特别的安全措施的情况下可以安全地存储和运输氨。

公开(公告)号：US20100024403A1

公开(公告)日：2010-02-04

申请号：US12577921

申请日：2009-10-13

Applicant: Tue Johannessen ,  Claus Hviid Christensen ,  Jens Kehlet Norskov ,  Ulrich Quaade ,  Rasmus Zink Sorensen

Inventor： Tue Johannessen ,  Claus Hviid Christensen ,  Jens Kehlet Norskov ,  Ulrich Quaade ,  Rasmus Zink Sorensen

IPC: B01D53/56 ,  F17C11/00 ,  F17C13/00

CPC classification number: C01G3/14 ,  B01D53/56 ,  B01D53/79 ,  B01D53/8625 ,  B01D53/90 ,  B01D53/9409 ,  B01J20/046 ,  B01J20/28011 ,  B01J20/28014 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/3042 ,  C01C1/006 ,  C01F11/24 ,  F01N2610/02 ,  F01N2610/06 ,  F17C11/00 ,  Y02E60/364

Abstract: A solid ammonia storage and delivery material comprising an ammonia absorbing/desorbing solid material, said storage and delivery material having been compacted to a density above 50% of the theoretic skeleton density provides a solid ammonia storage material which is easy to produce and handle and has a very high density of stored ammonia which is readily released under controlled conditions even though the porosity of the material is very low, and which storage material is safe for storage and transport of ammonia without special safety measures.

Abstract translation: 包含氨吸收/解吸固体材料的固体氨储存和输送材料，所述储存和输送材料已压实至理论骨架密度的50％以上的密度，提供了易于生产和处理的固体氨储存材料，并具有 尽管材料的孔隙率非常低，但在受控条件下容易释放的非常高密度的储存氨，并且哪些储存材料在没有特别的安全措施的情况下可以安全地存储和运输氨。

公开(公告)号：US20100021780A1

公开(公告)日：2010-01-28

申请号：US12557895

申请日：2009-09-11

Applicant: Tue Johannessen ,  Henning Schmidt

Inventor： Tue Johannessen ,  Henning Schmidt

IPC: H01M8/18 ,  F17C11/00 ,  F17C13/00 ,  B01D53/94 ,  F01N3/28

CPC classification number: F17C11/00 ,  B01D53/8631 ,  B01D53/90 ,  B01D53/9431 ,  B01D53/9495 ,  B01D2251/2062 ,  C01C1/006 ,  F01N3/2066 ,  F01N3/208 ,  F01N11/00 ,  F01N2560/026 ,  F01N2610/02 ,  F01N2610/06 ,  F01N2610/10 ,  F01N2610/14 ,  F01N2610/1406 ,  F01N2610/146 ,  F01N2900/0411 ,  F01N2900/08 ,  F01N2900/12 ,  F01N2900/1808 ,  F01N2900/1811 ,  F17C13/00 ,  F17C2221/01 ,  F17C2227/0302 ,  F17C2270/0581 ,  H01M8/0606 ,  H01M8/222 ,  Y02A50/2325 ,  Y02E60/321 ,  Y02T10/24

Abstract: A system for storing ammonia in and releasing ammonia from a storage material capable of binding and releasing ammonia reversibly by adsorption or absorption for a process with a gradual ammonia demand that can vary over the time. The system has a container capable of housing the ammonia-containing storage material; a heating source arranged to supply heat for the desorption of ammonia from the solid storage medium; and a controller arranged to control the heating source to release ammonia. The heating source is arranged inside the container and surrounded by ammonia storage material. A controllable dosing valve is arranged to dose released ammonia according to the ammonia demand. The controller comprises a feed-forward control arranged to control the heat supplied by the heating source, based on the ammonia demand.

Abstract translation: 一种用于将氨从储存材料中储存和释放氨的系统，该储存材料能够通过吸附或吸收可逆地结合和释放氨，以达到可随时间变化的逐渐氨需求的过程。 该系统具有能容纳含氨储存材料的容器; 加热源，其设置用于从固体储存介质中提供氨以解吸氨; 以及控制器，其布置成控制加热源以释放氨。 加热源设置在容器的内部并被氨储存材料包围。 布置可控计量阀以根据氨需求量剂量释放氨。 该控制器包括一个前馈控制装置，其基于氨的需求来控制由加热源供应的热量。

公开(公告)号：US20070207351A1

公开(公告)日：2007-09-06

申请号：US10593519

申请日：2005-03-22

Applicant: Claus Christensen ,  Tue Johannessen ,  Jens Norskov ,  Ulrich Quaade

Inventor： Claus Christensen ,  Tue Johannessen ,  Jens Norskov ,  Ulrich Quaade

IPC: H01M8/04

CPC classification number: C01C1/006 ,  C01F5/00 ,  C01F5/26 ,  C01P2002/72 ,  H01M8/04216 ,  H01M8/0606 ,  H01M8/22

Abstract: An electric power generating unit comprising (i) an ammonia storage device in the form of a container comprising an ammonia absorbing and releasing salt of the general formula: Ma(NH3)nXz, wherein M is one or more cations selected from alkali metals, alkaline earth metals, and transition metals such as Li, K, Mg, Ca, V, Cr, Mn, Fe, Co, Ni, Cu or Zn, X is one or more anions selected from fluoride, chloride, bromide, iodide, nitrate, thiocyanate, sulphate, molybdate, phosphate, and chlorate ions, a is the number of cations per salt molecule, Z is the number of anions per salt molecule, and n is the coordination number of 2 to 12. (ii) means for heating said container and ammonia absorbing and releasing salt for releasing ammonia gas and (iiia) a fuel cell for converting ammonia directly into electric power; or (iiib1) a reactor for dissociating ammonia into hydrogen and nitrogen and (iiib2) a fuel cell for converting hydrogen into electric power is useful for large stationary energy producing facilities, but also for use for is useful for large stationary energy producing facilities, but also for use for small rechargeable and/or replaceable power supply units for micro-fabricated or miniaturized ammonia decomposition reactors for use in mobile units and portable devices may be used for large energy producing facilities, and by use of small rechargeable and/or replaceable ammonia storage decomposition reactors, it is also possible to provide energy for mobile units and portable devices.

Abstract translation: 一种发电单元，包括（i）包含氨吸收和释放盐的容器形式的氨储存装置，其具有以下通式：Ma（NH 3）n N 其中M是选自碱金属，碱土金属和过渡金属如Li，K，Mg，Ca，V，Cr，Mn，Fe，Co中的一种或多种阳离子， Ni，Cu或Zn，X是选自氟化物，氯化物，溴化物，碘化物，硝酸盐，硫氰酸盐，硫酸盐，钼酸盐，磷酸盐和氯酸根离子中的一种或多种阴离子，a是每个盐分子的阳离子数，Z是数 的阴离子，n是2〜12的配位数。（ii）加热所述容器和氨吸收和释放氨以释放氨气的装置和（iiia）用于将氨直接转化为电力的燃料电池的装置; 或（iiib1）用于将氨离解成氢和氮的反应器和（iib2）用于将氢转化为电力的燃料电池对于大型固定能量生产设备是有用的，但也用于大型固定能量生产设施，但是 也可用于用于移动单元和便携式设备的微型或微型氨分解反应堆的小型可再充电和/或可更换电源单元，可用于大型能源生产设备，并可使用小型可再充电和/或可更换氨 存储分解反应器，还可以为移动单元和便携式设备提供能量。