摘要:
A method is provided for estimating the degree of saturation (S) of a reversible solid ammonia storage material (3) in a storage unit (1). The storage unit (1) is equipped with a heater (2) to release ammonia and a connected tube (4) for ammonia flow. The initial temperature (TINIT) is measured with a sensor (9) in or around the storage unit (1) before any heating is initiated. Heating is initiated while recording the active time of heating (t) or the amount of energy (Q) released by the heater. The desorption pressure created by solid storage material in the storage unit (1) is measured via a pressure sensor (8) in fluid communication with the storage unit (1). The time (tTARGET), or the heat (QTARGET) where the pressure reaches a certain target pressure (PTARGET) is recorded. The values of the target-pressure time (tTARGET), or the target-pressure heat (QTARGET), and the initial temperature (TINIT) are used to compute an approximate degree of saturation (S).
摘要:
A method is provided for estimating the degree of saturation (S) of a reversible solid ammonia storage material (3) in a storage unit (1). The storage unit (1) is equipped with a heater (2) to release ammonia and a connected tube (4) for ammonia flow. The initial temperature (TINIT) is measured with a sensor (9) in or around the storage unit (1) before any heating is initiated. Heating is initiated while recording the active time of heating (t) or the amount of energy (Q) released by the heater. The desorption pressure created by solid storage material in the storage unit (1) is measured via a pressure sensor (8) in fluid communication with the storage unit (1). The time (tTARGET), or the heat (QTARGET) where the pressure reaches a certain target pressure (PTARGET) is recorded. The values of the target-pressure time (tTARGET), or the target-pressure heat (QTARGET), and the initial temperature (TINIT) are used to compute an approximate degree of saturation (S).
摘要:
A system for storing ammonia in and releasing ammonia from a storage material capable of binding and releasing ammonia reversibly by adsorption or absorption for a process with a gradual ammonia demand that can vary over the time. The system has a container capable of housing the ammonia-containing storage material; a heating source arranged to supply heat for the desorption of ammonia from the solid storage medium; and a controller arranged to control the heating source to release ammonia. The heating source is arranged inside the container and surrounded by ammonia storage material. A controllable dosing valve is arranged to dose released ammonia according to the ammonia demand. The controller comprises a feed-forward control arranged to control the heat supplied by the heating source, based on the ammonia demand.
摘要:
A system for storage and dosing of ammonia, including a solid ammonia storage material capable of binding and releasing ammonia reversibly by adsorption/absorption. The system is able to release ammonia gradually according to a demand that can vary over time with intermediate periods of no ammonia demand. A main storage unit and a start-up storage unit are provided. The storage units hold ammonia storage material. At least one one-way valve is provided via which the one main storage unit is in communication with the start-up storage unit. The one-way valve prevents any back-flow of ammonia from the start-up storage unit to the main storage unit. Heating devices are arranged to heat the main storage unit and the start-up storage unit separately to generate gaseous ammonia by thermal desorption from the solid storage material. A controller controls the heating power of the main storage unit and the start-up storage unit, thereby enabling ammonia release from at least one of the start-up and/or the main storage unit. A dosing valve controls ammonia flow from the storage units according to a demand.
摘要:
Solid metal ammine complexes are applied for safe and high-density storage of ammonia to be released for use as reducing agent in selective catalytic reduction of NOx in exhaust gases or as an energy carrier for fuel cell applications. The compositional formula of the metal ammine complexes is M(NH3)nXz, where Mz+ represents one or more metal ions capable of binding ammonia, X represents one or more anions, n is the coordination number (from 2 to 12), and z the valency of the metal ion (and thus the total number of compensating anion charges). Ammonia is released by controlled dosing of water into the storage container whereby ammonia is released because water replaces ammonia on the active sites capable of binding ammonia. Consequently, ammonia can be released without applying a normal thermal desorption of ammonia and the operating temperature of the system is reduced as well as the energy needed for releasing ammonia.
摘要翻译:应用固体金属氨络合物来安全和高密度地储存氨,以用作废气中NOx的选择性催化还原或作为燃料电池应用的能量载体的还原剂。 金属络合物的组成式为M(NH 3)n X z,其中M z +表示一种或多种能结合氨的金属离子,X表示一种或多种阴离子,n为配位数(2至12),z为 金属离子的化合价(因此补偿阴离子电荷的总数)。 氨通过控制计量的水释放到储存容器中而释放,由此氨释放出能够结合氨的活性位上的氨。 因此,可以释放氨,而不会对氨进行正常的热解吸,同时降低系统的工作温度以及释放氨所需的能量。
摘要:
A system for storage and dosing of ammonia, including a solid ammonia storage material capable of binding and releasing ammonia reversibly by adsorption/absorption. The system is able to release ammonia gradually according to a demand that can vary over time with intermediate periods of no ammonia demand. A main storage unit and a start-up storage unit are provided. The storage units hold ammonia storage material. At least one one-way valve is provided via which the one main storage unit is in communication with the start-up storage unit. The one-way valve prevents any back-flow of ammonia from the start-up storage unit to the main storage unit. Heating devices are arranged to heat the main storage unit and the start-up storage unit separately to generate gaseous ammonia by thermal desorption from the solid storage material. A controller controls the heating power of the main storage unit and the start-up storage unit, thereby enabling ammonia release from at least one of the start-up and/or the main storage unit. A dosing valve controls ammonia flow from the storage units according to a demand.
摘要:
A method of storing and delivering ammonia and the use of electromagnetic radiation for desorption of ammonia from a chemical complex. Solid metal ammine complexes are applied for safe and high-density storage of ammonia to be released for use as reducing agent in selective catalytic reduction of NOx in exhaust gases. The compositional formula of the metal ammine complexes is M(NH3)nXz, where M2+ represents one or more metal ions capable of binding ammonia, X represents one or more anions, n is the coordination number (from 2 to 12), and z the valency of the metal ion (and thus the total number of compensating anion charges). Ammonia is released non-thermally by photon-activation using electromagnetic irradiation of the complex bond between ammonia coordinated to the metal ion
摘要翻译:一种储存和输送氨的方法,以及使用电磁辐射从化学络合物中解氨的方法。 应用固体金属氨络合物用于安全和高密度地储存氨,以用作废气中选择性催化还原NOx的还原剂。 金属络合物的组成式为M(NH 3)n X z,其中M 2 +表示一个或多个能结合氨的金属离子,X表示一个或多个阴离子,n为配位数(2至12),z为 金属离子的化合价(因此补偿阴离子电荷的总数)。 通过使用与金属离子配位的氨之间的复合键的电磁照射,通过光子激活而非热释放氨
摘要:
A system for storing ammonia in and releasing ammonia from a storage material capable of binding and releasing ammonia reversibly by adsorption or absorption for a process with a gradual ammonia demand that can vary over the time. The system has a container capable of housing the ammonia-containing storage material; a heating source arranged to supply heat for the desorption of ammonia from the solid storage medium; and a controller arranged to control the heating source to release ammonia. The heating source may be arranged inside the container and surrounded by ammonia storage material. A controllable dosing valve is arranged to dose released ammonia according to the ammonia demand. The controller comprises a feed-forward control arranged to control the heat supplied by the heating source, based on the ammonia demand.
摘要:
A method for controlling the effective heat transfer from a storage unit (1). During gas release from storage material (3) in the storage unit the storage material is heated by a heater (2). During re-saturation of the storage material (3) with gas the heater is off. Controlling of the effective heat transfer from the storage unit (1) is performed, during gas release, by ceasing convection of a convection gas and, during re-saturation, by performing or enabling convection of a convection gas to cool the storage unit (1).
摘要:
A method of storing and delivering ammonia and the use of electromagnetic radiation for desorption of ammonia from a chemical complex. Solid metal ammine complexes are applied for safe and high-density storage of ammonia to be released for use as reducing agent in selective catalytic reduction of NOx in exhaust gases. The compositional formula of the metal ammine complexes is M(NH3)nXz, where M2+ represents one or more metal ions capable of binding ammonia, X represents one or more anions, n is the coordination number (from 2 to 12), and z the valency of the metal ion (and thus the total number of compensating anion charges). Ammonia is released non-thermally by photon-activation using electromagnetic irradiation of the complex bond between ammonia coordinated to the metal ion.
摘要翻译:一种储存和输送氨的方法,以及使用电磁辐射从化学络合物中解氨的方法。 应用固体金属氨络合物用于安全和高密度地储存氨,以用作废气中选择性催化还原NOx的还原剂。 金属络合物的组成式为M(NH 3)n X z,其中M 2 +表示一个或多个能结合氨的金属离子,X表示一个或多个阴离子,n为配位数(2至12),z为 金属离子的化合价(因此补偿阴离子电荷的总数)。 通过使用与金属离子配位的氨之间的复合键的电磁照射,通过光子激活而非热释放氨。