摘要:
The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VI B and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm-1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm-1. The invention also concerns the process for preparing the catalyst and its use in hydroconversion.
摘要:
The invention relates to a process for the catalytic hydrotreating of a feedstock of petroleum origin of diesel fuel type and of a feedstock of biological origin based on vegetable oils and/or animal fats in a stationary bed catalytic hydrotreating unit, the said process being characterized in that the feedstock of petroleum origin is introduced into the said reactor upstream of the feedstock of biological origin.It also relates to a catalytic hydrotreating unit for the implementation of the said process and to a corresponding hydrorefining unit.
摘要:
The instant invention discloses a method for the valorization of spent catalyst from hydrocarbon processing slurry reactors as well as slurry flakes.
摘要:
The invention relates to a method and a system for controlling the production of a mixture of constituents, especially a mixture with premix dead volumes.By correcting the matrices for calculating the mixture constituents, used in calculating recipes, by introducing limit, order relationship and equality constraints, it is possible to avoid the drifts observed in certain special cases by the implementation of the method and to improve, on the one hand, the diagnostic assistance and the control of the estimation of the properties so as to limit the deviations from the actual quality of the constituents of the mixture and, on the other hand, the speed of manufacture of the mixture and the robustness of the method.The method and the system according to the invention ensure multivariable regulation feedback by a dynamic observer providing an estimate in real time of the properties of the constituents of the mixture, said estimate being sufficient to guarantee the effectiveness of the feedback loop.
摘要:
The invention relates to a method for preparing a hydroconversion catalyst based on mesoporous silica or silica-alumina, comprising the following steps: (A) deposition of alumina on a mesoporous material having interconnected pores by treatment with at least one aluminium-based reactant, so as to obtain a compound having a Si/Al ratio of between 0.1 and 1000; (B) addition of at least one catalytically active species chosen from the group formed by the metals of group VIII and/or of group VIB; and (C) drying followed by thermal and/or chemical treatment according to the invention. The invention also relates to the catalyst thus obtained as well as a method of hydroconverting (hydrocracking, hydroisomerizing) a hydrocarbon feedstock, which comprises bringing the feedstock to be treated into contact with the hydroconversion catalyst according to the invention.
摘要:
The invention deals with a method for preparing a nitrogen-depleted hydrocarbon feedstock (315, 412, 514, 614, 714, 718, 814, 822) having (i) an initial boiling point comprised between 0° C. and +180° C. and a final boiling point comprised between 30° C. and 250° C., and (ii) an olefin content higher than 5 weight %, by contacting a hydrocarbon feedstock starting material (310, 313, 410, 411, 510, 512, 610, 612, 710, 712, 713, 810, 812, 813) with a clay sorbent material in a reaction vessel (33,43,53,63,73,73,83,83), wherein the nitrogen-depleted hydrocarbon feedstock (315, 412, 514, 614, 714, 718, 814, 822) has a total nitrogen/nitrile ratio (ppm/ppm) comprised between 1 and 5. Additional purification section allows improved units working time and lower maintenance.
摘要:
The invention relates to a method and a device for controlling the production of a mixture of components, especially a mixture with premix dead volumes.The method and the device according to the invention ensure multivariable regulation feedback by a dynamic observer providing an estimate in real time of the properties of the components of the mixture, said estimate being sufficient to guarantee the effectiveness of the feedback loop. Thus, the desired properties of the mixture are guaranteed despite large uncertainties in the properties of the components on the one hand, and partial knowledge of the mixing process on the other.
摘要:
The invention relates to a process for hydrodeoxygenation (HDO) of pyrolysis oil and also to a process for upgrading of pyrolysis oil implementing said HDO process, and also to processing of the aqueous phase resulting from the HDO by steam pre-reforming and then steam reforming.
摘要:
The disclosure relates to a bituminous composition comprising at least one bitumen and at least one organogelling molecule taken alone or as a mixture, said organogelling molecule being represented by the following general formula (I): where: A represents an acyclic, cyclic or polycyclic, saturated or unsaturated, linear or branched hydrocarbon-based group having 3 to 92 carbon atoms, resulting from the polymerization of the side chains of at least one unsaturated fatty acid, X represents an NH group or an oxygen atom O, R1 represents a group chosen from: a linear or branched hydrocarbon-based group having 2 to 40 carbon atoms, optionally comprising one or more heteroatoms and optionally comprising one or more unsaturations, or a substituted or unsubstituted aromatic group, R2 represents a group chosen from: a hydrogen atom, a linear or branched hydrocarbon-based group having 1 to 40 carbon atoms, comprising one or more heteroatoms and optionally comprising one or more unsaturations, or a substituted or unsubstituted aromatic group, m and n represent, independently of one another, an integer that varies from 1 to 4, p represents an integer that varies from 0 to 4, q represents an integer that varies from 1 to 4 or a combination of these values, Y represents a group comprising a hydrogen bond donor such as the NH group and a hydrogen bond acceptor such as the C═O group.
摘要:
The present invention relates to a device (1) for damping pressure variations in a sealed chamber, including: a flat element (4) held stationary in the sealed chamber and perforated with at least one opening (10); at least one flat mobile element (3) arranged, in normal operation, in the same shared plane as the element held stationary in the chamber so as to cover the opening of the element which is held stationary, said mobile flat element being suitable for separating from the opening in the direction of the top or the bottom of the chamber, the dimensions of said element which is held stationary being at least equal to those of the opening for the element which is held stationary, preferably equal to those of said opening; at least one joining member (7) rigidly connecting the mobile element to the element which is held stationary and enabling the flat mobile element to be held, separated or returned relative to the opening of the element which is held stationary, in particular said joining member comprising a rod (8) surrounded by at least one torsion or compression spring (9), as well as use of the device.