MONOMERS COMPRISING AT LEAST ONE 4-(2-OXYETHYLIDENE)-1,3-DIOXOLAN-2-ONE UNIT AND USE THEREOF

    公开(公告)号:US20210070728A1

    公开(公告)日:2021-03-11

    申请号:US16951207

    申请日:2020-11-18

    申请人: BASF SE

    摘要: A compound of formula (I) wherein R1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R2, R3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

    Diene-based carboxylate anion and salt thereof, and polymerizable or curable composition thereof
    34.
    发明授权
    Diene-based carboxylate anion and salt thereof, and polymerizable or curable composition thereof 有权
    二烯系羧酸根阴离子及其盐及其可聚合或可固化的组合物

    公开(公告)号:US09499466B2

    公开(公告)日:2016-11-22

    申请号:US13877751

    申请日:2011-10-05

    申请人: Tomomasa Kaneko

    发明人: Tomomasa Kaneko

    摘要: The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

    摘要翻译: 要求保护的发明提供了一种未经过研究的新化合物,即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂,反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐,特别是其金属盐,在常温下可根据结构处于液态, 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂,提供了各种性能,例如硬度,耐擦伤性,抗指纹性,阻气性,水蒸气阻隔性,氧吸收性,紫外线防护 红外线保护,显色和着色,高折射率,附着力,各种催化能力,荧光能力和发光能力,光学放大,分散性和抗静电性能。 此外,阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料,也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。

    ISOLATING SEMICONDUCTING SINGLE-WALLED NANOTUBES OR METALLIC SINGLE-WALLED NANOTUBES AND APPROACHES THEREFOR
    35.
    发明申请
    ISOLATING SEMICONDUCTING SINGLE-WALLED NANOTUBES OR METALLIC SINGLE-WALLED NANOTUBES AND APPROACHES THEREFOR 审中-公开
    分离半导体单壁纳米管或金属单壁纳米管及其方法

    公开(公告)号:US20160280548A1

    公开(公告)日:2016-09-29

    申请号:US15080313

    申请日:2016-03-24

    IPC分类号: C01B31/02 H01C7/00 C08F136/20

    摘要: Embodiments in accordance with the present disclosure include methods, polymers, and complexes. For example, a method embodiments includes providing a solution including a disassembled supramolecular polymer and a bond disrupting agent, adding an antisolvent to the solution to precipitate the supramolecular polymer, and isolating the precipitated supramolecular polymer from the bond disrupting agent. The isolated supramolecular polymer is configured to selectively disperse single-walled carbon nanotubes (SWNTs) of a particular electrical type from a SWNT mixture including SWNTS of at least two electrical types

    摘要翻译: 根据本公开的实施方案包括方法,聚合物和配合物。 例如,方法实施方案包括提供包括分解的超分子聚合物和键断裂剂的溶液,向溶液中加入抗溶剂以沉淀超分子聚合物,并从沉淀的超分子聚合物与键断层剂分离。 分离的超分子聚合物被配置为从包含至少两种电气类型的SWNTS的SWNT混合物中选择性分散特定电气类型的单壁碳纳米管(SWNT)

    DISPERSING AGENT FOR INORGANIC FILLERS AND METHOD OF PRODUCING SAME
    38.
    发明申请
    DISPERSING AGENT FOR INORGANIC FILLERS AND METHOD OF PRODUCING SAME 审中-公开
    无机填料的分散剂及其生产方法

    公开(公告)号:US20140080978A1

    公开(公告)日:2014-03-20

    申请号:US14081398

    申请日:2013-11-15

    摘要: The invention provides dispersing agents for inorganic fillers capable of uniformly dispersing inorganic fillers in a substrate such as made of a rubber or resin material such that molded products with improved mechanical strength and abrasion resistance can be produced from such a substrate material and more specifically that rubber compositions with improved abrasion resistance and workability can be obtained and that automobile tires with improved low fuel consumption and handling stability can be produced from such rubber compositions, as well as a method of producing such dispersing agents characterized as using a modified conjugated diene polymer obtained by introducing specified structural units with improved mutual reaction with inorganic fillers into a conjugated diene polymer having affinity with rubber and resin materials.

    摘要翻译: 本发明提供了能够将无机填料均匀分散在诸如由橡胶或树脂材料制成的基材中的无机填料的分散剂,使得可以由这种基材生产具有改善的机械强度和耐磨性的成型产品,更具体地说,橡胶 可以获得具有改进的耐磨性和可加工性的组合物,并且可以由这种橡胶组合物制备具有改善的低燃料消耗和操作稳定性的汽车轮胎,以及制备这种分散剂的方法,其特征在于使用由 将具有改善的与无机填料相互反应的指定结构单元引入具有与橡胶和树脂材料具有亲和性的共轭二烯聚合物中。

    SYNTHESIS OF METHYLENE MALONATES USING RAPID RECOVERY IN THE PRESENCE OF A HEAT TRANSFER AGENT
    39.
    发明申请
    SYNTHESIS OF METHYLENE MALONATES USING RAPID RECOVERY IN THE PRESENCE OF A HEAT TRANSFER AGENT 有权
    在热转印剂存在下使用快速回收合成甲基丙烯酸甲酯

    公开(公告)号:US20130281580A1

    公开(公告)日:2013-10-24

    申请号:US13880471

    申请日:2011-10-19

    摘要: The present invention provides a method of making a methylene malonate monomer that includes the steps of reacting a malonic acid ester with a source of formaldehyde optionally in the presence of an acidic or basic catalyst and optionally in the presence of an acidic or non-acidic solvent to form reaction complex. The reaction is optionally performed in the presence of or contacted with an energy transfer means such as a heat transfer agent, a heat transfer surface, a source of radiation or a laser such that reaction complex is substantially vaporized to produce a vapor phase comprising methylene malonate monomer which may be isolated. The present invention further provides methylene malonate monomers prepared by the method of the invention, as well as compositions and products formed from the methylene malonate monomers, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

    摘要翻译: 本发明提供一种制备亚甲基丙二酸单体的方法,其包括以下步骤:使丙二酸酯与甲醛源任选地在酸性或碱性催化剂存在下反应,并任选在酸性或非酸性溶剂存在下反应 形成反应复合物。 该反应任选地在诸如传热剂,传热表面,辐射源或激光的能量转移装置的存在或接触的情况下进行,使得反应复合物基本上蒸发以产生包含亚甲基丙二酸酯的气相 可以分离的单体。 本发明还提供了通过本发明方法制备的亚甲基丙二酸单体,以及由亚甲基丙二酸酯单体形成的组合物和产品,包括基于单体的产品(例如油墨,粘合剂,涂料,密封剂或反应性模塑)和聚合物 (如纤维,薄膜,薄片,医用聚合物,复合聚合物和表面活性剂)。

    PHOTOREACTIVE MATERIAL LAYER AND METHOD OF MANUFACTURING THE SAME
    40.
    发明申请
    PHOTOREACTIVE MATERIAL LAYER AND METHOD OF MANUFACTURING THE SAME 有权
    光电材料层及其制造方法

    公开(公告)号:US20130211029A1

    公开(公告)日:2013-08-15

    申请号:US13534968

    申请日:2012-06-27

    IPC分类号: C08F136/20 B05D3/02 B05D3/06

    摘要: A photoreactive material layer includes an upper portion and a lower portion each including a uniformly aligned crosslinked photoreactive material, wherein the upper portion includes a first portion of the crosslinked photoreactive material and a second portion of the crosslinked photoreactive material, wherein the first portion of the photoreactive material and the second portion of the crosslinked photoreactive material are crosslinked with each other and aligned in a first direction, and the lower portion includes a third portion of the crosslinked photoreactive material and a fourth portion of the crosslinked photoreactive material, wherein the third portion of the crosslinked photoreactive material and the fourth portion of the crosslinked photoreactive material are crosslinked with each other and aligned in the first direction.

    摘要翻译: 光反应性材料层包括各自包含均匀排列的交联光反应性材料的上部和下部,其中上部包括交联的光反应性材料的第一部分和交联的光反应性材料的第二部分,其中第一部分 光反应性材料的第二部分和交联的光反应性材料的第二部分彼此交联并在第一方向上排列,并且下部包括交联的光反应性材料的第三部分和交联的光反应性材料的第四部分,其中第三部分 的交联光反应性材料和第四部分交联的光反应性材料彼此交联并沿第一方向排列。