METHOD FOR THE PREPARATION OF THIOCARBONATES

    公开(公告)号:US20220127241A1

    公开(公告)日:2022-04-28

    申请号:US17646766

    申请日:2022-01-03

    申请人: BASF SE

    IPC分类号: C07D327/04 C07D411/12

    摘要: A process can be used for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group. The process involves a) using a compound with at least one epoxy group as starting material; b) reacting the compound with phosgene or an alkyl chloroformate, thus giving an adduct; and c) reacting the adduct with a compound containing anionic sulfur, thus obtaining the compound with at least one five-membered cyclic monothiocarbonate group.

    PROCESS FOR THE MANUFACTURING OF A POLYMER WITH URETHANE GROUPS

    公开(公告)号:US20200239633A1

    公开(公告)日:2020-07-30

    申请号:US16639204

    申请日:2018-08-07

    申请人: BASF SE

    IPC分类号: C08G71/04 C07D327/04

    摘要: Process for the manufacturing of a polymer with urethane groups, wherein in a first alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups and a compound B) with at least two amino groups, selected from primary or secondary amino groups and optionally a compound C) with at least one functional group that reacts with a group —SH are reacted or wherein in a second alternative a compound A) with at least two five-membered cyclic monothiocarbonate groups or a mixture of a compound A) with a compound A1) with one five-membered cyclic monothiocarbonate group and a compound B) with at least two amino groups, selected from primary or secondary amino groups or a compound B1) with one amino group selected from primary or secondary amino groups or mixtures of compounds B) and B1) and a compound C) with at least two functional groups that react with a group —SH or in case of a carbon-carbon triple bond as functional group that react with a group —SH, a compound C) with at least one carbon-carbon triple bond. are reacted.

    PROCESS FOR THE MANUFACTURING OF A POLYMER WITH URETHANE GROUPS

    公开(公告)号:US20240279199A1

    公开(公告)日:2024-08-22

    申请号:US18595535

    申请日:2024-03-05

    申请人: BASF SE

    IPC分类号: C07D327/04 C08G71/04

    CPC分类号: C07D327/04 C08G71/04

    摘要: A process for the manufacturing of a polymer with urethane groups can be performed. In a first alternative a five-membered cyclic monothiocarbonate, a compound with at least two amino groups selected from primary or secondary amino groups, and a compound with at least two function groups that react with a —SH group are reacted. In a second alternative a five-membered cyclic monothiocarbonate and a compound with at least one primary or secondary amino group, and at least one function group that reacts with an —SH group are reacted.

    MONOMERS COMPRISING AT LEAST ONE 4-(2-OXYETHYLIDENE)-1,3-DIOXOLAN-2-ONE UNIT AND USE THEREOF

    公开(公告)号:US20210070728A1

    公开(公告)日:2021-03-11

    申请号:US16951207

    申请日:2020-11-18

    申请人: BASF SE

    摘要: A compound of formula (I) wherein R1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R2, R3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

    PROCESS FOR PREPARING CYCLIC CARBONATES
    10.
    发明申请

    公开(公告)号:US20200369640A1

    公开(公告)日:2020-11-26

    申请号:US16634255

    申请日:2018-08-14

    申请人: BASF SE

    摘要: The present invention relates to a process for preparing cyclic carbonates of formula Ia or Ib or mixtures thereof (Ia) (Ib) comprising the process step: a) reacting a propargylic alcohol of formula II (II) with carbon dioxide in the presence of at least one transition metal catalyst TMC1, which comprises a transition metal selected from metals of groups 10, 11 and 12 of the periodic table of the elements according to IUPAC and at least one bulky ligand.