Pipes and Polyolefin Composition For the Manufacture Thereof
    392.
    发明申请
    Pipes and Polyolefin Composition For the Manufacture Thereof 有权
    管和聚烯烃组合物的制造

    公开(公告)号:US20130095266A1

    公开(公告)日:2013-04-18

    申请号:US13805753

    申请日:2011-06-08

    Abstract: A heterophasic polypropylene composition comprising (percent by weight referred to the sum of components A) and B)): A) from 80% to 97% of a random copolymer of propylene containing from 0.1 to 4% of 1-hexene derived units; B) from 3-20% of a copolymer of propylene and ethylene having a content of ethylene derived units ranging from 50% to 55% extremes excluded; wherein the heterophasic polypropylene composition is endowed with a Melt Flow Rate: measured according to ISO 1133 (230° C., 5 Kg) ranging from 0.5 to 5 g/10 min; and an intrinsic viscosity (IV) of the fraction soluble in xylene at room temperature ranging from 2.5 to 5.5;

    Abstract translation: 一种多相聚丙烯组合物,其包含(以重量百分数称为组分A)和B)):A)80%至97%的含有0.1至4%的1-己烯衍生单元的丙烯的无规共聚物; B)从3-20%的丙烯和乙烯的共聚物的乙烯衍生单元的范围为不超过50%至55%的极限; 其中所述多相聚丙烯组合物具有根据ISO 1133(230℃,5Kg)测量的熔体流动速率,范围为0.5至5g / 10min; 和在室温范围为2.5〜5.5的可溶于二甲苯的馏分的特性粘度(Ⅳ);

    Polyolefin compositions
    393.
    发明授权
    Polyolefin compositions 有权
    聚烯烃组合物

    公开(公告)号:US08378028B2

    公开(公告)日:2013-02-19

    申请号:US12735705

    申请日:2009-02-04

    Abstract: Polyolefin composition, comprising in percent by weight: 1) 75-85% of a copolymer of propylene, said copolymer containing up to 15% by weight, of ethylene and/or C4-C10 α-olefin(s) and having a fraction soluble in Xilene at room temperature lower than 6% by weight, and 2) 15-25% of a copolymer of ethylene with one or more C4-C10 α-olefin(s) containing from 10 to 25% by weight of said C4-C10 α-olefin(s); said composition having the value of MFR, measured at 230° C., 2.16 kg, of less than 2.5 g/10 min, the total content of ethylene of from 14 to 22% by weight, the total content of C4-C10 α-olefin(s) of less than 4.5% by weight, the ratio of the total content of ethylene to the total content of C4-C10 α-olefin(s) equal to or higher than 4, the value of the intrinsic viscosity of the total fraction soluble in xylene at room temperature equal to or less than 1.5 dl/g, and the ratio of the amount of component 2) and the amount of C4-C10 α-olefin(s) in component 2) equal to or higher than 0.80.

    Abstract translation: 聚烯烃组合物,其包含以重量百分比计:1)75-85%的丙烯共聚物,所述共聚物含有至多15重量%的乙烯和/或C 4 -C 10α-烯烃,并且具有可溶解的馏分 在Xilene中,室温低于6重量%,和2)15-25%的乙烯与一种或多种含有10至25重量%的所述C 4 -C 10的C 4 -C 10α-烯烃的共聚物 α-烯烃; 所述组合物具有在230℃,2.16kg,小于2.5g / 10min下测量的MFR值,乙烯的总含量为14至22重量%,C 4 -C 10α-烯烃的总含量, 小于4.5重量%的烯烃,乙烯的总含量与C4-C10α-烯烃的总含量的比等于或高于4,特性粘度的值为总计 室温下可溶于二甲苯的馏分等于或小于1.5dl / g,组分2中的组分2的量与组分2中的C 4 -C 10α-烯烃的比例等于或高于0.80 。

    Polyolefin thermoplastic vulcanizate elastomers
    394.
    发明授权
    Polyolefin thermoplastic vulcanizate elastomers 有权
    聚烯烃热塑性硫化橡胶弹性体

    公开(公告)号:US08338543B2

    公开(公告)日:2012-12-25

    申请号:US12308625

    申请日:2007-05-15

    Abstract: Thermoplastic vulcanizate elastomer obtained by dynamic vulcanization of a heterophasic polyolefin composition in presence of at least (i) an alkenyl-substituted alkoxysilane grafting agent and (ii) water; wherein said heterophasic polyolefin composition has flexural modulus equal to or lower than 150 MPa, and comprises: (a) a crystalline propylene homopolymer or copolymer of propylene with up to 15% of ethylene or other alpha-olefin comonomer(s), or their combinations, and (b) a copolymer or a composition of copolymers of ethylene with other alpha-olefins, containing from 15% to 40% of ethylene, said thermoplastic vulcanizate elastomer having compression set values in the range from 45-65%, the ratio of elongation at break to compression set values over 10 and hardness shore A values below 90.

    Abstract translation: 存在至少(i)烯基取代的烷氧基硅烷接枝剂和(ii)水的多相聚烯烃组合物的动态硫化获得的热塑性硫化橡胶弹性体; 其中所述多相聚烯烃组合物具有等于或低于150MPa的挠曲模量,并且包括:(a)丙烯与至多15%的乙烯或其它α-烯烃共聚单体的结晶丙烯均聚物或共聚物,或其组合 ,和(b)乙烯与其它含有15%至40%乙烯的α-烯烃的共聚物或共聚物的组合物,所述热塑性硫化橡胶弹性体的压缩永久变形值在45-65%的范围内, 断裂伸长率为10以上的压缩永久变形值,硬度Shore A值低于90。

    Filled polyolefin compositions
    396.
    发明授权
    Filled polyolefin compositions 有权
    填充聚烯烃组合物

    公开(公告)号:US08309659B2

    公开(公告)日:2012-11-13

    申请号:US12448385

    申请日:2007-12-12

    Abstract: Filled polyolefin compositions comprising: A) from 20% to 80% by weight of a polypropylene component; B) from 20% to 80% by weight of a filler; wherein the percentages of A) and B) are referred to the sum of A) and B), and A) is selected from the following compositions: a) a polypropylene composition containing from 20% to 80% by weight of a polypropylene fraction AI) having a Melt Flow Rate value of 500 g/10 min. or more, and from 20% to 80% by weight of a polypropylene fraction AII) having a Melt Flow Rate value of from 0.1 to 30 g/10 min., the said percentages of AI) and AII) being referred to the sum of AI) and AII); or b) a polypropylene composition containing from 15% to 72% by weight of a polypropylene fraction AI) having a Melt Flow Rate value of 500 g/10 min. or more, from 15% to 70% by weight of a polypropylene fraction AII) having a Melt Flow Rate value of from 0.1 to 30 g/10 min. and from 0.5% to 15% by weight of a compatibilizer Q), the said percentages of AI), AII) and Q) being referred to the sum of AI), AII) and Q).

    Abstract translation: 填充的聚烯烃组合物,其包含:A)20重量%至80重量%的聚丙烯组分; B)20重量%至80重量%的填料; 其中A)和B)的百分比称为A)和B)的总和,A)选自以下组合物:a)包含20重量%至80重量%的聚丙烯部分AI的聚丙烯组合物 ),熔体流动速率值为500g / 10min。 或更高,20%至80%重量的聚丙烯级分AII),熔体流动速率值为0.1至30克/ 10分钟,所述百分比的AI)和AII)为 AI)和AII); 或b)含有15重量%至72重量%的熔体流动速率值为500g / 10min的聚丙烯部分AI的聚丙烯组合物。 以上,熔体流动速率值为0.1〜30g / 10分钟的15〜70重量%的聚丙烯组分AII)。 和相对剂Q的0.5重量%至15重量%),所述AI),AII)和Q)的百分比称为AI),AII)和Q)的总和。

    Process for the preparation of polymer of 1-butene
    400.
    发明授权
    Process for the preparation of polymer of 1-butene 有权
    1-丁烯聚合物的制备方法

    公开(公告)号:US08227563B2

    公开(公告)日:2012-07-24

    申请号:US13262918

    申请日:2010-03-31

    Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH2═CHZ wherein Z is a C3-C20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor Wherein: R1, R2, R3 and R4, equal to or different from each other, are hydrogen atoms or C1-C20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R1, R2, R3 and R4 can be joined to form a C5-C20, saturated or unsaturated ring.

    Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法,其中α-烯烃选自式为CH2 = CHZ的乙烯,丙烯或α-烯烃,其中Z为C 3 -C 20烷基, 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下,包括:(a)固体组分,其包含Ti化合物和负载在MgCl 2上的内部电子给体化合物(b)烷基铝助催化剂; 和(c)作为外部给体的式(I)化合物,其中R 1,R 2,R 3和R 4彼此相同或不同,是氢原子或任选含有属于第13-17族的杂原子的C 1 -C 20烃基 的元素周期表; 或两个R 1,R 2,R 3和R 4可以连接形成C 5 -C 20饱和或不饱和环。

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