HIGHLY FILLED SOFT POLYOLEFIN COMPOSITION FOR ROOFING MEMBRANE
    391.
    发明申请
    HIGHLY FILLED SOFT POLYOLEFIN COMPOSITION FOR ROOFING MEMBRANE 有权
    高填充柔软的聚烯烃组合物

    公开(公告)号:US20160257809A1

    公开(公告)日:2016-09-08

    申请号:US15029470

    申请日:2014-10-01

    Abstract: The present disclosure relates to highly filled polyolefin compositions with improved balance of properties particularly for applications where puncture and tear resistance is requested comprising a flexible heterophasic polyolefin composition (I), consisting of a crystalline polymer fraction (A) consisting of a copolymer of propylene with ethylene having a fraction insoluble in xylene at 25° C. of at least 90% by weight, and an elastomeric fraction (B) consisting of a copolymer or blend of copolymers of ethylene with propylene; the copolymer or blend containing units derived from ethylene in a quantity lower than 40% by weight. The fraction soluble in xylene at 25° C. of the polyolefin composition having an IVgpc lower than 2.5 dl/g, a broad molecular weight distribution Mw/Mn (GPC) equal to or higher than 4, and a Mz/Mw (GPC) equal to or higher than 2.5. The filled polyolefin composition further comprises inorganic filler (II) and a butene-1 copolymer having: a flexural modulus (ISO 178) lower than 60 MPa, a Shore A (ISO 868) lower than 90 and a Tg (DMTA) lower than −20° C.

    Abstract translation: 本发明涉及高度填充的聚烯烃组合物,其具有改善的性能平衡,特别是对于要求穿刺和抗撕裂性的应用,包括柔性多相聚烯烃组合物(I),其由由丙烯与丙烯共聚物组成的结晶聚合物部分(A) 乙烯在25℃下不溶于二甲苯的份数为至少90重量%,和由乙烯与丙烯的共聚物或共聚物的共聚物或共混物组成的弹性体组分(B) 含有低于40重量%乙烯衍生的单元的共聚物或共混物。 具有IVgpc低于2.5dl / g,宽分子量分布Mw / Mn(GPC)等于或高于4的聚烯烃组合物在25℃下可溶于二甲苯的部分和Mz / Mw(GPC) 等于或高于2.5。 填充的聚烯烃组合物还包含无机填料(II)和丁烯-1共聚物,其弯曲模量(ISO 178)低于60MPa,肖氏A(ISO 868)低于90,Tg(DMTA)低于 - 20°C

    Polypropylene compositions containing glass fiber fillers
    392.
    发明授权
    Polypropylene compositions containing glass fiber fillers 有权
    含有玻璃纤维填料的聚丙烯组合物

    公开(公告)号:US09428637B2

    公开(公告)日:2016-08-30

    申请号:US14903000

    申请日:2014-06-24

    Abstract: The present disclosure relates to a composition comprising: (A) 30-60% by weight of a soft polyolefin composition comprising 10-50% by weight of a copolymer (a) of propylene, which contains from 1-8% by weight of comonomer; 50-90% by weight of a copolymer (b) of ethylene and other alpha-olefin(s) and from 57-80% of ethylene; where the weight ratio of the content of copolymer component (b) to the fraction XS (soluble in xylene) at room temperature (about 25° C.), both (b and XS) referred to the total weight of (a)+(b), is 1.5 or less, and the intrinsic viscosity [η] of the XS fraction is 3 dl/g or more; and the total quantity of copolymerized ethylene is 30-65% by weight; (B) 5-30% of glass fiber filler; (C) 0.5%-3% by weight of a compatibilizer; and (D) 10-40% by weight of a polypropylene component selected from propylene homopolymers, propylene copolymers containing up to 5% by moles of ethylene and/or C4-C10 α-olefin(s) and combinations of such homopolymers and copolymers, with a MFR from 0.3 to 2500 g/10 min.

    Abstract translation: 本公开内容涉及一种组合物,其包含:(A)30-60重量%的包含10-50重量%的丙烯共聚物(a)的软聚烯烃组合物,其含有1-8重量%的共聚单体 ; 50-90重量%的乙烯和其它α-烯烃的共聚物(b)和57-80%的乙烯; 其中共聚物组分(b)的含量与室温(约25℃)下的馏分XS(可溶于二甲苯)的重量比(b和XS)均指(a)+( b)为1.5以下,XS馏分的特性粘度[η]为3dl / g以上, 共聚乙烯的总量为30-65重量%; (B)5-30%的玻璃纤维填料; (C)0.5%-3%(重量)增容剂; 和(D)10-40重量%的选自丙烯均聚物的聚丙烯组分,含有至多5摩尔%乙烯和/或C 4 -C 10α-烯烃的丙烯共聚物以及这些均聚物和共聚物的组合, MFR为0.3〜2500g / 10分钟。

    Catalyst components for the polymerization of olefins
    393.
    发明授权
    Catalyst components for the polymerization of olefins 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号:US09416203B2

    公开(公告)日:2016-08-16

    申请号:US14402941

    申请日:2013-05-17

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which R2-R8 groups, equal or different to each other, are selected from hydrogen, halogen and C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N, and Si and R9 groups are selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, O, P, S, N, and Si.

    Abstract translation: 用于包含Mg,Ti的烯烃聚合的催化剂组分和其中R 2 -R 8基彼此相同或不同的下式(I)的电子给体化合物选自氢,卤素和C 1 -C 15烃基, 任选地含有选自卤素,O,P,S,N和Si的杂原子,R 9基团选自任选含有选自卤素,O,P,S,N和Si的杂原子的C 1 -C 15烃基。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    394.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化组分

    公开(公告)号:US20160208027A1

    公开(公告)日:2016-07-21

    申请号:US14917549

    申请日:2014-09-08

    CPC classification number: C08F110/06 C07C271/12 C08F4/651 C08F2500/12

    Abstract: The present technology relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the general formula (I): where R1 is selected from C1-C15 hydrocarbon groups, the R2 groups are equal to or different from each other, are hydrogen, or the R1 groups can be fused together to form one or more cycles and A is a bivalent bridging group. The catalyst components of the present disclosure exhibit high activity and stereospecificity in the polymerization of olefins.

    Abstract translation: 本技术涉及用于烯烃聚合的固体催化剂组分,包括Mg,Ti和通式(I)的电子给体:其中R1选自C1-C15烃基,R2基团等于或不同于 彼此是氢,或者R1基团可以稠合在一起形成一个或多个循环,A是二价桥连基团。 本公开的催化剂组分在烯烃聚合中表现出高的活性和立体定向性。

    PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS
    396.
    发明申请
    PROCESS FOR THE PREPARATION OF ETHYLENE POLYMERS 有权
    制备乙烯聚合物的方法

    公开(公告)号:US20150376303A1

    公开(公告)日:2015-12-31

    申请号:US14760949

    申请日:2013-12-18

    Abstract: A process for the preparation of ethylene polymers comprising polymerizing ethylene, optionally with one or more α-olefin comonomers, in the presence of:(i) a solid catalyst component comprising titanium, magnesium, halogen and optionally an internal electron-donor compound, (ii) an aluminum alkyl compound, and (iii) an antistatic compound selected among the hydroxyesters with at least two free hydroxyl groups, wherein the weight ratio of aluminum alkyl compound to solid catalyst component is higher than 0.80 and the weight ratio of antistatic compound to aluminum alkyl compound is higher than 0.10.

    Abstract translation: 一种用于制备乙烯聚合物的方法,包括在以下存在下聚合乙烯,任选与一种或多种α-烯烃共聚单体:(i)包含钛,镁,卤素和任选的内电子给体化合物的固体催化剂组分( ii)铝烷基化合物,和(iii)选自具有至少两个游离羟基的羟基酯中​​的抗静电化合物,其中烷基铝化合物与固体催化剂组分的重量比高于0.80,抗静电化合物与 铝烷基化合物高于0.10。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    399.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化组分

    公开(公告)号:US20150133289A1

    公开(公告)日:2015-05-14

    申请号:US14383838

    申请日:2013-03-05

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R1 groups are selected from C1-C15 hydrocarbon groups, R8 groups, equal or different to each other, are selected from hydrogen, halogen and C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, O, P, S, N and Si and L is a divalent hydrocarbon group optionally containing heteroatoms selected from halogen, O, P, S, N and Si.

    Abstract translation: 包含Mg,Ti和下式(I)的电子给体化合物的烯烃聚合的催化剂组分其中R1基团选自C1-C15烃基,相互相同或不同的R8基团选自氢 卤素和C 1 -C 15烃基,任选地含有选自卤素,O,P,S,N和Si的杂原子,L是任选含有选自卤素,O,P,S,N和Si的杂原子的二价烃基。

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