摘要:
Zeolitic catalysts containing framework displaced aluminum, e.g., steamed or spent catalysts, are activated by contact with aqueous fluoride solution under mild conditions. The treatment can enhance catalytic activity, ion-exchange capacity and crystallinity by replacing aluminum in the zeolitic framework.
摘要:
The present invention provides a process for modifying a crystalline aluminosilicate zeolite having a Constraint Index of from about to about 12 which comprises:(a) steaming the as synthesized crytalline aluminosilicate zeolite containing organic template material to decompose at least a portion of said template material and to extract zeolitic aluminum; and,(b) contacting the zeolite resulting from step (a) in the ammonium, alkali metal or hydrogen form with a dealuminizing agent which forms a water-soluble complex with aluminum to remove a further quantity of zeolitic aluminum therefrom wherein said treated catalyst is employed in the making of lube oil from olefins.
摘要:
An improved process for the production of unsaturated carboxylic acids and unsaturated nitriles from their corresponding C3 to C5 alkanes, or mixtures of C3 to C5 alkanes and alkenes, that involves oxidation in the presence of a supported Mo—V-based mixed metal oxide catalyst in a multi-stage reaction system which employs both separation of the oxidation product from one or more intermediate effluent streams, as well as feeding additional oxygen to reaction zones subsequent to the first reaction zone.
摘要:
A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising synthetic cryptomelane or octahedral molecular sieve. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要:
An improved single-step catalytic vapor phase (amm)oxidation process for the conversion of one or more C2-C8 alkanes to one or more oxidation products, including unsaturated carboxylic acids and unsaturated nitriles, whereby a higher yield of the oxidation products is achieved.
摘要:
Modified metal oxide catalysts are disclosed which have different chemical, physical and catalytic properties, when used for catalytic conversions of carbon based compounds, as compared to corresponding unmodified metal oxide catalysts. Methods for preparing the modified catalysts are described and their utility in catalytic process is described. Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared directly from corresponding alkanes, alkenes or alkanes and alkenes utilizing using one or more modified metal oxide catalysts.
摘要:
A catalyst useful for the gas phase oxidation of alkanes to unsaturated aldehydes or carboxylic acids is disclosed. Processes for preparing the catalyst and using the catalyst to convert alkanes to unsaturated aldehydes or carboxylic acids are also disclosed.
摘要:
A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.
摘要:
A catalyst comprising a promoted mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.