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公开(公告)号：US07767770B2
公开(公告)日：2010-08-03
申请号：US12586146
申请日：2009-09-17
申请人： Scott Han , Daniel J. Martenak , Lei Jin , Steven Lawrence Suib
发明人： Scott Han , Daniel J. Martenak , Lei Jin , Steven Lawrence Suib
CPC分类号： C07C5/42 , C07C45/50 , C07C45/75 , C07C67/343 , C07C67/38 , C07C2529/04 , Y02P20/52 , C07C11/04 , C07C47/02 , C07C47/22 , C07C69/54 , C07C69/24
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising synthetic cryptomelane or octahedral molecular sieve. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过使乙烷和氧源与包含合成铬云母或八面体分子筛的催化剂接触来制备乙烯和一氧化碳的混合物的方法。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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公开(公告)号：US20100087615A1
公开(公告)日：2010-04-08
申请号：US12586146
申请日：2009-09-17
申请人： Scott Han , Daniel J. Martenak , Lei Jin , Steven Lawrence Suib
发明人： Scott Han , Daniel J. Martenak , Lei Jin , Steven Lawrence Suib
IPC分类号： C07C67/38 , C09K3/00 , C07C69/52 , C08F120/18 , C07C45/28
CPC分类号： C07C5/42 , C07C45/50 , C07C45/75 , C07C67/343 , C07C67/38 , C07C2529/04 , Y02P20/52 , C07C11/04 , C07C47/02 , C07C47/22 , C07C69/54 , C07C69/24
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising synthetic cryptomelane or octahedral molecular sieve. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
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公开(公告)号：US20090101516A1
公开(公告)日：2009-04-23
申请号：US12212948
申请日：2008-09-18
IPC分类号： C25B3/02
CPC分类号： H01M4/8621 , C07C45/36 , H01M4/9016 , C07C49/78
摘要： The present invention relates to methods and apparatus for activation of a low reactivity, non-polar chemical compound. In one example embodiment, the method comprises introducing the low reactivity chemical compound to a catalyst. At least one of (a) an oxidizing agent or a reducing agent and (b) a polar compound is provided to the catalyst and the chemical compound. An alternating current is applied to the catalyst to produce an activation reaction in the chemical compound. This activation reaction produces a useful product. The present invention also relates to a method for oxidizing aromatic compounds by electrocatalysis to oxidized products.
摘要翻译： 本发明涉及活化低反应性非极性化合物的方法和装置。 在一个示例性实施方案中，该方法包括将低反应性化合物引入催化剂。 向催化剂和化合物提供（a）氧化剂或还原剂和（b）极性化合物中的至少一种。 向催化剂施加交流电以在化合物中产生活化反应。 该活化反应产生有用的产物。 本发明还涉及通过电化学氧化产物来氧化芳族化合物的方法。
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公开(公告)号：US07964084B2
公开(公告)日：2011-06-21
申请号：US12284337
申请日：2008-09-18
IPC分类号： C25B15/08
CPC分类号： B01J8/0221 , B01J19/087 , B01J23/002 , B01J23/06 , B01J23/34 , B01J23/42 , B01J2208/00061 , B01J2208/00168 , B01J2219/0809 , B01J2523/00 , C07C45/53 , C07C49/403 , B01J2523/23 , B01J2523/48
摘要： The present invention relates to methods and apparatus for activation of a low reactivity, non-polar chemical compound. In one example embodiment, the method comprises introducing the low reactivity chemical compound to a catalyst. At least one of (a) an oxidizing agent or a reducing agent and (b) a polar compound is provided to the catalyst and the chemical compound. An alternating current is applied to the catalyst to produce an activation reaction in the chemical compound. This activation reaction produces a useful product.
摘要翻译： 本发明涉及活化低反应性非极性化合物的方法和装置。 在一个示例性实施方案中，该方法包括将低反应性化合物引入催化剂。 向催化剂和化合物提供（a）氧化剂或还原剂和（b）极性化合物中的至少一种。 向催化剂施加交流电以在化合物中产生活化反应。 该活化反应产生有用的产物。
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5.发明申请公开(公告)号：US20090011235A1
公开(公告)日：2009-01-08
申请号：US12209252
申请日：2008-09-12
申请人： Steven Lawrence Suib , Jikang Yuan
发明人： Steven Lawrence Suib , Jikang Yuan
CPC分类号： C01G45/1221 , B01D67/0039 , B01D67/0046 , B01D67/0051 , B01D69/141 , B01D71/021 , B01D71/022 , B01D71/024 , B01D71/028 , B01D2323/08 , B01D2323/24 , B01D2325/08 , B01D2325/10 , B01J20/0222 , B01J20/06 , B01J20/28 , B01J20/28004 , B01J20/28007 , B01J20/28026 , B01J20/28033 , B01J20/28038 , B01J20/28059 , B01J20/28078 , B01J39/10 , B82Y30/00 , C01G45/12 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/16 , C01P2006/12 , C01P2006/40 , H01M4/505 , H01M2004/025 , Y10S502/524 , Y10S977/755 , Y10S977/762 , Y10S977/811 , Y10T428/298
摘要： Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves and methods of making the same are disclosed. A method for forming nanowires includes hydrothermally treating a chemical precursor composition in a hydrothermal treating solvent to form the nanowires, wherein the chemical precursor composition comprises a source of manganese cations and a source of counter cations, and wherein the nanowires comprise ordered porous manganese oxide-based octahedral molecular sieves.
摘要翻译： 公开了包含有序多孔锰氧化物基八面体分子筛的纳米线，膜和膜及其制造方法。 形成纳米线的方法包括在水热处理溶剂中水热处理化学前体组合物以形成纳米线，其中所述化学前体组合物包含锰阳离子源和抗衡阳离子源，并且其中所述纳米线包含有序多孔氧化锰 - 基于八面体分子筛。
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6.发明授权Cd-exchanged zeolite rho compositions and compositions of zeolite rho encapsulated with hydrogen made therefrom 失效Cd交换的沸石rho组合物和由其制备的氢包封的沸石的组合物
公开(公告)号：US5944876A
公开(公告)日：1999-08-31
申请号：US869691
申请日：1997-06-05
CPC分类号： B01J20/186 , C01B3/001 , C01B3/508 , F17C11/005 , Y02E60/321 , Y02E60/324 , Y10S423/31 , Y10S95/902
摘要： Novel Cd-exchanged rho compositions and compositions of zeolite rho encapsulated with hydrogen made therefrom are disclosed. The Cd-exchanged zeolite rho compositions are useful in separating and selectively removing hydrogen from hydrogen-containing process streams and storing the separated hydrogen therein. Encapsulation of hydrogen can be accomplished in large amounts even at pressures of 1 atmosphere.
摘要翻译： 公开了新颖的Cd交换的rho组合物和由其制备的氢包封的沸石的组合物。 Cd交换的沸石rho组合物可用于从含氢工艺流中分离和选择性除去氢气并将分离的氢储存在其中。 即使在1个大气压下，氢气的封装也可以大量进行。
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公开(公告)号：US07438887B2
公开(公告)日：2008-10-21
申请号：US11220340
申请日：2005-09-06
申请人： Steven Lawrence Suib , Jikang Yuan
发明人： Steven Lawrence Suib , Jikang Yuan
IPC分类号： C01G45/02 , B01D39/14 , B01D69/02 , B01D53/22 , B01D69/10 , B01D59/12 , B81B1/00 , B81B3/00 , C30B29/16 , C30B29/68 , B01J23/34 , B01J29/78 , B01J35/04
CPC分类号： C01G45/1221 , B01D67/0039 , B01D67/0046 , B01D67/0051 , B01D69/141 , B01D71/021 , B01D71/022 , B01D71/024 , B01D71/028 , B01D2323/08 , B01D2323/24 , B01D2325/08 , B01D2325/10 , B01J20/0222 , B01J20/06 , B01J20/28 , B01J20/28004 , B01J20/28007 , B01J20/28026 , B01J20/28033 , B01J20/28038 , B01J20/28059 , B01J20/28078 , B01J39/10 , B82Y30/00 , C01G45/12 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/16 , C01P2006/12 , C01P2006/40 , H01M4/505 , H01M2004/025 , Y10S502/524 , Y10S977/755 , Y10S977/762 , Y10S977/811 , Y10T428/298
摘要： Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves, and methods of making, are disclosed. A single crystal ultra-long nanowire includes an ordered porous manganese oxide-based octahedral molecular sieve, and has an average length greater than about 10 micrometers and an average diameter of about 5 nanometers to about 100 nanometers. A film comprises a microporous network comprising a plurality of single crystal nanowires in the form of a layer, wherein a plurality of layers is stacked on a surface of a substrate, wherein the nanowires of each layer are substantially axially aligned. A free standing membrane comprises a microporous network comprising a plurality of single crystal nanowires in the form of a layer, wherein a plurality of layers is aggregately stacked, and wherein the nanowires of each layer are substantially axially aligned.
摘要翻译： 公开了包含有序多孔锰氧化物基八面体分子筛的纳米线，膜和膜及其制造方法。 单晶超长纳米线包括有序的多孔锰氧化物基八面体分子筛，其平均长度大于约10微米，平均直径约5纳米至约100纳米。 膜包括微层网络，其包括多层形式的单晶纳米线，其中多个层堆叠在衬底的表面上，其中每层的纳米线基本上是轴向对准的。 独立的隔膜包括微孔网络，其包括多层形式的单晶纳米线，其中多个层聚集地堆叠，并且其中每个层的纳米线基本上是轴向对准的。
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8.发明授权
公开(公告)号：US5702674A
公开(公告)日：1997-12-30
申请号：US667487
申请日：1996-06-24
CPC分类号： C01G45/02 , C01B39/00 , C01P2002/72 , C01P2002/74 , C01P2002/77
摘要： Manganese oxide octahedral molecular sieves are provided in which a portion of the framework manganese is substituted by at least one other metal, e.g., a transition metal.
摘要翻译： 提供氧化锰八面体分子筛，其中骨架锰的一部分被至少一种其它金属例如过渡金属取代。
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公开(公告)号：US5695618A
公开(公告)日：1997-12-09
申请号：US465691
申请日：1995-06-06
申请人： Chi-Lin O'Young , Yan-Fei Shen , Mark William Simon , Steven Lawrence Suib , Richard Paul Zerger
发明人： Chi-Lin O'Young , Yan-Fei Shen , Mark William Simon , Steven Lawrence Suib , Richard Paul Zerger
CPC分类号： B01J23/34 , B01J29/04 , C07C2/84 , C07C2523/34 , C07C2529/03 , Y10S585/953
摘要： A method of oxidatively coupling methane onto a manganese oxide molecular sieve comprising: (a) passing methane through a microwave plasma activation flow reaction zone onto a manganese oxide molecular sieve, whereby polymer-free methane coupled products are produced; and, (b) recovering the polymer-free methane coupled products.
摘要翻译： 一种将甲烷氧化耦合到氧化锰分子筛上的方法，包括：（a）将甲烷通过微波等离子体活化流反应区传递到氧化锰分子筛上，由此产生无聚合物的甲烷偶合产物; 和（b）回收无聚合物的甲烷偶联产物。
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公开(公告)号：US07887778B2
公开(公告)日：2011-02-15
申请号：US12209252
申请日：2008-09-12
申请人： Steven Lawrence Suib , Jikang Yuan
发明人： Steven Lawrence Suib , Jikang Yuan
CPC分类号： C01G45/1221 , B01D67/0039 , B01D67/0046 , B01D67/0051 , B01D69/141 , B01D71/021 , B01D71/022 , B01D71/024 , B01D71/028 , B01D2323/08 , B01D2323/24 , B01D2325/08 , B01D2325/10 , B01J20/0222 , B01J20/06 , B01J20/28 , B01J20/28004 , B01J20/28007 , B01J20/28026 , B01J20/28033 , B01J20/28038 , B01J20/28059 , B01J20/28078 , B01J39/10 , B82Y30/00 , C01G45/12 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/16 , C01P2006/12 , C01P2006/40 , H01M4/505 , H01M2004/025 , Y10S502/524 , Y10S977/755 , Y10S977/762 , Y10S977/811 , Y10T428/298
摘要： Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves and methods of making the same are disclosed. A method for forming nanowires includes hydrothermally treating a chemical precursor composition in a hydrothermal treating solvent to form the nanowires, wherein the chemical precursor composition comprises a source of manganese cations and a source of counter cations, and wherein the nanowires comprise ordered porous manganese oxide-based octahedral molecular sieves.
摘要翻译： 公开了包含有序多孔锰氧化物基八面体分子筛的纳米线，膜和膜及其制造方法。 形成纳米线的方法包括在水热处理溶剂中水热处理化学前体组合物以形成纳米线，其中所述化学前体组合物包含锰阳离子源和抗衡阳离子源，并且其中所述纳米线包含有序多孔氧化锰 - 基于八面体的分子筛。
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