公开(公告)号：US20100298458A1

公开(公告)日：2010-11-25

申请号：US12524350

申请日：2008-01-30

申请人： Timothy A. Morley ,  Francois M. Casati ,  Adrian J. Birch ,  David A. Babb ,  Charles A. Martin, II

发明人： Timothy A. Morley ,  Francois M. Casati ,  Adrian J. Birch ,  David A. Babb ,  Charles A. Martin, II

IPC分类号： C08J9/00

CPC分类号： C08G18/482 ,  C08G18/5027 ,  C08G65/2624 ,  C08G2101/0025 ,  C08G2101/005

摘要： Polyether polyols are initiated with orthocyclohexanediamines such as 1,2-diaminocyclohexane. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.

摘要翻译： 聚邻位环己二胺如1,2-二氨基环己烷引发聚醚多元醇。 多元醇可用于制造刚性聚氨酯泡沫，特别是用于浇注应用的泡沫，其中它们提供低k因子和短脱模时间的良好组合。

公开(公告)号：US20100249357A1

公开(公告)日：2010-09-30

申请号：US12668609

申请日：2008-07-10

申请人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

发明人： Paul J. Popa ,  Zenon Lysenko ,  David A. Babb ,  William A. Koonce ,  Gary E. Spilman

IPC分类号： C08G18/42 ,  C08G63/00

CPC分类号： C08G18/4288 ,  C08G18/4269 ,  C08G18/4277 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/06

摘要： A polyester polyol, referred to hereinafter as a MHMS polyol comprises fatty acid based mer units wherein at least about 80 weight percent of the fatty acid based mer units are from methyl 9 (10) hydroxymethylstearate, or is prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof and which has an average hydroxyl functionality of from 1.5 to 4. A reaction product, referred to herein after as MHMS alkoxysilane prepolymer, is produced from at least one such MHMS polyol and at least one isocyanate functional silane. The prepolymer is moisture cured to form a silylated MHMS polymer. The process of preparing a MHMS polyol comprises (A) reacting a fatty acid ester wherein at least about 80 weight percent of the fatty acid esters are methyl 9 (10) hydroxymethylstearate, or are prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof with an initiator having at least 2 reactive groups selected from primary hydroxyl groups, amine groups, terminal isocyanate groups, terminal carbonyl groups or a combination thereof. The process of preparing at least one MHMS alkoxysilane prepolymer comprises steps of: (a) supplying at least one MHMS polyol; (b) supplying at least one isocyanate functional silane and (c) admixing the MHMS polyol and isocyanate functional silane or combination thereof, optionally in the presence of at least one catalyst to produce at least one MHMS alkoxysilane prepolymer. A process of preparing at least one silylated MHMS polymer comprises steps of: (a) supplying at least one MHMS alkoxysilane prepolymer; and (b) exposing it to moisture under conditions such that at least one silylated MHMS polymer is formed. Articles comprising the polyol, prepolymer, or polymer include elastomers, sealants, adhesives, coatings and the like.

公开(公告)号：US20090312450A1

公开(公告)日：2009-12-17

申请号：US11996505

申请日：2006-07-26

申请人： Charles A. Martin ,  Aaron W. Sanders ,  Jimmy D. Earls ,  Kurt D. Olson ,  John R. Briggs ,  Alan K. Schrock ,  Zenon Lysenko ,  David A. Babb

发明人： Charles A. Martin ,  Aaron W. Sanders ,  Jimmy D. Earls ,  Kurt D. Olson ,  John R. Briggs ,  Alan K. Schrock ,  Zenon Lysenko ,  David A. Babb

IPC分类号： C08G18/34 ,  C08G18/32 ,  C07C229/02

CPC分类号： C08G18/3825 ,  C07C235/08 ,  C08G18/36 ,  C08G2101/0025 ,  C08G2101/005

摘要： Polyurethanes, and rigid polyurethane foams in particular, are made using certain amides of modified fatty acids. The fatty acid groups are substituted hydroxymethyl, N-hydroxyalkyl aminoalkyl or hydroxy-substituted ester groups. The amide portion of the molecule contains hydroxyalkyl or other hydroxyl-substituted organic groups bonded to the amide nitrogen.

摘要翻译： 聚氨酯和硬质聚氨酯泡沫特别是使用某些改性脂肪酸酰胺制成的。 脂肪酸基团是取代的羟甲基，N-羟基烷基氨基烷基或羟基取代的酯基。 分子的酰胺部分含有与酰胺氮键合的羟基烷基或其它羟基取代的有机基团。

公开(公告)号：US07615658B2

公开(公告)日：2009-11-10

申请号：US10551854

申请日：2004-04-22

申请人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

发明人： Zenon Lysenko ,  Donald L. Morrison ,  David A. Babb ,  Donald L. Bunning ,  Christopher W. Derstine ,  James H. Gilchrist ,  H. Ray Jouett ,  Jeffrey S. Kanel ,  Kurt D. Olson ,  Wei-Jun Peng ,  Joe D. Phillips ,  Brian M. Roesch ,  Aaron W. Sanders ,  Alan K. Schrock ,  Pulikkottil J. Thomas

IPC分类号： C07C51/367 ,  C07C27/00

CPC分类号： C08G18/4891 ,  C07C67/31 ,  C07C67/347 ,  C07C69/675 ,  C07C69/716 ,  C07C69/732 ,  C07C69/738 ,  C08G18/4072 ,  C08G18/4804 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

摘要： An aldehyde composition derived by hydroformylation of a transesterified seed oil and containing a mixture of formyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoformyl, greater than about 1 to less than about 65 percent diformyl, and greater than about 0.1 to less than about 10 percent triformyl-substituted fatty acids or fatty acid esters, and having a diformyl to triformyl weight ratio of greater than about 5/1; preferably, greater than about 3 to less than about 20 percent saturates; and preferably, greater than about 1 to less than about 20 percent unsaturates. An alcohol composition derived by hydrogenation of the aforementioned aldehyde composition, containing a mixture of hydroxymethyl-substituted fatty acids or fatty acid esters having the following composition by weight: greater than about 10 to less than about 95 percent monoalcohol {mono(hydroxymethyl)}, greater than about 1 to less than about 65 percent diol {di(hydroxymethyl)}, greater than about 0.1 to less than about 10 percent triol, tri(hydroxymethyl)-substituted fatty acids or fatty acid esters; preferably greater than about 3 to less than about 35 percent saturates; and preferably, less than about 10 percent unsaturates. The alcohol composition can be converted into an oligomeric polyol for use in the manufacture of polyurethane slab stock flexible foam.

摘要翻译： 通过酯交换种子油的加氢甲酰化衍生的醛组合物，并含有具有以下重量组成的甲酰取代的脂肪酸或脂肪酸酯的混合物：大于约10至小于约95％的单甲基，大于约1至少 并且具有大于约65％的二甲酰基和大于约0.1至小于约10％的三甲酰基取代的脂肪酸或脂肪酸酯，并且具有大于约5/1的二甲酰基 - 三甲酰基重量比; 优选大于约3至小于约20％的饱和物; 并且优选大于约1至小于约20％的不饱和度。 通过上述醛组合物的氢化衍生的醇组合物，其含有羟甲基取代的脂肪酸或具有以下重量组成的脂肪酸酯的混合物：大于约10至小于约95％的一元醇（单（羟甲基）}， 大于约1至小于约65％的二醇{二（羟甲基）}，大于约0.1至小于约10％的三醇，三（羟甲基）取代的脂肪酸或脂肪酸酯; 优选大于约3至小于约35％的饱和物; 并且优选小于约10％的不饱和物。 醇组合物可以转化为用于制造聚氨酯板坯柔性泡沫的低聚多元醇。

公开(公告)号：US5364917A

公开(公告)日：1994-11-15

申请号：US159892

申请日：1993-12-01

申请人： David A. Babb ,  W. Frank Richey ,  Katherine S. Clement ,  Bobby R. Ezzell

发明人： David A. Babb ,  W. Frank Richey ,  Katherine S. Clement ,  Bobby R. Ezzell

IPC分类号： C07C17/26 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C07D209/48 ,  C08F16/32 ,  C08G73/10 ,  C08G73/12 ,  C10M105/54 ,  C10M107/38 ,  C08F14/18 ,  B29B7/00 ,  C08F12/20 ,  C08F5/00

CPC分类号： C07D209/48 ,  C07C17/269 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C08G73/1039 ,  C08G73/123 ,  C10M105/54 ,  C10M107/38 ,  C07C2103/18

摘要： A process for preparing a polymer having perfluorocyclobutane rings by the steps of (a) contacting monomers having aromatic polyester, aromatic polyamide, or polyimide groups or combination thereof, at least two dimerizable perfluorovinyl groups; and (b) exposing the monomers to sufficient heat and for a sufficient time that a polymer containing perfluorocyclobutane rings is formed. Chain extending oligomers of polymers having poor processing characteristics by this process results in polymers which are more easily processed. For instance, perfluorocyclobutane groups formed in an extruder to chain lengthen polyimide oligomers, in effect, render polyimides extrudable. The polymer formed by the method preferably has polyimide groups. New monomers and polymers having imide and perfluorovinyl or perfluorocyclobutane structures, respectively, are prepared.

摘要翻译： 通过以下步骤制备具有全氟环丁烷环的聚合物的方法：（a）使具有芳族聚酯，芳族聚酰胺或聚酰亚胺基团的单体或其组合使至少两个可二聚的全氟乙烯基接触; 和（b）将单体暴露于足够的热量并持续足够的时间，形成含有全氟环丁烷环的聚合物。 通过该方法具有差加工特性的聚合物链延伸低聚物导致更容易加工的聚合物。 例如，在挤出机中形成的支链延长聚酰亚胺低聚物的全氟环丁烷基团实际上使聚酰亚胺可挤出。 通过该方法形成的聚合物优选具有聚酰亚胺基团。 分别制备具有酰亚胺和全氟乙烯基或全氟环丁烷结构的新单体和聚合物。

公开(公告)号：US5159037A

公开(公告)日：1992-10-27

申请号：US720553

申请日：1991-06-25

申请人： Katherine S. Clement ,  David A. Babb ,  Bobby R. Ezzell

发明人： Katherine S. Clement ,  David A. Babb ,  Bobby R. Ezzell

IPC分类号： C07C17/26 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C10M105/54 ,  C10M107/38

CPC分类号： C10M107/38 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C10M105/54 ,  C07C2103/18

摘要： The present invention is a process for preparing a polymer having perfluorocyclobutane rings by the steps of (a) contacting monomers having at least two dimerizable perfluorovinyl groups; and (b) exposing the monomers to sufficient heat and for a sufficient time that a polymer containing perfluorocyclobutane rings is formed wherein at least about 0.05 mole percent of the monomer, have at least 3 dimerizable perfluorovinyl groups and polymers prepared thereby.

摘要翻译： 本发明是通过以下步骤制备具有全氟环丁烷环的聚合物的方法：（a）使具有至少两个可二聚的全氟乙烯基的单体接触; 和（b）将单体暴露于足够的热量和足够的时间，形成含有全氟环丁烷环的聚合物，其中至少约0.05摩尔％的单体具有至少3个可二聚的全氟乙烯基和由此制备的聚合物。

公开(公告)号：US5159036A

公开(公告)日：1992-10-27

申请号：US673884

申请日：1991-03-22

申请人： David A. Babb

发明人： David A. Babb

IPC分类号： C07C17/26 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C10M105/54 ,  C10M107/38

CPC分类号： C10M107/38 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C10M105/54 ,  C07C2103/18

摘要： A crosslinked polymer having perfluorocyclobutane rings is prepared in a process comprising the steps of: (a) contacting monomers having two dimerizable perfluorovinyl groups; (b) exposing the monomers to sufficient heat and for a sufficient time that a (linear) polymer containing perfluorocyclobutane rings is formed; and (c) exposing the polymer to sufficient crosslinking initiating means and for a sufficient time such that crosslinking occurs. Crosslinked polymers, so prepared are novel and have tensile strength and other physical properties enhanced over the properties of the corresponding linear polymer.

摘要翻译： 制备具有全氟环丁烷环的交联聚合物的方法包括以下步骤：（a）使具有两个可二聚的全氟乙烯基的单体接触; （b）将单体暴露于足够的热量并持续足够的时间，形成含有全氟环丁烷环的（直链）聚合物; 和（c）将聚合物暴露于足够的交联引发装置并持续足够的时间使得发生交联。 如此制备的交联聚合物是新颖的，并且相对于相应的线性聚合物的性能具有增强的拉伸强度和其它物理性能。

公开(公告)号：US5037918A

公开(公告)日：1991-08-06

申请号：US451404

申请日：1989-12-15

申请人： David A. Babb

发明人： David A. Babb

IPC分类号： C07C17/26 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C10M105/54 ,  C10M107/38

CPC分类号： C10M107/38 ,  C07C43/17 ,  C07C43/225 ,  C07C65/21 ,  C07C65/24 ,  C08F16/32 ,  C10M105/54 ,  C07C2103/18

摘要： A crosslinked polymer having perfluorocyclobutane rings is prepared in a process comprising the steps of: (a) contacting monomers having two dimerizable perfluorovinyl groups; (b) exposing the monomers to sufficient heat and for a sufficient time that a (linear) polymer containing perfluorocyclobutane rings is formed; and (c) exposing the polymer to sufficient crosslinking initiating means and for a sufficient time such that crosslinking occurs. Crosslinked polymers, so prepared are novel and have tensile strength and other physical proeprties enhanced over the properties of the corresponding linear polymer.

摘要翻译： 制备具有全氟环丁烷环的交联聚合物的方法包括以下步骤：（a）使具有两个可二聚的全氟乙烯基的单体接触; （b）将单体暴露于足够的热量并持续足够的时间，形成含有全氟环丁烷环的（直链）聚合物; 和（c）将聚合物暴露于足够的交联引发装置并持续足够的时间使得发生交联。 如此制备的交联聚合物是新颖的，并且具有比相应的线性聚合物的性能增强的拉伸强度和其它物理性能。

公开(公告)号：US09725559B2

公开(公告)日：2017-08-08

申请号：US14849538

申请日：2015-09-09

申请人： Carlos M. Villa ,  Jean-Paul Masy ,  Ricco B. Borella ,  David A. Babb ,  Flor A. Castillo

发明人： Carlos M. Villa ,  Jean-Paul Masy ,  Ricco B. Borella ,  David A. Babb ,  Flor A. Castillo

IPC分类号： C08G65/12 ,  C08G65/26 ,  C08G18/32 ,  C08L71/02 ,  C08G18/18 ,  C08G18/24 ,  C08G18/48 ,  C08G18/76 ,  C08G101/00

CPC分类号： C08G65/12 ,  C08G18/18 ,  C08G18/24 ,  C08G18/3203 ,  C08G18/4833 ,  C08G18/4845 ,  C08G18/485 ,  C08G18/7621 ,  C08G65/2609 ,  C08G65/2624 ,  C08G2101/0008 ,  C08L71/02

摘要： Copolymers of propylene oxide and ethylene oxide have an inner block that contains from 65-90 weight percent oxyethylene units and from 10 to 35 weight percent oxypropylene units. This block has a molecular weight of from 150 to 350. The copolymer has an outer block which contains at least 95 weight % oxypropylene units and from 0 to 5% oxyethylene units. The equivalent weight of the copolymer is from 800 to 2000. The copolymers are useful in making polyurethane foams that have unexpectedly high tensile and/or tear strengths.

公开(公告)号：US09556309B2

公开(公告)日：2017-01-31

申请号：US14694258

申请日：2015-04-23

申请人： David S. Laitar ,  David A. Babb ,  Carlos M. Villa ,  Richard Keaton ,  Jean-Paul Masy

发明人： David S. Laitar ,  David A. Babb ,  Carlos M. Villa ,  Richard Keaton ,  Jean-Paul Masy

IPC分类号： C08G59/68 ,  C08G65/26 ,  C08G65/34 ,  C07C41/01 ,  C07C41/02 ,  C08G65/00

CPC分类号： C08G65/2663 ,  C07C41/01 ,  C07C41/02 ,  C08G65/269 ,  C08G65/34

摘要： Alkylene oxide polymerizations are performed in the presence of a double metal cyanide polymerization catalyst and certain magnesium, Group 3-Group 15 metal or lanthanide series metal compounds. The presence of the magnesium, Group 3-Group 15 metal or lanthanide series metal compound provides several benefits including more rapid catalyst activation, faster polymerization rates and the reduction in the amount of ultra high molecular weight polymers that are formed. The catalyst mixture is unexpectedly useful in making polyethers having low equivalent weights.

摘要翻译： 在双金属氰化物聚合催化剂和某些镁，第3族第15族金属或镧系金属化合物的存在下进行环氧烷聚合反应。 镁，第3族 - 第15族金属或镧系金属化合物的存在提供了几个益处，包括更快速的催化剂活化，更快的聚合速率和所形成的超高分子量聚合物的量的减少。 催化剂混合物意外地用于制备具有低当量重量的聚醚。