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    Use of a Catalyst Comprising a Phosphorous Modified Zeolite in an Alcohol Dehydration Process
    46.
    发明申请
    Use of a Catalyst Comprising a Phosphorous Modified Zeolite in an Alcohol Dehydration Process 有权
    在醇脱水过程中使用包含磷改性沸石的催化剂

    公开(公告)号：US20140243570A1

    公开(公告)日：2014-08-28

    申请号：US14236726

    申请日：2012-07-25

    申请人： Nikolai Nesterenko ,  Delphine Minoux ,  Cindy Adam ,  Jean-Pierre Dath ,  Joseph Lopez ,  Patrick Euzen

    发明人： Nikolai Nesterenko ,  Delphine Minoux ,  Cindy Adam ,  Jean-Pierre Dath ,  Joseph Lopez ,  Patrick Euzen

    IPC分类号： C07C1/24

    CPC分类号： C07C1/24 ,  B01J29/40 ,  B01J29/85 ,  B01J37/10 ,  B01J37/28 ,  C07C2527/14 ,  C07C2529/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/04

    摘要： A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.

    摘要翻译： 催化剂可用于将脱水过程中的醇转化为具有与醇相同数目的碳原子的烯烃。 催化剂可以包括通过在结构中提供具有至少一个十元环的沸石而制成的磷改性沸石，蒸煮沸石，将沸石与粘合剂和成型添加剂混合，以及成型沸石。 可以进行离子交换步骤，并且可以蒸成型催化剂。 磷可以以至少0.1重量％的量引入催化剂上，例如通过干浸渍或化学气相沉积。 可以引入金属。 可以将催化剂洗涤和/或煅烧，并在平衡步骤中蒸煮。 蒸汽浓度（X）可以至少约为2.催化剂可以在高于625℃的温度下蒸煮，例如700-800℃的温度。

    Process for Making Crystalline Metallosilicates
    47.
    发明申请
    Process for Making Crystalline Metallosilicates 审中-公开
    制备结晶金属硅酸盐的方法

    公开(公告)号：US20110190561A1

    公开(公告)日：2011-08-04

    申请号：US12994561

    申请日：2009-02-24

    申请人： Metin Bulut ,  Pierre Jacobs ,  Delphine Minoux ,  Nikolai Nesternko ,  Jean-Pierre Dath ,  Sander Van Donk

    发明人： Metin Bulut ,  Pierre Jacobs ,  Delphine Minoux ,  Nikolai Nesternko ,  Jean-Pierre Dath ,  Sander Van Donk

    IPC分类号： C07C1/20 ,  C01B39/00 ,  C01B39/02

    CPC分类号： B01J29/40 ,  B01J2229/62 ,  C01B37/005 ,  C01B39/02 ,  C01B39/04 ,  C01B39/38 ,  C01B39/40 ,  C07C2/864 ,  C07C2529/70 ,  C10G29/205 ,  Y02P20/52 ,  C07C15/08

    摘要： The present invention relates to a process for making a crystalline metallosilicate composition comprising crystallites having an inner part (the core) and an outer part (the outer layer or shell) such that: the ratio Si/metal is higher in the outer part than in the inner part, the crystallites have a continuous distribution of metal and silicon over the crystalline cross-section, said process comprising: a) providing an aqueous medium comprising OH— anions and a metal source, b) providing an aqueous medium comprising an inorganic source of silicon and optionally a templating agent, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallyze the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is

    摘要翻译： 本发明涉及一种制备结晶金属硅酸盐组合物的方法，其包含具有内部部分（芯部）和外部部分（外层或外壳）的微晶，使得：外部部分的Si /金属比例高于 所述内部部分，所述微晶在结晶截面上具有金属和硅的连续分布，所述方法包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机源的水性介质 的硅和任选的模板剂，c）任选地提供包含任选的二氧化硅有机源的非水性液体培养基，d）在有效地使所需的金属硅酸盐水解的条件下，将培养基a），b）和任选的c） ）回收所需的金属硅酸盐，其中在混合物a）+ b）+ c）中，在结晶之前，Si org / Si无机物的比例<0.3，有利地<0.2，优选为0，摩尔浓度 tio OH- / SiO 2为至少0.3，有利地为0.3至0.62，优选为0.31至0.61，更优选为0.32至0.61，非常优选为0.33至0.6，混合物a）+ b）+ c）， 在结晶之前，高于13，优选高于13.1，更优选高于13.2，还更优选高于13.3，最优选高于13.4。

    Use of Phosphorus Modified Molecular Sieves in Conversion of Organics to Olefins
    48.
    发明申请
    Use of Phosphorus Modified Molecular Sieves in Conversion of Organics to Olefins 有权
    使用磷改性分子筛将有机物转化为烯烃

    公开(公告)号：US20100261944A1

    公开(公告)日：2010-10-14

    申请号：US12671220

    申请日：2008-07-28

    申请人： Nikolai Nesterenko ,  Walter Vermeire ,  Delphine Minoux ,  Sander Van Donk

    发明人： Nikolai Nesterenko ,  Walter Vermeire ,  Delphine Minoux ,  Sander Van Donk

    IPC分类号： C07C1/00

    CPC分类号： C07C1/20 ,  B01J29/40 ,  B01J37/28 ,  B01J2229/18 ,  B01J2229/37 ,  C07C1/322 ,  C07C4/06 ,  C07C2529/85 ,  C10G2400/20 ,  Y02P30/42 ,  C07C11/02

    摘要： The present invention relates to a process to make light olefins, in a combined XTO−OCP process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor with a catalyst made of a P-modified zeolite (A) at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said P-modified zeolite (A) is made by a process comprising in that order: selecting a zeolite (advantageously with Si/Al ratio between 4 and 500) among H+ or NH4+-form of MFI, MEL, FER, MOR, clinoptilolite; introducing P at conditions effective to introduce advantageously at least 0.05 wt % of P; separation of the solid from the liquid if any; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.

    摘要翻译： 本发明涉及一种在组合的XTO-OCP方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：使含氧的含卤素或含硫的 在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下，使用具有P型改性沸石（A）的催化剂在XTO反应器中的有机原料; 将所述轻质烯烃与所述重质烃馏分分离; 在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下，使所述OCP反应器中的所述重质烃馏分与由P-改性沸石（A）制成的催化剂接触; 其中所述P-改性沸石（A）通过以下顺序制备：在MFI，MEL，FER，MOR，斜发沸石的H +或NH4 +形式中选择沸石（有利地为Si / Al比在4和500之间） ; 在有效引入至少0.05重量％的P的条件下引入P; 从液体中分离出固体物质; 任选的洗涤步骤或任选的干燥步骤或任选的干燥步骤，随后进行洗涤步骤; 煅烧步骤。

    PRODUCTION OF PROPYLENE VIA SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS FOLLOWED BY METATHESIS
    49.
    发明申请
    PRODUCTION OF PROPYLENE VIA SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS FOLLOWED BY METATHESIS 有权
    通过METATHESIS的酸性催化剂同时脱水和异构异丙醇生产丙烯

    公开(公告)号：US20130245348A1

    公开(公告)日：2013-09-19

    申请号：US13583990

    申请日：2011-03-15

    申请人： Walter Vermeiren ,  Cindy Adam ,  Delphine Minoux

    发明人： Walter Vermeiren ,  Cindy Adam ,  Delphine Minoux

    IPC分类号： C07C1/24

    CPC分类号： C07C1/24 ,  C07C5/2506 ,  C07C5/2708 ,  C07C6/04 ,  C07C7/14866 ,  C07C7/14891 ,  C07C7/177 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2523/75 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/127 ,  Y02P20/52 ,  C07C11/06 ,  C07C11/09 ,  C07C11/08

    摘要： The present invention relates to a process for the production of propylene in which in a first step isobutanol is subjected to a simultaneous dehydration and skeletal isomerisation to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene and in a second step n-butenes are subjected to methathesis, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerase at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, d) fractionating said mixture to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recycled with stream (A) to the dehydration/isomerization reactor of step b), e) sending the stream (N) to a methathesis reactor and contacting stream (N) with a catalyst in said methathesis reactor, optionally in the presence of ethylene, at conditions effective to produce propylene, f) recovering from said methathesis reactor a stream (P) comprising essentially propylene, unreacted n-butenes, heavies, optionally unreacted ethylene, g) fractionating stream (P) to recover propylene and optionally recycling unreacted n-butenes and unreacted ethylene to the methathesis reactor.

    摘要翻译： 本发明涉及一种生产丙烯的方法，其中在第一步中异丁醇同时进行脱水和骨架异构化以制备具有相同数目的碳的基本上相应的烯烃并且基本上由正丁烯的混合物组成 所述方法包括：a）在反应器中引入包含异丁醇，任选的水，任选的惰性组分的物流（A），b）使所述物流与一种或多种异丁烯接触， 催化剂在所述反应器中有效脱水和骨架异构酶至少一部分异丁醇以形成正丁烯和异丁烯的混合物，c）从所述反应器回收流（B），除去水，惰性组分 如果有任何和未转化的异丁醇，以获得正丁烯和异丁烯的混合物，d）分馏所述混合物以产生正丁烯流（N）并除去主要部分 任选地将物流（A）循环到步骤b）的脱水/异构化反应器中的芸香素，e）将所述物流（N）送入复分解反应器并将所述（N）与所述复分解反应器中的催化剂接触，任选地在 乙烯，在有效产生丙烯的条件下，f）从所述复分解反应器回收包含基本上丙烯，未反应的正丁烯，重质，任选未反应的乙烯的流（P），g）分馏流（P）以回收丙烯并任选地循环未反应 正丁烯和未反应的乙烯。