摘要:
A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.
摘要:
A rubber composition for a tire containing (i) 100 parts by weight of a diene-based rubber and (ii) 0.5 to 25 parts by weight of a heat-expandable microcapsule including a shell, and a substance capable of vaporizing or expanding under heating to thereby generate a gas and a nonpolar oil, both encapsulated in the shell,wherein the shell is made of a thermoplastic resin obtained by polymerization of a nitrile-based monomer (I), a monomer (II) having an unsaturated double bond and a carboxyl group in the molecule thereof, an optional monomer (III) having two or more polymerizable double bonds, and an optional copolymerizable monomer (IV) for adjusting the expansion properties.
摘要:
The present invention is concerned with a vinyl polymer having at least one group of the general formula (1) per molecule at the molecular chain terminus. -Z-R—CR1═CR2R3 (1) wherein Z represents an oxygen atom, a sulfur atom, a group of the formula NR′, R′ represents a univalent hydrocarbon group containing 1 to 20 carbon atoms, or a bivalent organic group containing 1 to 20 carbon atoms, and R represents a carbonyl group, a direct bond or a bivalent organic group containing 1 to 20 carbon atoms; R1 and R2 are the same or different and each represents a hydrogen atom or a univalent organic group group containing 1 to 20 carbon atoms, and R3 represents an organic group containg 1 to 20 carbon atoms. The present invention is further concerned with a curable composition comprising the above vinyl polymer.
摘要:
The present invention provides: a process for preparing a vinyl polymer containing a halogen in an amount of 1,000 mg or less per kilogram, in which a vinyl polymer containing the halogen produced by atom transfer radical polymerization of a vinyl monomer is heated at a temperature in the range of 140 to 250° C. to dehalogenate the vinyl polymer; a vinyl polymer obtained by the process; and a hydrosilylation-reactive curable composition containing the vinyl polymer.
摘要:
A positioning device comprising a moving portion provided with a pair of magnets arranged respectively along with a first axis and a second axis, a fixed portion provided to face to the moving portion, and a voice coil motor (VCM) for relatively driving the moving portion and the fixed portion by an electromagnetic action between a coil and a drive magnet provided to each of the moving portion and the fixed portion: wherein one of the magnets is arranged so as to reduce a rotation moment generated by an electromagnetic connection between the other magnet and the voice coil motor.
摘要:
The present invention relates to a vinyl polymer terminated in a silanol group, a hydrolyzable silyl group or an acrylic functional group, to a method of producing a vinyl polymer having a hydrolyzable silyl group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound having two or more silicon atom-bound hydrolyzable groups, and a method of producing a vinyl polymer having an acrylic functional group at one or more termini thereof which comprises reacting a vinyl polymer having a silanol group at one or more termini thereof with a silicon compound represented by the general formula (3): XSiR2-G-O—C(O)C(L)=CH2 (3) wherein X is a hydrolyzable group.
摘要:
A vinyl polymer having, at a molecular chain terminus, a structure represented by the general formula 1: (wherein R3 is a hydroxy, amino, epoxy, carboxylic acid, ester, ether, amide or silyl group, an alkenyl group having low polymerizability, an organic compound having 1 to 20 carbon atoms, X is a halogen atom, a nitroxide or sulfide group or a cobalt porphyrin complex).
摘要:
An alkenyl- or crosslinkable silyl-terminated vinyl polymer is provided. Such a functional group is introduced into its terminus at a high ratio, not via sulfur atoms. Those polymers can be prepared by polymerizing a vinyl monomer for obtaining a halogen-terminated vinyl polymer, and then substituting an oxy anion or carbanion having such a functional group for the terminal halogen of said polymer.
摘要:
The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living-radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition-having an epoxy group at a main chain terminus thereof.
摘要:
This invention is related to a production method of a branched polymer which comprises polymerizing a macromonomer [I], said macromonomer [I] being a vinyl polymer obtainable by radical polymerization and terminally having one polymerizable carbon-carbon double bond-containing group per molecule. Furthermore, by producing the macromonomer by living radical polymerization, in particular atom transfer radical polymerization, it becomes possible to produce the above polymers or gels having a well controlled side chain molecular weights.