摘要:
The invention concerns a catalyst comprising at least one matrix, at least one dioctahedral 2:1 phyllosilicate which is optionally synthesized in a fluorine-containing medium and optionally bridged, at least one metal selected from elements from group VIB and/or group VIII of the periodic table, boron and/or silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also concerns the use of the catalyst for hydrocracking hydrocarbon-containing feeds.
摘要:
The invention provides a hydrocracking catalyst comprising at least one mineral matrix, at least one beta zeolite, at least one group VB element or at least one mixed sulphide phase comprising sulphur, optionally at least one group VIB or group VIII element, optionally at least one element selected from the group formed by silicon, boron or phosphorous, and optionally at least one group VIIA element.
摘要:
The invention concerns a process for selective hydroisomerization of compounds with an n-alkane chain containing more than 10 carbon atoms, in which the compound to be treated is brought into contact with a catalyst comprising at least one hydro-dehydrogenating element and at least one molecular sieve having a one- or two-dimensional pore network, the accessible pore openings of which are delimited by 10 oxygen atoms, and a distance termed the bridging distance between the pores of less then 0.70 nm, and the zeolite is such that a catalyst which undergoes a standard n-heptadecane isomerization test has, for a conversion of 95%, a selectivity of at least 70% for isomerized products, and the catalyst contains at least 5% by weight of at least one hydro-dehydrogenating element selected from the group formed by non noble GVIII metals, GVIB metals, and niobium, and the catalyst preferably contains phosphorous. The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.
摘要:
The invention provides a hydrocracking catalyst comprising at least one NU-88 zeolite, at least one group VB metal, preferably niobium, at least one amorphous or low crystallinity matrix, optionally at least one metal selected from the group formed by group VIB and VIII metals, optionally at least one element selected from the group formed by phosphorous, boron and silicon, and optionally at least one group VIIA element. The invention also relates to the use of the catalyst for hydrocracking hydrocarbon-containing feeds.
摘要:
The invention concerns a hydrocracking catalyst comprising at least one amorphous or poorly crystallised matrix of oxide type, at least one element from group VB, preferably niobium, at least one zeolite selected from the group formed by zeolites NU-85, NU-86 and NU-87, and at least one element selected among boron and silicon, optionally P, optionally at least one element selected from the elements from group VIB and group VIII, and/or optionally at least one element from group VIIA. The invention also concerns the use of that catalyst in the hydrocracking of hydrocarbon charges.
摘要:
An NU-88 zeolite and a hydrocracking catalyst comprising at least one matrix, a NU-88 zeolite, at least one group VIB or VII metal, a phosphorous, boron or silicon promoter, optionally at least one group VIIA element, and optionally at least one group VIIB element, and also the use of the catalyst for hydrocracking hydrocarbon feeds.
摘要:
The invention concerns NU-88 zeolite, characterized by:i) a chemical composition with the following formula, expressed in terms of the mole ratios of the oxides for the anhydrous state:100 XO.sub.2, mY.sub.2 O.sub.3, pR.sub.2/n Owherem is 10 or less;p is 20 or less;R represents one or more cations with valency n;X represents silicon and/or germanium;Y represents one or more of the following elements: aluminium, iron, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese; andii) an X ray diffraction diagram, in its as synthesized state, which comprises the results shown in Table 1 of the description.The invention also concerns the preparation of the zeolite, any catalyst containing the zeolite and any catalytic process using such a catalyst.
摘要:
The present invention concerns a process for the acylation of an aromatic ether.Preferably the invention relates to a process for the acylation of a substituted aromatic ether, in particular veratrol.The acylation process of the invention consists of reacting the ether with an acylation agent in the presence of a zeolitic catalyst, and is characterized in that the acylation reaction is carried out in the presence of an effective quantity of a catalyst comprising a faujasite type zeolite or a Y zeolite with the following physico-chemical characteristics:an atomic ratio denoted "global Si/Me.sup.1 " between the number of atoms of the element silicon and the number of atoms of every trivalent element Me.sup.1 contained in the zeolite in the range 2.4 to 90, preferably in the range 2.4 to 75, and more preferably in the range 2.4 to 60;an Me.sup.2 alkali metal content such that the atomic ratio Me.sup.2 /Me.sup.1(IV) between the number of atoms of alkali metal Me.sup.2 and the number of atoms of every trivalent element Me.sup.1(IV) included in the zeolitic network is less than 0.2, preferably less than 0.1, and more preferably less than 0.05.
摘要:
A phosphorous-containing zeolite with structural type CON in its aluminosilicate or borosilicate form contains at most 10% by weight of phosphorous. A process for its preparation is described, starting from existing zeolites (SSZ-26, SSZ-33 or CIT-1) or from beta zeolites and an organic structuring agent or template which is 1-N,N,N-trimethyl adamantammonium hydroxide or 2-N,N,N-trimethyl adamantammonium hydroxide. The zeolite is used for catalytic cracking of hydrocarbon feeds.
摘要:
A catalyst comprising at least one catalytic element, and a support comprising 20-99% by weight of at least one matrix, 1-80% by weight of at least one 2:1 trioctahedral phyllosilicate containing fluorine and 0-30% by weight of at least one Y zeolite, in which the catalytic element is from groups VI and/or VIII, and phosphorous can be present, as well as a process for the hydroconversion of petroleum with said catalyst.