摘要:
Methods for generating a color image are provided which include a multi-layer construction in which at least one of the layers is a thermally activatable layer that includes a thermally activatable composition. The thermally activatable composition includes a non-linear light to heat converter composition and a color forming compound. Upon activation with a light source an image forms.
摘要:
A process for making a microlens array or a microlens array masterform comprises (a) providing a photoreactive composition, the photoreactive composition comprising (1) at least one reactive species that is capable of undergoing an acid- or radical-initiated chemical reaction, and (2) at least one multiphoton photoinitiator system; and (b) imagewise exposing at least a portion of the composition to light sufficient to cause simultaneous absorption of at least two photons, thereby inducing at least one acid- or radical-initiated chemical reaction where the composition is exposed to the light, the imagewise exposing being carried out in a pattern that is effective to define at least the surface of a plurality of microlenses, each of the microlenses having a principal axis and a focal length, and at least one of the microlenses being an aspherical microlens.
摘要:
Translucent, transparent, or semi-translucent microlens sheetings with composite images are disclosed, in which a composite image floats above or below the sheeting, or both. The composite image may be two-dimensional or three-dimensional. The sheeting may have at least one layer of material having a surface of microlenses that form one or more images at positions internal to the layer of material, at least one of the images being a partially complete image. Additional layers, such as retroreflective, translucent, transparent, or optical structure layers may also be incorporated into the sheeting.
摘要:
Translucent, transparent, or semi-translucent microlens sheetings with composite images are disclosed, in which a composite image floats above or below the sheeting, or both. The composite image may be two-dimensional or three-dimensional. The sheeting may have at least one layer of material having a surface of microlenses that form one or more images at positions internal to the layer of material, at least one of the images being a partially complete image. Additional layers, such as retroreflective, translucent, transparent, or optical structure layers may also be incorporated into the sheeting.
摘要:
A reflective film includes interior layers that selectively reflect light by constructive or destructive interference, the layers extending from a first to a second zone of the film. In the first zone the layers provide a first reflective polarizer characteristic, and in a second zone the layers provide a substantially different reflective polarizer characteristic. The second zone is characterized by at least some of the layers having a reduced birefringence relative to their birefringence in the first zone. In some cases the first reflective polarizer characteristic may have a pass axis that is substantially orthogonal to that of the second reflective polarizer characteristic. The film may have substantially the same thickness in the first and second zones, or a substantially reduced thickness in the second zone relative to the first zone.
摘要:
Multi-layer articles are described that are capable of forming color images. The articles include at least six layers, four thermally activatable layers (layers 1-4) and two blocking layers (layer 5 and 6). The layers are arranged such that layer 5 is disposed between layers 1 and 2 and layer 6 is disposed between layers 3 and 4. Thermally activatable layers 1 and 2 are activatable upon exposure to light of a first write wavelength, and blocking layer 5 is adapted to at least partially block light of the first write wavelength. Thermally activatable layers 3 and 4 are activatable upon exposure to light of a second write wavelength, and blocking layer 6 is adapted to at least partially block light of the second write wavelength. At least one, and possibly all of the thermally activatable layers include a light to heat convertor composition and a color changing compound. Some of the thermally activatable layers may be a group of layers arranged to selectively reflect light by constructive or destructive interference to provide a first reflective characteristic, the group of layers also having a first absorption characteristic suitable to, upon exposure to light comprising a write wavelength, absorptively heat the first group of layers by an amount sufficient to change the first reflective characteristic to a second reflective characteristic while maintaining the structural integrity of the group of layers.
摘要:
A reflective film includes interior layers arranged to selectively reflect light by constructive or destructive interference, the layers extending from a first zone to a second zone of the film. The film has a first thickness and the interior layers provide a first reflective characteristic in the first zone; the film has a second thickness and the interior layers provide a second reflective characteristic in the second zone. The difference between the first and second reflective characteristics is not substantially attributable to any difference between the first and second thicknesses, which difference may be zero. Rather, the difference in the reflective characteristics is substantially attributable to reduced birefringence of at least some of the interior layers in one zone relative to the other zone. The film may also incorporate absorbing agents to assist in the manufacture or processing of the film. Related methods and articles are also disclosed.
摘要:
A method for building three-dimensional articles using a thermal polymerization process in provided. The articles are built by using a composition that includes a thermally polymerizable composition, a thermal initiator, and a nonlinear light-to-heat conversion material such as a reverse saturable dye. The article is built by the sequential exposure of adjacent voxels with a laser beam. Microlens arrays can be used to expose more than one voxel at a time.
摘要:
A method for forming a color shifting film on a support, the film comprising a reflective stack disposed adjacent to the support and an image is disclosed. The reflective stack comprises an at least partially transparent spacer layer comprising a substituted acrylamide polymer disposed between a partially reflective first layer and a reflective second layer. The acrylamide layer has a thickness sufficient to produce an interference color.
摘要:
A reflective film includes interior layers that selectively reflect light by constructive or destructive interference, the layers extending from a first to a second zone of the film. In the first zone the layers provide a first reflective polarizer characteristic, and in a second zone the layers provide a substantially different reflective polarizer characteristic. The second zone is characterized by at least some of the layers having a reduced birefringence relative to their birefringence in the first zone. In some cases the first reflective polarizer characteristic may have a pass axis that is substantially orthogonal to that of the second reflective polarizer characteristic. The film may have substantially the same thickness in the first and second zones, or a substantially reduced thickness in the second zone relative to the first zone.