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41.发明授权Catalyst, method of preparation and use thereof in hydrodesulfurizing cracked naphtha 失效催化剂，其制备方法及其在加氢脱硫裂化石脑油中的应用
公开(公告)号：US4203829A
公开(公告)日：1980-05-20
申请号：US946573
申请日：1978-09-28
申请人： Ralph J. Bertolacini
发明人： Ralph J. Bertolacini
IPC分类号： B01J21/10 , B01J23/85 , B01J23/882 , B01J27/047 , B01J35/00 , B01J35/10 , B01J37/04 , C10G45/08 , C10G23/02 , B01J23/88
CPC分类号： B01J23/8872 , B01J23/85 , C10G45/08 , B01J21/10 , B01J23/882 , B01J35/0006 , B01J35/10 , B01J35/1014 , B01J35/1038 , B01J35/1061
摘要： Catalyst comprising magnesium oxide and aluminum oxide is prepared by dry blending particulate alumina with a dried composite of magnesia impregnated with hydrogenation metals of Group VIB and Group VIII; the catalyst is employed in selective hydrodesulfurization of cracked naphtha.
摘要翻译： 包含氧化镁和氧化铝的催化剂通过将颗粒氧化铝与浸渍有VIB族和VIII族的氢化金属的氧化镁的干燥复合物干混合来制备; 催化剂用于裂化石脑油的选择性加氢脱硫。
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42.发明授权Process for the selective desulfurization of cracked naphthas with magnesia-containing catalyst 失效用含氧化镁催化剂选择性脱硫裂化石脑油的工艺
公开(公告)号：US4140626A
公开(公告)日：1979-02-20
申请号：US820376
申请日：1977-07-29
CPC分类号： B01J23/85 , C10G2400/02
摘要： The process comprises contacting a cracked naphtha in a reaction zone under hydrodesulfurization conditions and in the presence of hydrogen with a catalyst comprising a hydrogenation component comprising a Group VIB metal and a Group VIII metal deposited on a solid support comprising magnesium oxide. The catalyst support may also comprise a refractory inorganic oxide, such as alumina. In the latter case, the catalyst support should contain at least 70 wt.% magnesium oxide to furnish a satisfactory embodiment of the catalyst.
摘要翻译： 该方法包括在加氢脱硫条件下和在氢气存在下使反应区中的裂化石脑油与包含沉积在包含氧化镁的固体载体上的包含VIB族金属和VIII族金属的氢化组分的催化剂接触。 催化剂载体还可以包含耐火无机氧化物，例如氧化铝。 在后一种情况下，催化剂载体应含有至少70重量％的氧化镁，以提供催化剂的令人满意的实施方案。
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公开(公告)号：US4122096A
公开(公告)日：1978-10-24
申请号：US817986
申请日：1977-07-22
IPC分类号： B01J23/22 , B01J27/198 , B01J37/16 , B01J37/18 , C07C51/215 , C07D307/60
CPC分类号： B01J37/18 , B01J23/22 , B01J27/198 , B01J37/16 , C07C51/215
摘要： A catalytic composition is produced by reacting in an aqueous medium, vanadium and phosphorus compounds together with a hydrogen halide and removing liquid from the resulting reactants to form a solid which in an improved manner is heated at a temperature of about less than 470.degree. C. to effect liberation of water of hydration from the solid and thereafter contacting with a reducing material selected from the group of carbon monoxide, hydrogen and hydrogen sulfide at a temperature of from about 300.degree. to about 600.degree. C. and in the substantial absence of gaseous oxygen other than that liberated from the solid. The specific reduction step as taught and claimed herein improves catalyst activity performance by increasing the catalyst conversion and selectivity to a desired oxygenated product, and the ultimate yield of the oxygenated product per quantity of feed component converted. It also minimizes formation of inactive VPO.sub.5, improves the strength of pellets and reduces the residual chloride content of the catalyst.
摘要翻译： 催化剂组合物通过在水性介质，钒和磷化合物中与卤化氢反应并从所得反应物中除去液体以形成固体而产生，其以改进的方式在约低于470℃的温度下加热。 从固体中释放水合水，然后在约300至约600℃的温度下与选自一氧化碳，氢气和硫化氢的还原材料接触，并且基本上不存在气态 除了从固体中释放的氧以外的氧。 如本文教导和要求保护的具体还原步骤通过增加催化剂转化率和对期望的氧化产物的选择性来提高催化剂活性性能，并且每量转化的进料组分的含氧产物的最终产率。 它还使无活性VPO5的形成最小化，提高了颗粒的强度并降低了催化剂的残留氯含量。
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44.发明授权Process for the isomerization of dimethylnaphthalenes using a mordenite/alumina catalyst 失效使用丝光沸石/氧化铝催化剂异构化二甲基萘的方法
公开(公告)号：US4041089A
公开(公告)日：1977-08-09
申请号：US700323
申请日：1976-06-28
CPC分类号： B01J29/18 , C07C5/2737 , C07C2521/04 , C07C2529/18
摘要： A process for the isomerization of 1,5 and 1,6-dimethylnaphthalenes to a product including 2,6-dimethylnaphthalene which comprises passing a feed stream containing the 1,5 and 1,6 isomers over a catalyst at isomerization reaction conditions which catalyst consists essentially of from about 35 to about 45 weight per cent of the hydrogen form of mordenite dispersed in an alumina matrix.
摘要翻译： 将1,5和1,6-二甲基萘异构化为包括2,6-二甲基萘的产物的方法，该方法包括使异构化反应条件下将包含1,5和1,6异构体的进料流在催化剂上通入催化剂组成 基本上为分散在氧化铝基质中的约35至约45重量％的形式的丝光沸石。
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公开(公告)号：US4728415A
公开(公告)日：1988-03-01
申请号：US945084
申请日：1986-12-22
CPC分类号： C10G65/043 , C10G45/64
摘要： The present invention provides for a process for reducing the pour point of a hydrocarbon feedstock containing nitrogen- and sulfur-containing impurities. The hydrocarbon feedstock is contacted with hydrogen and a hydrotreating catalyst under hydrotreating conditions whereby a portion of the nitrogen- and sulfur-containing compounds are converted to hydrogen sulfide and ammonia. A portion of the hydrotreater effluent is then passed to a dewaxing zone and contacted with hydrogen under dewaxing conditions in the presence of a dewaxing catalyst containing a borosilicate molecular sieve on silica-alumina-containing matrix.
摘要翻译： 本发明提供了减少含有含氮和含硫杂质的烃原料的倾点的方法。 在加氢处理条件下，碳氢化合物原料与氢气和加氢处理催化剂接触，由此一部分含氮和硫的化合物转化为硫化氢和氨。 然后将一部分加氢处理器流出物通入脱蜡区，并在含二氧化硅 - 氧化铝的基质上含有硼硅酸盐分子筛的脱蜡催化剂存在下，在脱蜡条件下与氢气接触。
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公开(公告)号：US4381991A
公开(公告)日：1983-05-03
申请号：US288944
申请日：1981-07-31
CPC分类号： B01D53/508 , C10G11/18
摘要： Sulfur oxides are removed from a gas by an absorbent comprising magnesium oxide in association with at least one free or combined rare earth metal selected from the group consisting of lanthanum, cerium, praseodymium, samarium, and dysprosium, wherein the ratio by weight of inorganic oxide or oxides to rare earth metal or metals is from about 0.1 to about 30,000. Absorbed sulfur oxides are recovered as a sulfur-containing gas comprising hydrogen sulfide by contacting the spent absorbent with a hydrocarbon in the presence of a hydrocarbon cracking catalyst at a temperature from about 375.degree. to about 900.degree. C. The absorbent can be circulated through a fluidized catalytic cracking process together with the hydrocarbon cracking catalyst to reduce sulfur oxide emissions from the regeneration zone.
摘要翻译： 通过包含氧化镁的吸收剂与至少一种选自镧，铈，镨，钐和镝的游离或组合的稀土金属从气体中除去硫氧化物，其中无机氧化物的重量比 或氧化物至稀土金属或金属为约0.1至约30,000。 通过在烃裂化催化剂存在下，在大约375°至大约900℃的温度下，使用废吸收剂与烃接触，将吸收的硫氧化物作为包含硫化氢的含硫气体回收。吸收剂可循环通过 流化催化裂化过程与烃裂化催化剂一起减少再生区的硫氧化物排放。
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公开(公告)号：US4341660A
公开(公告)日：1982-07-27
申请号：US225712
申请日：1981-01-16
摘要： An improved fluid catalytic cracking process comprises a method for the regeneration of the fluidizable hydrocarbon conversion catalyst, particularly of the molecular sieve type, which has been deactivated with coke deposits while employed in a hydrocarbon catalytic cracking process, in which the coke-containing hydrocarbon conversion catalyst is contacted with an oxygen-containing gas to burn the coke from the catalyst under conditions providing substantially complete combustion of carbon monoxide and substantially complete combustion of the coke on the catalyst. In the regenerator, particles of the hydrocarbon conversion catalyst are in association with particles of a platinum group metal or rhenium oxidation catalyst which promotes the combustion of carbon monoxide to carbon dioxide. The catalyst composite contains a mixture of cracking catalyst particles and particles having the platinum group metal or rhenium oxidation catalyst supported on a substrate. Evolved heat is recovered by direct heat transfer to the catalyst, for example within a dilute or dense phase zone in the regenerator vessel. The gaseous effluent from the regenerator has a low content of carbon monoxide and may be discharged directly to the atmosphere with little discernible effect upon ambient air quality. The regenerated hydrocarbon conversion catalyst may have less than about 0.05 weight percent coke thereon.
摘要翻译： 改进的流化催化裂化方法包括用于再生可流化烃转化催化剂的方法，特别是分子筛类型的方法，该方法在用于烃催化裂化方法中已经被焦炭沉积物失活，其中含焦炭烃转化 催化剂与含氧气体接触，以在提供基本上完全燃烧一氧化碳并基本上完全燃烧催化剂上的焦炭的条件下从催化剂中燃烧焦炭。 在再生器中，烃转化催化剂的颗粒与促进一氧化碳燃烧成二氧化碳的铂族金属或铼氧化催化剂的颗粒相结合。 催化剂复合材料含有裂化催化剂颗粒和负载在基材上的具有铂族金属或铼氧化催化剂的颗粒的混合物。 通过直接传递到催化剂，例如在再生器容器中的稀相或致密相区中回收升温。 来自再生器的气态流出物具有低的一氧化碳含量，并且可以直接排放到大气中，对环境空气质量几乎没有明显的影响。 再生烃转化催化剂可以具有小于约0.05重量％的焦炭。
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48.发明授权Catalytic cracking using a mixture of cracking catalyst particles with particles of platinum group metal or rhenium on inert substrates regenerated to up to about 0.1% coke 失效使用裂化催化剂颗粒与铂族金属或铼颗粒的混合物在惰性底物上再生至高达约0.1％焦炭的催化裂化
公开(公告)号：US4341623A
公开(公告)日：1982-07-27
申请号：US158613
申请日：1980-06-11
IPC分类号： B01J8/24 , B01J23/90 , B01J29/90 , B01J37/04 , C10G11/18 , B01J23/96 , B01J29/38 , C10G11/05
CPC分类号： C10G11/182 , B01J23/90 , B01J29/90 , B01J37/04 , B01J8/24 , Y02P30/446
摘要： An improved fluid catalytic cracking process comprises a method for the regeneration of the fluidizable hydrocarbon conversion catalyst, particularly of the molecular sieve type, which has been deactivated with coke deposits while employed in a hydrocarbon catalytic cracking process, in which the coke-containing hydrocarbon conversion catalyst is contacted with an oxygen-containing gas to burn the coke from the catalyst under conditions providing substantially complete combustion of carbon monoxide and substantially complete combustion of the coke on the catalyst. In the regenerator, particles of the hydrocarbon conversion catalyst are in association with particles of a platinum group metal or rhenium oxidation catalyst which promotes the combustion of carbon monoxide to carbon dioxide. The catalyst composite contains a mixture of cracking catalyst particles and particles having the platinum group metal or rhenium oxidation catalyst supported on a substrate. Evolved heat is recovered by direct heat transfer to the catalyst, for example within a dilute or dense phase zone in the regenerator vessel. The gaseous effluent from the regenerator has a low content of carbon monoxide and may be discharged directly to the atmosphere with little discernible effect upon ambient air quality. The regenerated hydrocarbon conversion catalyst may have less than about 0.05 weight percent coke thereon.
摘要翻译： 改进的流化催化裂化方法包括用于再生可流化烃转化催化剂的方法，特别是分子筛类型的方法，该方法在用于烃催化裂化方法中已经被焦炭沉积物失活，其中含焦炭烃转化 催化剂与含氧气体接触，以在提供基本上完全燃烧一氧化碳并基本上完全燃烧催化剂上的焦炭的条件下从催化剂中燃烧焦炭。 在再生器中，烃转化催化剂的颗粒与促进一氧化碳燃烧成二氧化碳的铂族金属或铼氧化催化剂的颗粒相结合。 催化剂复合材料含有裂化催化剂颗粒和负载在基材上的具有铂族金属或铼氧化催化剂的颗粒的混合物。 通过直接传递到催化剂，例如在再生器容器中的稀相或致密相区中回收升温。 来自再生器的气态流出物具有低的一氧化碳含量，并且可以直接排放到大气中，对环境空气质量几乎没有明显的影响。 再生烃转化催化剂可以具有小于约0.05重量％的焦炭。
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公开(公告)号：US4238319A
公开(公告)日：1980-12-09
申请号：US32268
申请日：1979-04-23
IPC分类号： B01J29/12 , C10G35/095 , C10G45/64 , C10G35/08
CPC分类号： C10G35/095 , B01J29/12 , C10G2400/02
摘要： Isomerization process for petroleum light hydrocarbons with a boiling point within the range of from about 100.degree. F. (38.degree. C.) to about 210.degree. F. (99.degree. C.) wherein said process comprises contacting said hydrocarbons with a catalyst consisting essentially of an ultrastable, large pore crystalline zeolite aluminosilicate material containing less than 1 (wt)% alkali metal and characterized by well-defined hydroxyl infra-red bands and a maximum unit cubic cell dimension of 24.55 A and a metal component selected from the metals, oxides or sulfides of the Group VIII elements of the Periodic Table, under suitable isomerization conditions.
摘要翻译： 沸点在约100°F（38℃）至约210°F（99℃）范围内的石油轻烃的异构化方法，其中所述方法包括使所述烃与基本上组成的催化剂接触 包含小于1（wt）％碱金属的超细大孔结晶沸石硅铝酸盐材料，其特征在于明确的羟基红外带和最大单位立方晶胞尺寸为24.55A，金属组分选自金属， 在合适的异构化条件下，元素周期表第Ⅷ族元素的氧化物或硫化物。
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公开(公告)号：US4077909A
公开(公告)日：1978-03-07
申请号：US559055
申请日：1975-03-17
IPC分类号： B01J29/26 , C10G35/095 , C10G59/02 , B01J29/06 , C10G35/06
CPC分类号： C10G59/02 , B01J29/26 , C10G35/095
摘要： The catalyst comprises a hydrogenation component comprising a member selected from the group consisting of a metal of Group VIA, compounds of a metal of Group VIA, and mixtures thereof supported on a co-catalytic solid support comprising mordenite and a porous refractory inorganic oxide. The hydrogenation component may be characterized further by a member selected from the group consisting of rhenium, compounds of rhenium, a non-noble metal of Group VIII, compounds of a non-noble metal of Group VIII, and mixtures thereof. The preferred Group VIA metal is molybdenum.The catalyst preparation may comprise blending finely-divided mordenite into a sol or gel of the refractory inorganic oxide to form a blend, gelling the blend, if a sol is present, to form a gel by adding a solution of a suitable inorganic ammonium-affording compound, and drying and calcining the gel to form a calcined material.According to the invention, the reforming process comprises contacting a petroleum hydrocarbon stream in a reforming zone under reforming conditions and in the presence of hydrogen with the above catalyst. In one embodiment, the process comprises contacting a partially-reformed hydrocarbon stream in a reforming zone under reforming conditions and in the presence of hydrogen with the above catalyst. In another embodiment, the process comprises contacting the petroleum hydrocarbon stream in a first reforming zone under reforming conditions and in the presence of hydrogen with a catalyst comprising a platinum group metal and a halide on alumina to produce a first reformate and subsequently contacting the first reformate in a second reforming zone under reforming conditions and in the presence of hydrogen with the above catalyst.
摘要翻译： 催化剂包含氢化组分，其包含选自VIA族的金属，VIA族的金属化合物和它们的负载在包含丝光沸石和多孔耐火无机氧化物的助催化固体载体上的混合物的成员。 氢化组分还可以由选自铼，铼化合物，VIII族非贵金属，VIII族非贵金属化合物及其混合物的成员组成的组中表征。 优选的VIA族金属是钼。
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