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公开(公告)号：US4306106A
公开(公告)日：1981-12-15
申请号：US934236
申请日：1978-08-16
IPC分类号： B01J20/18 , B01J29/08 , B01J29/18 , B01J29/40 , C07C1/24 , C07C29/10 , C07C29/32 , C07C37/055 , C07C37/11 , C07C37/14 , C07C37/20 , C07C41/06 , C07C45/74 , C07C209/68 , C07D295/023 , B01J29/06 , C07C45/51
CPC分类号： C07D295/023 , B01J20/186 , B01J29/088 , B01J29/18 , B01J29/40 , C01B33/2869 , C07C209/68 , C07C29/106 , C07C29/32 , C07C29/38 , C07C29/44 , C07C37/055 , C07C37/115 , C07C37/14 , C07C41/06 , C07C45/74 , B01J2229/16 , C07C2101/14 , C07C2529/08 , Y02P20/52
摘要： Conversion, e.g. dehydration of aliphatic organic oxygenates having up to about 6 carbon atoms by contact with a crystalline aluminosilicate zeolite, preferably ZSM-5, having a silica to alumina ratio substantially greater than 10, at a temperature of about 70.degree. to 1400.degree. F., depending upon the exact nature of the reactant and product.
摘要翻译： 转换，例如 在大约70°至1400°F的温度下，通过与晶体硅铝酸盐沸石（优选ZSM-5）接触而具有高达约6个碳原子的脂肪族有机含氧化合物脱水，其中二氧化硅与氧化铝的比例基本上大于10。 根据反应物和产品的确切性质。
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公开(公告)号：US4276151A
公开(公告)日：1981-06-30
申请号：US134818
申请日：1980-03-28
IPC分类号： C10G35/095 , C10G35/06
CPC分类号： C10G35/095
摘要： ZSM-5 type zeolites as more specifically defined hereinabove, are added to reforming catalysts in order to produce a new catalyst composition with high catalytic activity and excellent selectivity. These new catalysts when utilized in reforming naphtha, reduce the C.sub.1 plus C.sub.2 concentrations in reformer gas product, while increasing the C.sub.3 plus C.sub.4 concentrations.
摘要翻译： 为了制备具有高催化活性和优异选择性的新催化剂组合物，将重质催化剂加入上文更具体地定义的ZSM-5型沸石。 这些新型催化剂用于重整石脑油时，降低重整气产物中的C1 + C2浓度，同时提高C3 + C4浓度。
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公开(公告)号：US4247728A
公开(公告)日：1981-01-27
申请号：US92311
申请日：1979-11-08
CPC分类号： B01J29/70 , C07C1/20 , C07C2/00 , C07C2529/70
摘要： A new crystalline zeolite, designated ZSM-43, a method of making same and the use thereof in catalytic conversion of organic compounds is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides, as follows:(0.6 to 2.1)M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2wherein M is at least one cation having a valence n and x is at least 5, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译： 一种名为ZSM-43的新型结晶沸石，其制备方法及其在有机化合物的催化转化中的应用是本申请的主题。 新沸石具有无水状态的氧化物摩尔比表示的组成：（0.6-2.1）M2 / nO：Al2O3：xSiO2其中M是至少一个价数为n的阳离子，x是 至少5个，其特征在于指定的X射线粉末衍射图。
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公开(公告)号：US4191638A
公开(公告)日：1980-03-04
申请号：US953671
申请日：1978-10-23
IPC分类号： B01J37/04 , C10G35/095 , C10G35/08
CPC分类号： B01J37/04 , C10G35/095
摘要： Crystalline aluminosilicate zeolites are mixed with conventional reforming catalysts to produce new catalytic compositions with high catalytic activity and selectivity and excellent aging characteristics. These new catalytic compositions may be utilized alone or in conjunction with conventional reforming catalysts. The acidic activity of the total catalyst system is controlled within defined limits. When so controlled the utility of these catalyst systems in reforming hydrocarbon mixtures is to reduce the C.sub.1 and C.sub.2 concentrations in reformer gas product, while increasing the C.sub.3 and C.sub.4 concentrations and maintaining high liquid yield at high octane numbers.
摘要翻译： 将结晶硅铝酸盐沸石与常规重整催化剂混合以产生具有高催化活性和选择性以及优异的老化特性的新催化组合物。 这些新的催化组合物可以单独使用或与常规重整催化剂结合使用。 总催化剂体系的酸性活性控制在规定的限度内。 如果这样控制，这些催化剂体系在重整烃混合物中的效用是降低重整器气体产物中的C1和C2浓度，同时增加C3和C4浓度，并保持高辛烷值下的高液体产率。
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45.发明授权
公开(公告)号：US4151189A
公开(公告)日：1979-04-24
申请号：US894887
申请日：1978-04-10
IPC分类号： B01J20/18 , B01J29/06 , B01J29/40 , B01J29/65 , B01J29/70 , C01B39/04 , C01B39/36 , C01B39/38 , C01B39/40 , C01B39/42 , C01B39/44 , C07F5/06
CPC分类号： B01J29/40 , C01B33/2876 , B01J29/65 , B01J29/70 , Y10S423/22
摘要： A method is disclosed for synthesizing a crystalline aluminosilicate zeolite containing an organic nitrogen cation in the presence of a primary monoalkylamine having 2 to 9 carbon atoms in the alkyl portion. The method produces a zeolite having a very low percentage, i.e. less than about 0.14 weight percent, generally less than about 0.1 weight percent of alkali metal, e.g. sodium, in the as-synthesized form. The product can be used directly as a catalyst without intermediate precalcination and cation exchange. This is not possible with zeolites such as those of the ZSM-5 type synthesized by the methods of the art.
摘要翻译： 公开了一种在烷基部分存在下具有2〜9个碳原子的伯一烷基胺的情况下合成含有有机氮阳离子的结晶硅铝酸盐沸石的方法。 该方法产生具有非常低百分比，即小于约0.14重量％，通常小于约0.1重量％的碱金属的沸石。 钠，以合成形式。 该产品可直接用作催化剂，无需中间预煅烧和阳离子交换。 这是不可能的沸石，如通过本领域的方法合成的ZSM-5型沸石。
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公开(公告)号：US4128504A
公开(公告)日：1978-12-05
申请号：US551949
申请日：1975-02-21
CPC分类号： B01J29/46 , B01J29/40 , B01J29/405 , B01J29/44 , C07C2/00 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/40
摘要： Crystalline aluminosilicate catalysts, especially those containing zinc, are stabilized with respect to elution of the zinc by adding thereto another metal of Group IB or Group VIII (e.g. copper or nickel). Germanium, rhenium and the rare earth metals may also be added.
摘要翻译： 结晶硅铝酸盐催化剂，特别是那些含锌的硅酸铝催化剂，通过加入另一种IB族或VIII族金属（如铜或镍）而使锌的洗脱稳定。 还可以加入锗，铼和稀土金属。
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公开(公告)号：US4086186A
公开(公告)日：1978-04-25
申请号：US738771
申请日：1976-11-04
IPC分类号： C07C43/04 , B01J29/00 , B01J29/50 , B01J29/70 , C01B39/30 , C07B61/00 , C07C1/00 , C07C1/20 , C07C2/12 , C07C4/06 , C07C5/27 , C07C6/12 , C07C9/00 , C07C11/02 , C07C15/02 , C07C41/00 , C07C67/00 , C10G11/05 , C01B33/28 , B01J29/06 , B01J29/28
CPC分类号： C10G11/05 , B01J29/50 , B01J29/70 , B01J29/7049 , C01B39/305 , C07C1/20 , C07C2/12 , C07C4/06 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/06
摘要： A crystalline zeolite, designated ZSM-34, having the composition as synthesized and in anhydrous form, expressed as mole ratios of oxides as follows:(0.5-1.3)R.sub.2 O: (0-0.15)Na.sub.2 O: (0.10-0.50)K.sub.2 O: Al.sub.2 O.sub.3 : XSiO.sub.2where R is the organic nitrogen-containing cation derived from choline [(CH.sub.3).sub.3 NCH.sub.2 CH.sub.2 OH] and X is 8 to 50, said zeolite having an X-ray diffraction pattern, identifying it as a member of the offretite-erionite family and the ability, after calcination at 1000.degree. F for at least a period of time to remove the organic cation, to sorb at least 9.5 weight percent of n-hexane at ambient temperature and a n-hexane pressure of 20mm. Organic compound conversion is carried out in the presence of a catalytically-active form of said zeolite.
摘要翻译： 称为ZSM-34的结晶沸石，具有合成和无水形式的组成，表示为氧化物的摩尔比如下：
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公开(公告)号：US4079096A
公开(公告)日：1978-03-14
申请号：US738773
申请日：1976-11-04
CPC分类号： C07C1/20 , B01J29/50 , B01J2229/36 , C07C2529/06 , C07C2529/50 , Y02P20/52 , Y02P30/42 , Y10S585/906
摘要： A catalytic process is provided for converting a charge consisting essentially of methanol, dimethyl ether or mixtures thereof to a hydrocarbon product rich in ethylene and propylene by contact, under conversion conditions, with a catalyst comprising the crystalline aluminosilicate zeolite designated "ZSM-34".
摘要翻译： 提供了一种催化方法，用于在转化条件下与包含称为“ZSM-34”的结晶硅铝酸盐沸石的催化剂接触，将基本上由甲醇，二甲醚或其混合物组成的电荷转化成富含乙烯和丙烯的烃产物。
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公开(公告)号：US4079095A
公开(公告)日：1978-03-14
申请号：US738772
申请日：1976-11-04
CPC分类号： C07C1/20 , C07C2529/50 , Y02P30/42 , Y10S585/901 , Y10S585/906 , Y10S585/954
摘要： A catalytic process is provided for converting an organic charge consisting essentially of methanol, dimethyl ether or mixtures thereof together with at least about 0.25 moles of water per mole of said organic charge to a hydrocarbon product rich in ethylene and propylene by contact, under conversion conditions, with a catalyst comprising a crystalline aluminosilicate zeolite of the erionite-offretite family.
摘要翻译： 提供了一种催化方法，用于将基本上由甲醇，二甲醚或其混合物组成的有机电荷与每摩尔所述有机电荷的至少约0.25摩尔水转化成富含乙烯和丙烯的烃产物，在转化条件下接触 ，其中催化剂包含该起始玻璃体系的结晶硅铝酸盐沸石。
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公开(公告)号：US4046859A
公开(公告)日：1977-09-06
申请号：US560412
申请日：1975-03-20
CPC分类号： C01B39/445 , B01J23/30 , B01J29/65 , B01J29/655
摘要： A new family of crystalline zeolites, designated ZSM-21, a method of making same and the use thereof in catalytic conversion of hydrocarbons is the subject of this application. The new zeolites have the composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O : (0-0.8)M.sub.2 O : Al.sub.2 O.sub.3 : >8 SiO.sub.2wherein R is an organic nitrogen-containing cation and M is an alkali metal cation, and are characterized by a specified X-ray powder diffraction pattern.
摘要翻译： 一种名为ZSM-21的新型结晶沸石系列，其制备方法及其在烃的催化转化中的应用是本申请的主题。 新的沸石具有无水状态的组成，以氧化物的摩尔比表示如下：
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