Adhesive systems comprising a bisamino piperazine-containing polyamide
    43.
    发明授权
    Adhesive systems comprising a bisamino piperazine-containing polyamide 失效
    包含含双苯胺的含哌啶胺的粘合体系

    公开(公告)号:US4082708A

    公开(公告)日:1978-04-04

    申请号:US725012

    申请日:1976-09-20

    申请人: Ramesh Mehta

    发明人: Ramesh Mehta

    摘要: The disclosed adhesive system comprises a curable liquid epoxide and a bisamino piperazine-containing thermoplastic polyamide hardener or co-curative. This adhesive system forms high strength metal-to-metal bonds with unusually high T-peel strength, high tensile shear strength, excellent low temperature properties, and good impact resistance while possessing the fast assembly speed characteristics of a hot melt. Both two-part and stable one-part curable systems can be formulated from (a) suitable epoxy resins and (b) the bisamino piperazine-containing thermoplastic polyamide.The particularly preferred polyamide comprises the amidification product, at temperatures of from 180.degree. C. to 300.degree. C., of:(a) from about 25-35% by weight of a diamine component comprising:(1) from about 45-65 equivalent percent of 1,4-Bis(3-aminopropyl) piperazine;(2) from about 15-35 equivalent percent polyoxypropylene diamine containing about 2 to about 35 repeating oxypropylene units;(3) from about 15-35 equivalent percent piperazine;(b) from about 65-75% by weight of a dicarboxylic acid component comprising:(1) from about 70-100 equivalent percent polymerized tall oil fatty acid having a dimeric fatty acid content greater than 90% by weight;(2) from about 0-30 equivalent percent azelaic acid.

    Liquid polyamide epoxy resin hardener
    44.
    发明授权
    Liquid polyamide epoxy resin hardener 失效
    液态聚酰胺环氧树脂固化剂

    公开(公告)号:US3919142A

    公开(公告)日:1975-11-11

    申请号:US42708173

    申请日:1973-12-21

    申请人: KAO CORP

    摘要: wherein R3 and R4 are H or alkyl having 1-19 carbon atoms), or the dibasic acid prepared by hydrolysis of said ester, or the saturated dibasic acid or ester prepared by hydrogenation of said acid or ester, with (B) polyalkylene polyamine.

    An epoxy resin hardener consisting of polyamide resin prepared by reacting (A) dibasic acid ester of the formula, R2OOC-CH2-CH2R1-CH2-CH2-COOR2 (wherein R1 is a bivalent vinylidene-type olefin radical having one double bond and R2 is a radical which forms an ester with acrylic acid), which dibasic acid ester is prepared from acrylic ester and vinylidene type olefin

    摘要翻译: 一种由聚酰胺树脂组成的环氧树脂固化剂,其通过使(A)下式的二元酸R2OOC-CH2-CH2-R1-CH2-CH2-COOR2(其中R1是具有一个双键的二价亚乙烯基型烯烃基团和 R2是与丙烯酸形成酯的基团),该二元酸酯由丙烯酸酯和亚乙烯基型烯烃R3-CH2烷基C = CH2R4-CH2制备,其中R3和R4是H或具有1-19个碳原子的烷基 )或通过所述酯水解制备的二元酸或通过所述酸或酯氢化制备的饱和二元酸或酯与(B)聚亚烷基多胺制备。

    Surface sweeping machine equipped with gutter brush
    46.
    发明授权
    Surface sweeping machine equipped with gutter brush 失效
    表面清洁机配GUTTER BRUSH

    公开(公告)号:US3790981A

    公开(公告)日:1974-02-12

    申请号:US28945372

    申请日:1972-09-15

    申请人: YOUNG B

    发明人: YOUNG B

    IPC分类号: C08G59/44 E01H1/05 E01H1/04

    CPC分类号: E01H1/053 C08G59/44

    摘要: A mobile road or like surface sweeping machine has a gutter brush and a brush driving hydraulic motor carried on a supporting structure which is mounted on the machine frame for compound vertical and horizontal swinging movements from a stowed position, with the brush in close to the machine frame and elevated and out of contact with the ground surface, to an extended operating position relatively wide of the frame and in pressure engagement with the surface to be swept. The brush rotates about a generally vertical although slightly tilted axis. A single power operated means, a hydraulic ram, operates the supporting structure to produce the compound vertical and horizontal swinging of the latter. When the brush encounters increased resistance to rotation, for example due to built-up or heavy debris, the pressure of the hydraulic fluid at the motor inlet increases, and the ram responds to that condition by forcing the brush into greater pressure contact with the surface, thereby ensuring greater capability of sweeping the obstruction.

    摘要翻译: 移动路面或类似表面扫掠机具有沟槽刷和刷驱动液压马达,其支撑结构安装在机架上,用于从收起位置进行复合的垂直和水平摆动运动,刷子靠近机器 框架并升高并与地表面接触,延伸到相对宽的框架的延伸的操作位置,并与要扫掠的表面压力接合。 刷子围绕大致垂直但稍微倾斜的轴线旋转。 单个动力操作装置,液压油缸,操作支撑结构以产生后者的复合垂直和水平摆动。 当刷子遇到增加的旋转阻力时,例如由于堆积或沉重的碎屑,电动机入口处的液压流体的压力增加,并且冲击器通过迫使刷子与表面更大的压力接触来响应该状态 ,从而确保更大的扫除障碍物的能力。

    Novel low-viscosity epoxy curing agents
    47.
    发明授权
    Novel low-viscosity epoxy curing agents 失效
    新型低粘度环氧固化剂

    公开(公告)号:US3790633A

    公开(公告)日:1974-02-05

    申请号:US3790633D

    申请日:1971-03-10

    申请人: LUBRIZOL CORP

    发明人: JEDLICKA W

    CPC分类号: C08G59/54 C08G59/44

    摘要: NOVEL COMPOSITIONS ARE PREPARED BY THE REACTION OF A POLYAMIDE OR POLYAMINE WITH AN N-3-OXOHYDROCARBONSUBSTITUTED 3-ALKOXY-, 3-MERCAPTO- OR 3-AMINOPROPIONAMIDE OR SIMILAR COMPOUND. THESE COMPOSITIONS ARE USEFUL AS CURING AGENTS FOR POLYEPOXIDES, ESPECIALLY EPOXY RESINS. MANY OF THEN ALSO HAVE LOW VISCOSITY, LOW TOXICITY AND LOW TENDENCY TO SKIN AND EYE IRRITATION.

    Process for producing epoxide polyadducts in presence of phosphoric acid triamide accelerators
    49.
    发明授权
    Process for producing epoxide polyadducts in presence of phosphoric acid triamide accelerators 失效
    磷酸三钙加速器存在下生产环氧化物聚合物的方法

    公开(公告)号:US3764582A

    公开(公告)日:1973-10-09

    申请号:US3764582D

    申请日:1972-02-01

    发明人: LORENZ J

    IPC分类号: C08G59/44 C08G30/14

    CPC分类号: C08G59/446

    摘要: Process for the production of epoxide polyadducts by the reaction of epoxide compounds with compounds giving polyadducts of epoxide compounds, whereby the reaction is carried out in the presence of a phosphoric acid triamide as a reaction accelerator in an amount of 0.05 to 10 parts by weight to 100 parts by weight of the epoxide compound.

    摘要翻译: 通过环氧化物与赋予环氧化合物的加合物的化合物的反应生成环氧化物多加成物的方法,其中反应在作为反应促进剂的磷酸三酰胺存在下进行,其量为0.05〜10重量份〜 100重量份的环氧化合物。

    Improved curing compositions for epoxy resins comprising latent amine curing agent and accelerator
    50.
    发明授权
    Improved curing compositions for epoxy resins comprising latent amine curing agent and accelerator 失效
    用于包含有效胺固化剂和加速器的环氧树脂改进的固化组合物

    公开(公告)号:US3759914A

    公开(公告)日:1973-09-18

    申请号:US3759914D

    申请日:1971-08-10

    申请人: DU PONT

    发明人: SIMMS J TREMPER H

    摘要: Composition, useful for curing polyepoxide having a plurality of 1,2-epoxy groups comprising an admixture of: A. a latent amine curing agent for a polyepoxide having a plurality of 1,2-epoxy groups, and B. an accelerator for (A), the accelerator having the formula

    WHEREIN

    WHEREIN X Cl, Br, CH3, NO2, H, or OCH3 Y Cl, Br, CH3, NO2, H, or OCH3 X and Y can be the same as each other or different from each other, Z a monovalent radical derived from a secondary amine having at least three carbon atoms, PROVIDED THAT WHEN X and Y are selected from the group consisting of Cl, Br, CH3, NO2, or -OCH3 or when X Br and Y H, then Z can be a monovalent radical derived from a secondary amine having at least two carbon atoms, THE ACCELERATOR BEING PRESENT IN AN AMOUNT OF ABOUT 0.1-300 PERCENT BY WEIGHT BASED ON THE WEIGHT OF THE LATENT AMINE CURING AGENT.

    摘要翻译: 组合物,可用于固化具有多个1,2-环氧基团的聚环氧化物,所述1,2-环氧基团包含以下混合物: