摘要:
(Dimethylaminoalkyl)carboxylic and -carbamic acid esters and (dimethylaminoalkyl) ethers and ureas are compounds which are especially suitable for use as amine curing agents for polyepoxide compounds. They impart longer curing times to the curable mixtures and thus good processing properties, especially when the mixtures are used as adhesives. In addition, the mechanical properties are often improved. Further, these compounds afford advantages when used as curing agents on account of their low volatility.
摘要:
An epoxy resin having superior resistance to thermal shock comprises a vicinal polyepoxide, a curing amount of a certain bicyclic anhydride and an effective amount of an additive comprising a polyoxyalkylenepolyamine-maleic anhydride condensation product having thioureide, ureide or thioformamide or formamide end groups.
摘要:
The disclosed adhesive system comprises a curable liquid epoxide and a bisamino piperazine-containing thermoplastic polyamide hardener or co-curative. This adhesive system forms high strength metal-to-metal bonds with unusually high T-peel strength, high tensile shear strength, excellent low temperature properties, and good impact resistance while possessing the fast assembly speed characteristics of a hot melt. Both two-part and stable one-part curable systems can be formulated from (a) suitable epoxy resins and (b) the bisamino piperazine-containing thermoplastic polyamide.The particularly preferred polyamide comprises the amidification product, at temperatures of from 180.degree. C. to 300.degree. C., of:(a) from about 25-35% by weight of a diamine component comprising:(1) from about 45-65 equivalent percent of 1,4-Bis(3-aminopropyl) piperazine;(2) from about 15-35 equivalent percent polyoxypropylene diamine containing about 2 to about 35 repeating oxypropylene units;(3) from about 15-35 equivalent percent piperazine;(b) from about 65-75% by weight of a dicarboxylic acid component comprising:(1) from about 70-100 equivalent percent polymerized tall oil fatty acid having a dimeric fatty acid content greater than 90% by weight;(2) from about 0-30 equivalent percent azelaic acid.
摘要:
wherein R3 and R4 are H or alkyl having 1-19 carbon atoms), or the dibasic acid prepared by hydrolysis of said ester, or the saturated dibasic acid or ester prepared by hydrogenation of said acid or ester, with (B) polyalkylene polyamine.
An epoxy resin hardener consisting of polyamide resin prepared by reacting (A) dibasic acid ester of the formula, R2OOC-CH2-CH2R1-CH2-CH2-COOR2 (wherein R1 is a bivalent vinylidene-type olefin radical having one double bond and R2 is a radical which forms an ester with acrylic acid), which dibasic acid ester is prepared from acrylic ester and vinylidene type olefin
摘要:
Method of preparing a copper-clad laminate by impregnating a base material with a varnish of a thermosetting resin, drying the base material, adhering a copper foil to the base material through an adhesive containing a curable epoxy resin and a specific type of curing agent, for example, a compound having amino and allyl radicals, and heating the assembly under pressure.
摘要:
A mobile road or like surface sweeping machine has a gutter brush and a brush driving hydraulic motor carried on a supporting structure which is mounted on the machine frame for compound vertical and horizontal swinging movements from a stowed position, with the brush in close to the machine frame and elevated and out of contact with the ground surface, to an extended operating position relatively wide of the frame and in pressure engagement with the surface to be swept. The brush rotates about a generally vertical although slightly tilted axis. A single power operated means, a hydraulic ram, operates the supporting structure to produce the compound vertical and horizontal swinging of the latter. When the brush encounters increased resistance to rotation, for example due to built-up or heavy debris, the pressure of the hydraulic fluid at the motor inlet increases, and the ram responds to that condition by forcing the brush into greater pressure contact with the surface, thereby ensuring greater capability of sweeping the obstruction.
摘要:
NOVEL COMPOSITIONS ARE PREPARED BY THE REACTION OF A POLYAMIDE OR POLYAMINE WITH AN N-3-OXOHYDROCARBONSUBSTITUTED 3-ALKOXY-, 3-MERCAPTO- OR 3-AMINOPROPIONAMIDE OR SIMILAR COMPOUND. THESE COMPOSITIONS ARE USEFUL AS CURING AGENTS FOR POLYEPOXIDES, ESPECIALLY EPOXY RESINS. MANY OF THEN ALSO HAVE LOW VISCOSITY, LOW TOXICITY AND LOW TENDENCY TO SKIN AND EYE IRRITATION.
摘要:
Process for the production of epoxide polyadducts by the reaction of epoxide compounds with compounds giving polyadducts of epoxide compounds, whereby the reaction is carried out in the presence of a phosphoric acid triamide as a reaction accelerator in an amount of 0.05 to 10 parts by weight to 100 parts by weight of the epoxide compound.
摘要:
Composition, useful for curing polyepoxide having a plurality of 1,2-epoxy groups comprising an admixture of: A. a latent amine curing agent for a polyepoxide having a plurality of 1,2-epoxy groups, and B. an accelerator for (A), the accelerator having the formula
WHEREIN
WHEREIN X Cl, Br, CH3, NO2, H, or OCH3 Y Cl, Br, CH3, NO2, H, or OCH3 X and Y can be the same as each other or different from each other, Z a monovalent radical derived from a secondary amine having at least three carbon atoms, PROVIDED THAT WHEN X and Y are selected from the group consisting of Cl, Br, CH3, NO2, or -OCH3 or when X Br and Y H, then Z can be a monovalent radical derived from a secondary amine having at least two carbon atoms, THE ACCELERATOR BEING PRESENT IN AN AMOUNT OF ABOUT 0.1-300 PERCENT BY WEIGHT BASED ON THE WEIGHT OF THE LATENT AMINE CURING AGENT.