THERMOPLASTIC ACRYLIC RESIN AND METHOD FOR PRODUCING SAME, AND RESIN COMPOSITION

    公开(公告)号:US20210009802A1

    公开(公告)日:2021-01-14

    申请号:US17033241

    申请日:2020-09-25

    Abstract: A thermoplastic acrylic resin is provided. The thermoplastic acrylic resin is a graft copolymer in which a stem polymer is an acrylic resin containing acrylonitrile and another ethylenically unsaturated monomer, and a branch polymer is a polymer composed of an ethylenically unsaturated monomer. The acrylonitrile is contained in an amount of 35 mass % or more and 84.5 mass % or less, the other ethylenically unsaturated monomer is contained in an amount of 15 mass % or more and 64.5 mass % or less, and the polymer composed of an ethylenically unsaturated monomer is contained in an amount of 0.5 mass % or more and 40 mass % or less. Thus, provided are a thermoplastic acrylic resin having improved melt-processability without compromising heat resistance, a method for producing the thermoplastic acrylic resin, a thermoplastic acrylic resin composition, a molded body, an acrylic fiber, and a method for producing the acrylic fiber.

    ACRYLIC RESIN FILM, LAMINATED FILM, PRODUCTION METHOD FOR LAMINATED FILM, AND MOLDED ARTICLE

    公开(公告)号:US20210002437A1

    公开(公告)日:2021-01-07

    申请号:US17023904

    申请日:2020-09-17

    Abstract: An acrylic resin film is provided that may include graft copolymer particles (A) with a multilayer structure and graft copolymer particles (B) with a multilayer structure, wherein the graft copolymer particles (A) may have an average particle size in the range of 20 to 150 nm, the graft copolymer particles (B) may have a larger average particle size than the graft copolymer particles (A). The graft copolymer particles (A) may include a cross-linked elastomer (A1) and a graft polymer layer (A2), the graft polymer layer (A2) being closer to a surface layer than the cross-linked elastomer (A1). Further, a constituent unit may be derived from an acrylate with an alkyl ester moiety having two or more carbon atoms constitutes 8% or less by mass of the graft polymer layer (A2), the graft copolymer particles (B) may contain a cross-linked elastomer (B1).

    Graft copolymer and acrylic resin composition containing same

    公开(公告)号:US10745505B2

    公开(公告)日:2020-08-18

    申请号:US16138245

    申请日:2018-09-21

    Abstract: A graft copolymer includes: an inner layer made of a hard polymer (I) obtained by polymerizing a monomer mixture including 40 to 100 wt % of a methacrylate ester 0 to 15 wt % of an aromatic vinyl monomer, and 0 to 45 wt % of another copolymerizable monomer and 0.01 to 10 parts by weight of a polyfunctional monomer; an intermediate layer made of a soft polymer (II) obtained by polymerizing a monomer mixture including 60 to 100 wt % of an acrylate ester and 0 to 40 wt % of another copolymerizable monomer, 0.01 to 5 parts by weight of allyl (meth)acrylate, and a di(meth)acrylic compound; and an outer layer made of a hard polymer (III) obtained by polymerizing a monomer mixture including 40 to 100 wt % of a methacrylate ester and 60 to 0 wt % of another copolymerizable monomer and 0 to 10 parts by weight of a polyfunctional monomer.

    Multi-part acrylic cold-curing composition

    公开(公告)号:US10745504B2

    公开(公告)日:2020-08-18

    申请号:US15322660

    申请日:2015-07-08

    Abstract: A multi-part acrylic cold curing composition for metallography moulds to produce a metallography mount is described. The composition has a storage stable solid part and a storage stable liquid part. The parts are operable to form a mixture which polymerises to a solid mass upon mixing of the parts together. The solid part comprises polymer powder and initiator and the liquid part comprises acrylic monomer and optionally activator or accelerator. The initiator is present in an amount effective to polymerize the acrylic monomer component upon being mixed with the liquid part. The composition comprises a cyclic ester side group containing monofunctional acrylic monomer. The composition liquid part may contain a mixture of monofunctional monomer(s) and polyfunctional monomer(s), wherein the polyfunctional monomers comprise between 12 and 22% w/w of the total monomers in the uncured composition. Metallography mounts and processes for producing the mounts are also described.

    Multilayer film and multilayer molded article

    公开(公告)号:US10737466B2

    公开(公告)日:2020-08-11

    申请号:US15758569

    申请日:2016-09-06

    Abstract: As a laminated film having high transparency, stress whitening resistance, and chemical resistance, a laminated film comprising a layer comprising a fluorine-based resin (X) and a layer comprising an acrylic resin composition (Y), and satisfying the following conditions (1) and (2) is provided. (1) When a test piece is stretched from a chuck-to-chuck distance of 25 mm to 35 mm at a temperature of 0° C. and a tensile rate of 500 mm/min according to ISO 527-3, a difference (ΔW) between a degree of whiteness of the test piece before and that after stretching is 5 or less. (2) The acrylic resin composition (Y) comprises a rubber-containing polymer (B) comprising 30% by mass or more of an elastic polymer (B1).

    Multistage polymer composition, its method of preparation, its use and composition comprising it

    公开(公告)号:US10723873B2

    公开(公告)日:2020-07-28

    申请号:US16382328

    申请日:2019-04-12

    Applicant: Arkema France

    Abstract: The present invention relates to a multistage polymer in form of polymeric particles, its composition and its process of preparation. In particular the present invention it relates to a multistage polymer in form of polymeric particles made by a multistage process while the last stage comprises a polymer with a low molecular weight. More particularly the present invention relates to polymer composition in form of polymeric particles made by a multistage process comprising at least three stages while the last stage comprises a polymer with a low molecular weight, its method of preparation, its use as impact modifier in polymer compositions for composites comprising thermosetting resins or thermoplastic polymers and compositions and articles comprising it.

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