摘要:
A method includes:generating a peroxide radical on a dielectric substrate surface by treating the dielectric substrate surface with atmospheric pressure plasma using a rare gas; fixing a functional group forming a coordinate bond with a silver ion, by reacting a grafting agent; and applying a silver-containing composition to the substrate surface, followed by heating and curing the silver-containing composition, to thereby form a silver thin film layer, the silver-containing composition containing a silver compound (A) represented by Formula (1) and an amine compound (B) represented by Formula (2), the silver compound (A) being contained in an amount of 10 to 50% by mass, the amine compound (B) being contained in an amount of 50 to 90% by mass, relative to a total amount of 100% by mass of the silver compound (A) and the amine compound (B).The method enables to form a metal film having high adhesiveness even on the surface of a fluorine resin, which is suitable as a dielectric substrate due to its property of avoidance of delay in signal transmission speed or increase in power consumption, but has extremely low adhesiveness. (R1; a hydrogen atom, —(CY2)a-CH3, or —((CH2)b-O—CHZ)c-CH3; R2: —(CY2)d-CH3 or —((CH2)e-O—CHZ)f-CH3; Y: a hydrogen atom or —(CH2)g-CH3; Z: a hydrogen atom or —(CH2)h-CH3; a: an integer of 0 to 8; b: an integer of 1 to 4; c: an integer of 1 to 3; d: an integer of 1 to 8; e: an integer of 1 to 4; f: an integer of 1 to 3; g: an integer of 1 to 3; h: an integer of 1 or 2)
摘要:
A method for purifying a polyethylene glycol compound having one amino group, which includes (A) preparing an aqueous solution of the compound having a pH of 1 to 5, (B) an extracting step of mixing the aqueous solution with a mixed organic solvent to cause layer separation into organic and aqueous layers, wherein a ratio of an organic solvent I is 25 to 65% by mass and a ratio of an organic solvent II is 75 to 35% by mass, the organic solvent I is selected from an aromatic hydrocarbon and an ester, the organic solvent II is a halogenated hydrocarbon, and a mixing ratio Y of I to II, temperature T (° C.) at mixing, and molecular weight M of the compound satisfy the following relationship: 1.9×10−6M+0.09≦Y−0.015T≦−1.4×10−6M+0.44 and (C) recovering the compound from the aqueous layer.
摘要:
A hydrophilic polymer derivative having a benzylidene acetal linker whose hydrolysis rate at the pH of a weakly acidic environment in the living body can be accurately controlled. A hydrophilic polymer derivative having a benzylidene acetal linker, which is represented by the following formula (1): wherein R1 is a hydrogen atom or a hydrocarbon group; R2, R3, R4, R5, and R6 are each independently a hydrogen atom or a substituent and at least one of R3, R4, and R5 is an electron-withdrawing substituent or at least one of R2 and R6 represents a substituent; X1 is a chemically reactive functional group; P is a hydrophilic polymer; w is an integer of 1 to 8; and Z1 and Z2 are an independently selected divalent spacer.
摘要:
The present invention relates to an ester for refrigerator oils having less remaining by-products in the ester and having high thermal stability, and a method for producing the ester for refrigerator oils. The ester for refrigerator oils is obtained by treating a crude ester product, which is obtained by reacting a neopentyl polyol having a carbon number of 5 to 10 with an aliphatic carboxylic acid having a carbon number of 4 to 12, with one or more kinds of salts selected from the group consisting of sulfite, bisulfite, and pyrosulfite.
摘要:
Provided are silver nanoparticles having excellent dispersion stability and capable of forming on a substrate a silver element, such as a silver film or line, having excellent electrical conductivity and adhesivity through heating. A method for producing the silver nanoparticles, its dispersion liquid, and a substrate having a silver element formed thereon using the dispersion liquid are disclosed. The silver nanoparticles contain silver compound (A) of formula (1): amine compound (B) having a primary amino group; and polymer (C) obtained by polymerization of a monomer composition containing diol (meth)acrylate compound (c1) having a urethane bond of formula (2): (R1: hydrogen atom or methyl group; R2: —(CH2)n-; n: 1 to 4), and at least one monomer (c2) selected from (meth)acrylate monomers, acrylamide monomers, vinyl monomers, vinyl ether monomers, or monomers having an epoxy group.
摘要:
A polymerizable polyoxyalkylene monoalkyl ether derivative prepared by using a polyoxyalklene monoalkyl ether which gives, in gel permeation chromatography, a chromatogram which satisfies a relation expressed by an equation: S1/S0null0.15, wherein S1 represents the area under a portion of the chromatogram from the start of elution to the earliest elution time when the intensity of the refractive index has a value of L/3, L representing the shortest distance between the greatest maximum point of the intensity of the refractive index and the base line and So represents the area under a portion of the chromatogram from the start of elution to an elution time when the intensity of the refractive index has the greatest maximum value; a process for producing the above ether comprising adjusting the content of water in a reactor, which is used in addition polymerization of alkylene oxides with addition to a monohydric alcohol, so as to satisfy an equation: Winull(CfnullCi)/Vnull10, wherein the content of water in the reactor is obtained by placing a solvent having a content of water Ci (ppm) in an amount Wi (g) in the reactor having an inner volume V (ml), stirring the solvent to clean the reactor, removing the solvent from the reactor and obtaining a content of water Cf (ppm) in the removed solvent.
摘要:
A cosmetic composition comprises 0.00005 to 10 wt % of polymethoxyflavone having at least four methoxy groups. Cosmetic compositions in the form of lotions, milky lotions, oil-in-water creams, water-in-oil creams are preferable. Thus, the present invention provides cosmetic compositions that are excellent in the whitening effect, allow the skin to retain moisture for a long time, vitalize the skin, suppress wrinkles, and have excellent storage stability.
摘要:
A wireless detonation system (1) includes a blasting operation device (40), a detonator (10), and a relay device (30). The blasting operation device (40) is disposed at a distance from a blasting face (71) and wirelessly transmits a first downstream signal at a first frequency. The detonator (10) is loaded in a blast hole (72) in the blasting face (71), and has a receiving coil (12) for wirelessly receiving a second downstream signal at a second frequency lower than the first frequency. A relay device (30) includes a first transmitting-receiving antenna (35) that wirelessly receives the first downstream signal, a relay processor (32) that wirelessly receives the first downstream signal and processes it into the second downstream signal to be wirelessly transmitted at the second frequency, and a second transmitting-receiving antenna (37) that transmits the second downstream signal. The second transmitter-receiver antenna (37) is loaded into an insertion hole (74) in the blasting face (71) aligned with the blast hole (72).
摘要:
An additive for lubricating oil may include a phosphite ester compound (A) having a specific structure and a phosphite ester compound (B) having a specific structure, wherein the (A):(B) mass ratio of the phosphite ester compound (A) to the phosphite ester compound (B) is in a range of from 99:1 to 80:20. Such an additive may be provided to a lubricating oil, capable of imparting wear resistance and demulsibility with respect to a base oil for lubricating oil, and to impart durability even in the presence of water.
摘要:
Provided is a modifier for an ophthalmic device capable of imparting high wettability and lubricity to a silicone hydrogel, specifically, a modifier for an ophthalmic device capable of expressing such effect when contained in a small amount. Also provided are a silicone hydrogel obtained by curing a silicone hydrogel composition containing the modifier for an ophthalmic device, and an ophthalmic device using the silicone hydrogel. It has been found that a water-soluble silicone-containing water-soluble copolymer obtained by copolymerizing a phosphorylcholine group-containing monomer and a specific silicone monomer can impart high wettability and lubricity to a silicone hydrogel when contained in a small amount.