摘要:
A process for preparing molecular sieves of type Y faujasite structure is described, as well as pre-shaped bodies of faujasite structure type Y molecular sieves. The process comprises preparing a precursor gel from a source of silica-alumina or a source of alumina and a source of silica with a template agent at a SiO2/Al2O3 greater than 7 and suitable for forming a type Y zeolite, drying the precursor gel and contacting the dried precursor gel with steam, optionally followed by caustic washing, without the formation of crystalline phases other than type Y zeolite being observed. Advantageously, the pre-shaped bodies prepared with the precursor gel of Y zeolite, when subjected to the process of the invention, will have their outer surface covered by type Y zeolite crystals. The molecular sieves so obtained may be employed as catalysts or adsorbents in various processes of the chemical or oil industry.
摘要翻译:描述了制备Y型八面沸石结构的分子筛的方法,以及Y型分子筛的八面沸石结构体的预制体。 该方法包括从二氧化硅 - 氧化铝源或氧化铝源和二氧化硅源以二氧化硅/ Al 2 O 3大于7的模板剂制备前体凝胶并适于形成Y型沸石,干燥前体凝胶和 使干燥的前体凝胶与蒸汽接触,任选地随后进行苛性碱洗涤,而不形成除Y型沸石以外的结晶相。 有利的是,当用Y沸石的前体凝胶制备的预制体在进行本发明的方法时,其外表面将被Y型沸石晶体覆盖。 如此获得的分子筛可用作化学或石油工业的各种方法中的催化剂或吸附剂。
摘要:
This invention relates to catalysts containing crystalline alumino-silicate zeolite, hydrothermally treated silica-alumina cogels and the employment of the same as cracking catalysts.
摘要:
This invention relates to hydrothermal treatment of silica-alumina cogels resulting in a reduction in the NH.sub.4 content of the gel and the generation of a gamma crystal phase and the employment of such gels as cracking catalysts.
摘要:
This invention relates to hydrothermally treated silica-alumina cogels resulting in a reduction in the NH.sub.4 content of the gel and the employment of such gels as cracking catalysts.
摘要:
This invention relates silica-alumina cogels containing a crystalline phase and to hydrothermally treatment of silica-alumina cogels resulting in generation of a crystalline phase in the gel and the employment of such crystallized gels as hydrocarbon conversion catalysts.
摘要:
A process of producing an ammonium zeolite of the faujasite type in which a zeolite of the faujasite type whose exchange sites are substantially entirely occupied by Na cations, is treated with an ammonium salt solution to exchange substantially all of the Na cations with NH.sub.4 cations with substantially no impairment of crystallinity by a control of the relation of the equivalents of NH.sub.4 in the solution to equivalents of Na in the zeolite.
摘要:
A process is disclosed for converting Tar Sand to fuels and/or valuable chemicais. The process comprises the steps of a) activating Tar Sand to make it more susceptible to conversion; c) partially converting the Tar Sand to a solubilized material; and d) subjecting the unconverted Tar Sand to a second conversion step. The process optionally comprises a step b) of adding a solvent to the activated Tar Sand. In a preferred embodiment the solubilized Tar Sand obtained in step c) is removed before the unconverted Tar Sand is subjected to step d).
摘要:
Hydrocarbon conversion process comprising the steps of (a) suspending catalyst particles comprising a layered material in a first, polar hydrocarbon, employing conditions such as will cause delamination of the layered material to form a suspension comprising particles with a size of less than 1 micron, (b) optionally adding the suspension to a second hydrocarbon, (c) converting the first and/or the optional second hydrocarbon in the presence of said delaminated layered material, and (d) separating the delaminated material from the first and the optional second hydrocarbon. This process provides an economically desired way of converting hydrocarbons using small catalyst particles.
摘要:
Process for upgrading a liquid hydrocarbon feed comprising the steps of (a) preparing a slurry comprising the hydrocarbon feed having a boiling range above 350° C. and solid particles comprising a rehydratable material, (b) thermally treating said slurry at a temperature in the range of 250 to 550° C., (c) optionally separating the thermally treated slurry into (I) a lower boiling fraction and (ii) a higher boiling fraction containing the solid particles and formed coke, if any, and (d) separating the solid particles and formed coke, if any, from the thermally treated slurry resulting from step b) or the higher boiling fraction of step c).