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72 条记录 (耗时 0.021 秒)

    Rubber-like thermoplastic polymer mixtures
    54.
    发明授权
    Rubber-like thermoplastic polymer mixtures 失效
    橡胶状热塑性聚合物混合物

    公开(公告)号：US4902745A

    公开(公告)日：1990-02-20

    申请号：US283464

    申请日：1988-12-12

    申请人： Karl-Erwin Piejko ,  Otto Billinger ,  Lothar Meier ,  Christian Lindner ,  Karl-Heinz Ott

    发明人： Karl-Erwin Piejko ,  Otto Billinger ,  Lothar Meier ,  Christian Lindner ,  Karl-Heinz Ott

    IPC分类号： C08L33/04 ,  C08L33/08 ,  C08L51/04

    CPC分类号： C08L33/08 ,  C08L51/04

    摘要： Soft polymer mixtures of(a) 10 to 50 parts by weight of a graft polymer obtained from a particulate, highly cross linked diene or alkyl acrylate rubber and graft polymerized alkyl methacylate, acrylonitrile, styrene, alkyl acrylate or mixtures thereof and(b) 90 to 50 parts by weight of a partly cross-linked, particulate, rubber-like copolymer of acrylonitrile and/or methyl methacrylate and C.sub.1 to C.sub.8 alkyl acrylate having a gel content of from 60 to 99% by weight and an average particle diameter (d.sub.50) of from 0.1 to 0.6 .mu.m,and a process for the preparation of the mixtures and their use for the production of moulded articles.

    摘要翻译： 由（a）10至50重量份由颗粒状高度交联的二烯或丙烯酸烷基酯橡胶和接枝聚合的甲基丙烯酸烷基酯，丙烯腈，苯乙烯，丙烯酸烷基酯或其混合物获得的接枝聚合物和（b）90 至50重量份的丙烯腈和/或甲基丙烯酸甲酯的部分交联的颗粒状橡胶状共聚物和丙烯酸C1-C8烷基酯，其凝胶含量为60至99重量％，平均粒径（d50 ）为0.1至0.6μm，以及制备混合物的方法及其用于生产模塑制品的方法。

    Method of producing ABS moulding compositions
    56.
    发明授权
    Method of producing ABS moulding compositions 失效
    生产ABS成型组合物的方法

    公开(公告)号：US5981644A

    公开(公告)日：1999-11-09

    申请号：US814988

    申请日：1997-03-14

    申请人： Ralph Ostarek ,  Herbert Eichenauer ,  Karl-Erwin Piejko ,  Frank Wingler ,  Claus Wulff

    发明人： Ralph Ostarek ,  Herbert Eichenauer ,  Karl-Erwin Piejko ,  Frank Wingler ,  Claus Wulff

    IPC分类号： C08L25/08 ,  C08F2/44 ,  C08F279/00 ,  C08F279/02 ,  C08F279/04 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08J3/11

    CPC分类号： C08F279/02 ,  C08F279/04

    摘要： A method of producing ABS moulding compositions wherein a solution of polymers in group (A) solvents is gradually supplied to a polymerizing mixture of previously-formed soluble rubber, aromatic mono-alkenyl compounds, ethylenically unsaturated nitrites, optional other copolymerizable compounds and optionally a group (B) solvent or a mixture of group (A) and group (B) solvents, the gradual addition of the polymer solution to the polymerizing mixture being started before the beginning of phase inversion and at a monomer conversion rate of 5 to 15% and a viscosity of the polymerizing mixture of less than 20 Pa.sec with simultaneous continuation of polymerization, the group (A) solvent is an aliphatic (C.sub.1 -C.sub.8) or cycloaliphatic alcohol, ketone, ether, ester and/or nitrile, and the group (B) solvent is an aliphatic (C.sub.4 -C.sub.10), cycloaliphatic and/or aromatic hydrocarbon.

    摘要翻译： 一种制备ABS模塑组合物的方法，其中将（A）组溶剂中的聚合物溶液逐渐供应到预先形成的可溶性橡胶，芳族单链烯基化合物，烯属不饱和亚硝酸盐，任选的其它可共聚化合物和任选的基团 （B）溶剂或（A）组和（B）组溶剂的混合物中，聚合溶液逐渐加入到聚合混合物中，在相转变开始之前开始，单体转化率为5〜15％， 聚合混合物的粘度小于20Pa·s，同时持续聚合，基团（A）溶剂是脂族（C1-C8）或脂环族醇，酮，醚，酯和/或腈，基团 （B）溶剂是脂族（C 4 -C 10），脂环族和/或芳族烃。

    Process for the preparation of N-substituted cyclic imides
    57.
    发明授权
    Process for the preparation of N-substituted cyclic imides 失效
    制备N-取代的环状酰亚胺的方法

    公开(公告)号：US5773630A

    公开(公告)日：1998-06-30

    申请号：US595982

    申请日：1996-02-06

    申请人： Torsten Groth ,  Karl-Erwin Piejko ,  Winfried Joentgen ,  Josef Kasbauer ,  Bernd Alig ,  Werner Struver

    发明人： Torsten Groth ,  Karl-Erwin Piejko ,  Winfried Joentgen ,  Josef Kasbauer ,  Bernd Alig ,  Werner Struver

    IPC分类号： C07D207/40 ,  C07D207/416 ,  C07D207/44 ,  C07D207/444 ,  C07D207/452 ,  C07D209/48 ,  C07D207/36

    CPC分类号： C07D207/452 ,  C07D207/40

    摘要： N-Substituted cyclic imides are obtained by reacting a cyclic acid anhydride with an amine in the presence of a solvent and an acid catalyst at 80.degree. to 200.degree. C. and with removal of the water formed, it being particularly advantageous to carry out this reaction in the presence of a stabilizer and an inert, dipolar aprotic cosolvent, optionally to add an inert organic solvent of low or zero polarity to the reaction mixture present after the reaction, to add a non-aqueous base in an amount of 0.5 to 50% by weight, based on the cyclic anhydride of the formula (II) used, and to separate off the precipitate formed to give a filtrate containing the N-substituted cyclic imide.

    摘要翻译： N-取代的环状酰亚胺通过使环酸酐与胺在溶剂和酸催化剂的存在下在80℃至200℃下反应并除去形成的水而获得，特别有利的是进行该 在稳定剂和惰性非质子助溶剂的存在下反应，任选地向反应后存在的反应混合物中加入低或零极性的惰性有机溶剂，加入0.5至50的非水性碱 基于所使用的式（II）的环状酸酐，并分离形成的沉淀物，得到含有N-取代的环状酰亚胺的滤液。

    ABS moulding compositions with improved properties
    58.
    发明授权
    ABS moulding compositions with improved properties 失效
    具有改进性能的ABS模塑组合物

    公开(公告)号：US5741853A

    公开(公告)日：1998-04-21

    申请号：US651454

    申请日：1996-05-22

    申请人： Herbert Eichenauer ,  Ulrich Jansen ,  Karl-Erwin Piejko ,  Edgar Leitz

    发明人： Herbert Eichenauer ,  Ulrich Jansen ,  Karl-Erwin Piejko ,  Edgar Leitz

    IPC分类号： C08L25/12 ,  C08F279/02 ,  C08F279/04 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02

    摘要： Thermoplastic moulding compositions of the ABS type of I) at least one graft copolymer which is obtainable by emulsion polymerization of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, in the presence of at least two butadiene polymer latices of types (A) and (B), which each contain, copolymerized, 0 to 50 wt. % of a further vinyl monomer, and wherein the weight ratio of monomers used to butadiene polymers used is 25:75 to 70:30, and II) at least one copolymer of styrene and acrylonitrile in the weight ratio 90:10 to 50:50, wherein styrene and/or acrylonitrile can be completely or partly replaced by .alpha.-methylstyrene, methyl methacrylate or N-phenylmaleimide, characterized in that the butadiene polymer latex (A) has a particle diameter d.sub.50 .ltoreq.320 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 30 to 100 nm, and a gel content.ltoreq.70 wt. % and the butadiene polymer latex (B) has a particle diameter d.sub.50 .gtoreq.370 nm, a width of the particle size distribution (measured as d.sub.90 -d.sub.10 from the integral particle size distribution) of 50 to 500 nm and a gel content.gtoreq.70 wt. %.

    摘要翻译： ABS型I型热塑性成型组合物）至少一种接枝共聚物，其可通过苯乙烯和丙烯腈的重量比90:10至50:50的乳液聚合获得，其中苯乙烯和/或丙烯腈可以完全或部分地被 α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺，在至少两种类型（A）和（B）的丁二烯聚合物胶乳的存在下，它们各自含有0至50wt。 ％的另外的乙烯基单体，并且其中使用的单体与丁二烯聚合物的重量比为25:75至70:30，和II）至少一种苯乙烯和丙烯腈的共聚物，其重量比为90:10至50:50 其中苯乙烯和/或丙烯腈可以被α-甲基苯乙烯，甲基丙烯酸甲酯或N-苯基马来酰亚胺完全或部分替代，其特征在于丁二烯聚合物胶乳（A）的粒径d50 <320nm， 粒度分布（从整体粒度分布以d90-d10测量）为30至100nm，凝胶含量为70wt。 ％，丁二烯聚合物胶乳（B）的粒径d50≥370nm，粒度分布的宽度（以积分粒度分布测定为d90-d10）为50〜500nm，凝胶含量> / = 70wt。 ％。

    Thermoplastic moulding compositions of the ABS type
    60.
    发明授权
    Thermoplastic moulding compositions of the ABS type 失效
    ABS型热塑性成型组合物

    公开(公告)号：US5696204A

    公开(公告)日：1997-12-09

    申请号：US609163

    申请日：1996-02-26

    申请人： Herbert Eichenauer ,  Edgar Leitz ,  Karl-Erwin Piejko ,  Heinrich Alberts

    发明人： Herbert Eichenauer ,  Edgar Leitz ,  Karl-Erwin Piejko ,  Heinrich Alberts

    IPC分类号： C08L33/20 ,  C08L33/18 ,  C08L51/04 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08F279/00

    CPC分类号： C08L55/02

    摘要： Thermoplastic moulding compositions comprising A) 1 to 60 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by emulsion polymerisation, in which at least 50% of the graft rubber particles (number) have a structure detectable via transmission electron microscopy photographs in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles has an irregular jagged structure such that 5 to 30 of such peaks are present per depicted particle, which particles differ from an idealised round particle (having a diameter d) by a diameter d+d/x, where x=3 to 15, B) 40 to 99 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by solution or bulk polymerisation and which has the morphology which is characteristic of bulk types of ABS, and optionally C) 0 to 200 parts by weight of at least one thermoplastic, rubber-free resin.

    摘要翻译： 包含A）1至60重量份的至少一种由乳液聚合制备的至少一种ABS型颗粒接枝橡胶聚合物，其中至少50％的接枝橡胶颗粒（数量）具有可检测的结构 透射电子显微镜照片，其中单个颗粒含有形成树脂的聚合物的不规则细胞夹杂物，并且颗粒表面具有不规则的锯齿状结构，使得每个所述颗粒存在5至30个这样的峰，该颗粒与理想化圆 颗粒（直径d）直径d + d / x，其中x = 3至15，B）40至99重量份的由溶液或体积产生的ABS型的至少一种颗粒接枝橡胶聚合物 聚合并且其具有ABS的主体类型特征的形态，并且任选地C）0至200重量份的至少一种热塑性橡胶树脂。