摘要:
The invention relates to a catalyst that comprises a metal M from the group of platinum, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally at least one promoter X2 that is selected from the group that consists of gallium, indium and thallium, a halogenated compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108. The invention also relates to the process for the preparation of this catalyst and a reforming process using said catalyst.
摘要:
A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite selected from IM-5 zeolite and zeolites with structure type MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IIIA metal and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
摘要:
The invention concerns a process for producing propylene, especially from a light steam cracking and/or catalytic cracking cut, preferably comprising both butenes and pentenes, said process comprising a step for moving bed catalytic cracking with a catalyst regeneration loop. The catalyst comprises at least one zeolite with a zeolitic composition with a Si/Al ratio which is preferably less than 130.The invention can produce a high conversion with a good yield of propylene at a high space velocity, meaning that the volume of catalyst can be reduced.
摘要:
A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite having channels the opening to which is defined by a ring of 10 oxygen atoms (10 MR), at least one zeolite having channels the opening to which is defined by a ring of 12 oxygen atoms (12 MR) and at least one porous mineral matrix. Said catalyst optionally also contains at least one group VIII metal. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
摘要:
The invention relates to a method for formulation of a synthetic gas oil or an additive for gas oil in which an alkyl-aromatic compound or a mixture of alkyl-aromatic compounds is selected based on at least one parameter that is selected from the group that consists of the number of cycles of the aromatic core, the number of alkyl chains that are grafted to the aromatic cycle, the length of the alkyl chain or chains, the position of the aromatic cycle or cycles on the alkyl chain or chains of said alkyl-aromatic compound or compounds such that the cetane number of the synthetic gas oil or the additive for gas oil is greater than 30. The invention also relates to a process for the production of alkyl-aromatic compounds for use as a gas oil or additive.
摘要:
A process for regeneration of a catalyst that comprises at least one EUO-structural-type zeolite in acid form and at least one hydro-dehydrogenating metal, used in a process for isomerization of a hydrocarbon feedstock that comprises aromatic compounds with eight carbon atoms, comprising at least a) a stage for eliminating a majority of the coke, deposited on said catalyst, by combustion in the presence of a gas that contains oxygen at a temperature that is less than or equal to 600° C., and b) a stage for oxychlorination of the product that is obtained from stage a), carried out between 200 and 550° C. in the presence of at least one gas mixture that contains at least oxygen, water and chlorine and/or at least one chlorinated compound, is described.
摘要:
This invention relates to a catalyst that contains at least one BOG-structured zeolite that comprises silicon and at least one Element T that is selected from the group that is formed by aluminum, iron, gallium and boron. The catalyst contains at least one metal that is selected from the group that is formed by the non-noble elements of groups VIB, VIIB and VIII of the periodic table. Said catalyst is used in a process for transalkylation of alkyl-aromatic hydrocarbons such as toluene and the alkyl-aromatic compounds with at least 9 carbon atoms.
摘要:
The invention relates to a process for production of propylene in particular from a C4 and/or C5 cut from steam cracking and/or catalytic cracking, preferably comprising both butenes and pentenes, said process comprising at least one oligomerization stage, followed by a stage of catalytic cracking of the oligomers formed.Preliminary oligomerization, in particular of a wide fraction of the charge, makes it possible to optimize the yields, the conversion, and the selectivity for propylene, relative to direct cracking. It also makes it possible for cracking to be carried out in a fixed, moving, or fluidized bed, optionally with co-production of oligomers for uses other than the production of propylene.
摘要:
A reaction device with staged zones making it possible to implement strongly endothermic or exothermic reactions. The device reduces the differences in catalytic activity between these zones using an addition of fresh or regenerated catalyst at the inlet of each reaction zone and provides an integrated heat exchanger. A process of chemical conversion employs the device for gas-phase and/or liquid-phase exothermic or endothermic reactions, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.
摘要:
This invention relates to a staged-zone reactor of the axial-flow type that makes it possible to implement strongly endothermic or exothermic reactions. The reactor comprises a constriction of the catalytic bed between an upper zone (3a) and a lower zone (3b), making it possible to house in the reactor a heat exchanger for the intermediate heating or cooling of the effluents. Process of chemical conversion using this reactor for exothermic or endothermic reactions in the gas and/or liquid phase, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.