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    Catalytic conversion of hydrofluoroalkanol to hydrofluoroalkene
    51.
    发明授权
    Catalytic conversion of hydrofluoroalkanol to hydrofluoroalkene 有权
    氢氟烷醇催化转化成氢氟烯烃

    公开(公告)号：US07026520B1

    公开(公告)日：2006-04-11

    申请号：US11006922

    申请日：2004-12-08

    申请人： Sudip Mukhopadhyay ,  HsuehSung Tung ,  Haridasan K. Nair

    发明人： Sudip Mukhopadhyay ,  HsuehSung Tung ,  Haridasan K. Nair

    IPC分类号： C07C17/00 ,  C07C17/08 ,  C07C21/18 ,  C07C23/00 ,  C07C25/13

    CPC分类号： C07C17/00 ,  C07C17/25 ,  C07C21/18

    摘要： Methane is used as the selective dehydrating agent for the production of 2,3,3,3-tetrafluoro-1-propene (R1234yf) from 2,2,3,3,3-pentafluoro-1-propanol. Supported transition metal catalysts are prepared and used for this reaction with high activity. Almost 58% selectivity to R1234yf is obtained at an alcohol conversion level of 60% using unsupported Ni-mesh as the catalyst. Pd and Pt show almost similar level of conversion; however, the selectivity to the desired product is low. The activity of the metal catalyst was found to be a function of the type of support material, activated carbon showing better activity than alumina. Different important process parameters such as temperature, pressure, and contact time are studied to optimize the process. High pressure and temperature are deleterious to the rate of 1234yf formation; yet, the highest yield to 1234yf is obtained while performing a reaction at 494° C. with a contact time of 23 sec.

    摘要翻译： 甲烷用作用于从2,2,3,3,3-五氟-1-丙醇生产2,3,3,3-四氟-1-丙烯（R1234yf）的选择性脱水剂。 制备负载型过渡金属催化剂，并以高活性用于该反应。 使用未负载的Ni-网作为催化剂，在60％的醇转化率下获得对R1234yf几乎58％的选择性。 Pd和Pt显示几乎相似的转化水平; 然而，对所需产物的选择性低。 发现金属催化剂的活性是支撑材料的类型的函数，活性炭表现出比氧化铝更好的活性。 研究了不同的重要工艺参数，如温度，压力和接触时间，以优化工艺。 高压和高温对于1234yf的形成是有害的; 然而，在494℃下以23秒的接触时间进行反应，获得了对1234yf的最高产率。

    Processes for synthesis of 1,3,3,3-tetrafluoropropene
    52.
    发明申请
    Processes for synthesis of 1,3,3,3-tetrafluoropropene 有权
    合成1,3,3,3-四氟丙烯的方法

    公开(公告)号：US20060030744A1

    公开(公告)日：2006-02-09

    申请号：US11118530

    申请日：2005-04-29

    申请人： Sudip Mukhopadhyay ,  Haridasan Nair ,  HsuehSung Tung ,  Michael Van Der Puy

    发明人： Sudip Mukhopadhyay ,  Haridasan Nair ,  HsuehSung Tung ,  Michael Van Der Puy

    IPC分类号： C07C17/087

    CPC分类号： C07C17/06 ,  C07C17/04 ,  C07C17/206 ,  C07C17/21 ,  C07C17/25 ,  C07C21/18 ,  C07C19/14 ,  C07C19/16 ,  C07C19/01 ,  C07C19/10

    摘要： Disclosed in one embodiment is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises (a) reacting a compound of formula (I) X1X2 with a compound of formula (II) CF3CH═CH2 to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2, wherein X1 and X2 are each independently selected from the group consisting of hydrogen, chlorine, bromine and iodine, provided that X1 and X2 are not both hydrogen; (b) when X2 in formula (III) is not fluorine, fluorinating the compound of formula (III) to produce a reaction product comprising a compound of formula (III) wherein X1 is as described above and X2 is fluorine; and (c) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene. In another embodiment, the process comprises (a) reacting chlorine with a compound of formula (I) CH3CH═CH2 to produce a reaction product comprising a compound of formula (II) CCl3CHC1CH2C1; (b) fluorinating the compound of formula (II) to produce a reaction product comprising a compound of formula (III) CF3CHC1CH2F; and (c) exposing said compound of said formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.

    摘要翻译： 在一个实施方案中公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括（a）使式（I）化合物X 1，X 2， 与式（II）化合物CF 3 CH-CH 2取代，生成包含式（III）化合物的反应产物CF 3 其中X 1和X 2都是（CH 2）2 CH 2，其中X 1和X 2都是 各自独立地选自氢，氯，溴和碘，条件是X 1和X 2都不是氢; （b）当式（III）中的X 2不是氟时，氟化式（III）化合物以产生包含式（III）化合物的反应产物，其中X 1， / SUP>如上所述，X 2是氟; 和（c）将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。 在另一个实施方案中，该方法包括（a）使氯与式（I）CH 3 CH-CH 2 2的化合物反应以产生包含式 （II）CCl 3 CHClCH 2 C 1; （b）氟化式（II）化合物以产生包含式（III）化合物的反应产物：CF 3 CHClCH 2 F; 和（c）将所述式（III）的所述化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

    Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof
    56.
    发明授权
    Compositions, coatings and films for tri-layer patterning applications and methods of preparation thereof 有权
    用于三层图案化应用的组合物，涂料和膜及其制备方法

    公开(公告)号：US08642246B2

    公开(公告)日：2014-02-04

    申请号：US11838854

    申请日：2007-08-14

    申请人： Joseph Kennedy ,  Songyuan Xie ,  Kim Do ,  Sudip Mukhopadhyay

    发明人： Joseph Kennedy ,  Songyuan Xie ,  Kim Do ,  Sudip Mukhopadhyay

    IPC分类号： G03F7/075 ,  G03F7/11 ,  C08L83/06

    CPC分类号： G03F7/0752 ,  C08G77/20 ,  C08G77/70 ,  C08L83/04 ,  C08L83/06 ,  C09D183/04 ,  G03F7/091 ,  G03F7/11 ,  H01L21/02126 ,  H01L21/02216 ,  H01L21/02282 ,  H01L21/3122 ,  C08L2666/44

    摘要： Compositions for use in tri-layer applications are described herein, wherein the composition has a matrix and includes: a formulated polymer comprising at least one type of silicon-based moiety forming the matrix of the polymer, a plurality of vinyl groups coupled to the matrix of the polymer, and a plurality of phenyl groups coupled to the matrix of the polymer, at least one condensation catalyst, and at least one solvent. Tri-layer structures are also contemplated herein that comprise an organic underlayer (first layer), antireflective compositions and/or films contemplated herein (second layer) and a photoresist material (third layer) that are coupled to one another. Methods of producing a composition for tri-layer patterning applications includes: providing a formulated polymer comprising at least one type of silicon-based moiety forming the matrix of the polymer, a plurality of vinyl groups coupled to the matrix of the polymer, and a plurality of phenyl groups coupled to the matrix of the polymer, providing at least one condensation catalyst, providing at least one solvent, providing at least one pH modifier, blending the formulated polymer and part of the at least one solvent in a reaction vessel to form a reactive mixture; and incorporating the at least one pH modifier, the at least one condensation catalyst and the remaining at least one solvent into the reactive mixture to form the composition.

    摘要翻译： 本文描述了用于三层应用的组合物，其中所述组合物具有基质，并且包括：配制的聚合物，其包含形成聚合物基质的至少一种类型的硅基部分，多个与基质偶联的乙烯基 的聚合物，以及与聚合物的基质偶联的多个苯基，至少一种缩合催化剂和至少一种溶剂。 本文还涵盖三层结构，其包括彼此耦合的有机底层（第一层），抗反射组合物和/或本文考虑的抗反射组合物（第二层）和光致抗蚀剂材料（第三层）。 制备用于三层图案化应用的组合物的方法包括：提供配制的聚合物，其包含形成聚合物基质的至少一种类型的硅基部分，与聚合物基质偶联的多个乙烯基，以及多个 提供至少一种缩合催化剂，提供至少一种溶剂，提供至少一种pH调节剂，将配制的聚合物和部分至少一种溶剂混合在反应容器中以形成 反应性混合物 并将至少一种pH调节剂，至少一种缩合催化剂和剩余的至少一种溶剂掺入到反应混合物中以形成组合物。

    PROCESS FOR SYNTHESIS OF FLUORINATED OLEFINS
    59.
    发明申请
    PROCESS FOR SYNTHESIS OF FLUORINATED OLEFINS 有权
    合成氟化烯烃的方法

    公开(公告)号：US20090099396A1

    公开(公告)日：2009-04-16

    申请号：US12249958

    申请日：2008-10-12

    申请人： Sudip Mukhopadhyay ,  Cheryl L. Bortz ,  Barbara A. Light ,  Cheryl L. Cantlon ,  Robert C. Johnson

    发明人： Sudip Mukhopadhyay ,  Cheryl L. Bortz ,  Barbara A. Light ,  Cheryl L. Cantlon ,  Robert C. Johnson

    IPC分类号： C07C17/20

    CPC分类号： C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C21/18 ,  C07C19/08

    摘要： Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise: (a) reacting a compound of formula (I) X1X2  (I) with a compound of formula (II) CX1X2X3CX1═CX1X2  (II) to produce a reaction product comprising a compound of formula (III) CF3CHX1CH2X2  (III), and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV) CF3CZ=CH2  (IV) wherein X1, X2, and X3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X1 and X2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F.

    摘要翻译： 公开了用于合成氟化烯烃的方法，特别优选的实施方案中，在不饱和的非末端碳上具有F的四氟化烯烃如2,3,3,3-四氟丙烯。 根据一个实施方案的本发明的优选方法通常包括：（a）使式（I）化合物<？in-line-formula description =“In-Line Formulas”end =“lead”→> X1X2 I）<？in-line-formula description =“In-line formula”end =“tail”？>与式（II）的化合物<？in-line-formula description =“In-line Formulas”end =“ 引线“→CX1X2X3CX1-CX1X2（II）<？在线公式描述=”内联式“末端=”尾“→产生包含式（III）化合物的反应产物 -formulae description =“In-line Formulas”end =“lead”？> CF3CHX1CH2X2（III）和<？in-line-formula description =“In-line Formulas”end =“tail”？>（b） 式（III）化合物与有效将所述式（III）化合物转化成式（IV）化合物的反应条件<β在线式描述=“在线式”末端=“铅”→CF 3 CZ = CH2（IV）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X1，X2和X3各自独立 式（I）中的X 1和X 2不同时为氢，Z为Cl，I，Br或F时，选自氢，氯，溴，氟和碘组成的组。