公开(公告)号：US20050038137A1

公开(公告)日：2005-02-17

申请号：US10488434

申请日：2002-09-03

Applicant: Toshio Yoshihara ,  Takahiro Niimi

Inventor： Toshio Yoshihara ,  Takahiro Niimi

IPC: C09D4/00 ,  C09D4/06 ,  G02B1/10 ,  G02B1/11 ,  C08K9/00 ,  C08K3/00 ,  C08K3/18 ,  C08K3/22 ,  C08K3/34

CPC classification number: C09D4/00 ,  C09D4/06 ,  G02B1/105 ,  G02B1/111 ,  G02B1/113 ,  G02B1/14

Abstract: The present invention provides a coating composition capable of forming a fluorine-containing coating layer having a low refractive index and a high hardness, a coating layer formed by using the coating composition, an anti-reflecting layer using the coating layer and an anti-reflecting film and an image display device to which the anti-reflecting layer is applied. The coating composition according to the present invention comprises (A) a binder system containing a fluorine-containing component (a) having one or both of a functional group which can be cured by ionizing radiation and a polar group which can be heat-cured, and contains both an ionizing radiation-curable group and a heatcurable polar group as a whole and (B) an inorganic superfine particle of the order of submicron in size which can be dispersed in a colloidal state in a liquid medium for preparing a coating liquid. The coating layer formed using this coating composition is preferable for forming a light-transmitting layer, particularly, a low-refractive index layer 20, constituting a monolayer type or multilayer type anti-reflecting layer 17.

Abstract translation: 本发明提供一种能够形成低折射率，高硬度的含氟涂层的涂料组合物，使用该涂料组合物形成的涂层，使用该涂层的防反射层和防反射层 胶片和应用了抗反射层的图像显示装置。 根据本发明的涂料组合物包含（A）含有可以通过电离辐射固化的官能团和可以被热固化的极性基团中的一个或两个的含氟组分（a）的粘合剂体系， 并且包含电离辐射固化基团和可热固化的极性基团作为整体，（B）尺寸为亚微米级的无机超细颗粒，其可以在胶体状态下分散在用于制备涂布液体的液体介质中。 使用该涂料组合物形成的涂层优选用于形成构成单层型或多层型抗反射层17的透光层，特别是低折射率层20。

公开(公告)号：US06682594B2

公开(公告)日：2004-01-27

申请号：US10162193

申请日：2002-06-05

Applicant: Toshio Yoshihara ,  Nobuko Takahashi ,  Satoshi Mitamura

Inventor： Toshio Yoshihara ,  Nobuko Takahashi ,  Satoshi Mitamura

IPC: C09D100

CPC classification number: H01J9/02 ,  C09D5/00 ,  H01J11/12 ,  H01J11/40 ,  H01J2211/40

Abstract: A process for making a functional film by adding a magnesium alkoxide and a diethanolamine, which can dissolve or disperse the magnesium alkoxide, in an organic solvent followed by allowing hydrolysis of the magnesium alkoxide to proceed in a rate-controlling manner wherein the magnesium alkoxide is dissolved or dispersed in the organic solvent. Water is added in no more than a stoichiometric amount to the solution or dispersion partially to hydrolyze the magnesium alkoxide. The partial hydrolyzate solution is matured to grow magnesium oxide and/or magnesium hydroxide particles, resulting in a stable sol solution.

Abstract translation: 通过将可溶解或分散镁醇盐的烷氧基镁和二乙醇胺加入到有机溶剂中，然后使镁醇盐水解以使镁醇盐为镁盐的速率控制方式进行水解制备功能膜的方法 溶解或分散在有机溶剂中。 水以不超过化学计量的量与溶液或分散体部分加入以水解醇盐。 部分水解产物溶液成熟以生长氧化镁和/或氢氧化镁颗粒，产生稳定的溶胶溶液。

公开(公告)号：US06656985B1

公开(公告)日：2003-12-02

申请号：US09640175

申请日：2000-08-17

Applicant: Toshio Yoshihara ,  Kiyoshi Itou ,  Kazuhiko Nakamura ,  Minoru Furukawa ,  Abul Iqbal ,  Zhimin Hao

Inventor： Toshio Yoshihara ,  Kiyoshi Itou ,  Kazuhiko Nakamura ,  Minoru Furukawa ,  Abul Iqbal ,  Zhimin Hao

IPC: C08K534

CPC classification number: C08K5/0041 ,  C09B67/0078 ,  C09B67/0091

Abstract: There are provided a pigment-containing coloring material stably dispersible in a high concentration in various organic solvents, and a process for producing the same. The production process of the coloring material is characterized by comprising the steps of: providing a solution comprising (1) a soluble pigment precursor which is convertible into an insoluble pigment, (2) a solvent capable of dissolving the soluble pigment precursor therein, and (3) a stabilizing agent comprising an organic compound having a structure or a functional group capable of stabilizing the dispersibility of the insolubilized pigment in the solvent; and converting said soluble pigment precursor into an insoluble pigment to obtain the coloring material containing the insolubilized pigment dispersed stably in the solvent.

Abstract translation: 提供了在各种有机溶剂中高浓度稳定分散的含颜料的着色材料及其制造方法。 着色材料的制造方法的特征在于包括以下步骤：提供包含（1）可溶于颜料的可溶性颜料前体的溶液，（2）能够溶解可溶性颜料前体的溶剂和（ 3）稳定剂，其包含具有能够稳定不溶性颜料在溶剂中的分散性的结构或官能团的有机化合物; 并将所述可溶性颜料前体转化为不溶性颜料，得到含有稳定分散在溶剂中的不溶性颜料的着色材料。

公开(公告)号：US06638606B2

公开(公告)日：2003-10-28

申请号：US10046171

申请日：2002-01-16

Applicant: Toshio Yoshihara ,  Yurie Ota ,  Nobuko Takahashi ,  Noboru Kunimine ,  Satoshi Shioda ,  Mikiko Hojo

Inventor： Toshio Yoshihara ,  Yurie Ota ,  Nobuko Takahashi ,  Noboru Kunimine ,  Satoshi Shioda ,  Mikiko Hojo

IPC: B32B500

CPC classification number: C08J7/047 ,  C08F2/44 ,  Y10S428/913 ,  Y10S428/915 ,  Y10S428/916 ,  Y10T428/1471 ,  Y10T428/1486 ,  Y10T428/24364 ,  Y10T428/24372 ,  Y10T428/24893 ,  Y10T428/249999 ,  Y10T428/25 ,  Y10T428/265 ,  Y10T428/28 ,  Y10T428/2804 ,  Y10T428/2848

Abstract: A hardcoat for a plastic substrate film is provided which has good suitability for printing and satisfactory hardness, can prevent influence of the deformation of a plastic substrate film from extending to the hardcoat, and is resistant to cracking and peeling. The hardcoat is produced from a coating component containing one or more organic components having a polymerizable functional group and an inorganic filler, at least one of the organic components being free from a hydrogen bond-forming group. In the hard coat, the content of the inorganic filler in the surface of the hardcoat is higher than that in the interior of the hardcoat. The hardcoat can be applied to antireflection films and hologram labels.

公开(公告)号：US06376060B1

公开(公告)日：2002-04-23

申请号：US09401407

申请日：1999-09-22

Applicant: Toshio Yoshihara ,  Yurie Ota ,  Nobuko Takahashi ,  Noboru Kunimine ,  Satoshi Shioda ,  Mikiko Hojo

Inventor： Toshio Yoshihara ,  Yurie Ota ,  Nobuko Takahashi ,  Noboru Kunimine ,  Satoshi Shioda ,  Mikiko Hojo

IPC: B32B516

CPC classification number: C08J7/047 ,  C08F2/44 ,  Y10S428/913 ,  Y10S428/915 ,  Y10S428/916 ,  Y10T428/1471 ,  Y10T428/1486 ,  Y10T428/24364 ,  Y10T428/24372 ,  Y10T428/24893 ,  Y10T428/249999 ,  Y10T428/25 ,  Y10T428/265 ,  Y10T428/28 ,  Y10T428/2804 ,  Y10T428/2848

Abstract: A hardcoat for a plastic substrate film is provided which has good suitability for printing and satisfactory hardness, can prevent influence of the deformation of a plastic substrate film from extending to the hardcoat, and is resistant to cracking and peeling. The hardcoat is produced from a coating component containing one or more organic components having a polymerizable functional group and an inorganic filler, at least one of the organic components being free from a hydrogen bond-forming group. In the hard coat, the content of the inorganic filler in the surface of the hardcoat is higher than that in the interior of the hardcoat. The hardcoat can be applied to antireflection films and hologram labels.

Abstract translation: 提供了一种用于塑料基材薄膜的硬涂层，其对印刷具有良好的适用性和令人满意的硬度，可以防止塑料基材薄膜变形对硬涂层的影响，并且耐开裂和剥离。 硬涂层由含有一种或多种具有可聚合官能团和无机填料的有机组分的涂料组分制备，至少一种有机组分不含氢键形成基团。 在硬涂层中，硬涂层表面中的无机填料的含量高于硬涂层的内部。 硬涂层可以应用于抗反射膜和全息图标签。

公开(公告)号：US06218061B1

公开(公告)日：2001-04-17

申请号：US09352869

申请日：1999-07-13

Applicant: Junichi Hanna ,  Kyoko Kogo ,  Toshio Yoshihara ,  Hiroki Maeda

Inventor： Junichi Hanna ,  Kyoko Kogo ,  Toshio Yoshihara ,  Hiroki Maeda

IPC: G03G5047

CPC classification number: C09K19/322 ,  C09K19/0225 ,  Y10S428/913 ,  Y10T428/1055

Abstract: There is provided a ferroelectric charge-transport liquid crystal material comprising a liquid crystal compound, the liquid crystal material having a carrier mobility of not less than 10−5 cm2/Vs. There are further provided an image display device, an electroluminescence device, a photoconductor, a space light modulating device, a thin-film transistor, a photosensor, and a photorefractive device each comprising the ferroelectric charge-transport liquid crystal material.

Abstract translation: 提供一种包含液晶化合物的铁电电荷传输液晶材料，该液晶材料的载流子迁移率不低于10-5cm 2 / V。另外还提供了一种图像显示装置，电致发光装置， 光电导体，空间光调制装置，薄膜​​晶体管，光电传感器和光折射装置，各自包含铁电电荷输送液晶材料。

公开(公告)号：US5976236A

公开(公告)日：1999-11-02

申请号：US621581

申请日：1996-03-26

Applicant: Toshio Yoshihara ,  Nobuko Takahashi ,  Satoshi Mitamura

Inventor： Toshio Yoshihara ,  Nobuko Takahashi ,  Satoshi Mitamura

IPC: B05D5/06 ,  C09D1/00 ,  C09D5/00 ,  C09D185/00 ,  G02B1/10 ,  G02B1/111 ,  H01J11/12 ,  H01J11/22 ,  H01J11/24 ,  H01J11/26 ,  H01J11/34 ,  H01J11/36 ,  H01J11/38 ,  H01J11/40 ,  H01J11/42 ,  H01J11/44 ,  H01J11/50 ,  B01J13/00 ,  C09C1/02

CPC classification number: H01J9/02 ,  C09D5/00 ,  H01J11/12 ,  H01J11/40 ,  H01J2211/40

Abstract: There are provided a coating composition that can satisfactorily form a film even at a low temperature by chemical means in a simple and stable manner, has excellent film strength, adhesion, protective effect and other properties in the form of a functional film and can form a functional film at a low cost, a process for producing the coating composition, a functional film, and a process for producing the functional films.A hydrolyzable reaction site is partially hydrolyzed to prepare a sol of a partial hydrolyzate which is then coated on a substrate. The coating is then baked to prepare a corresponding metal oxide film, thereby forming a thin protective layer. Since no hydrolyzate is precipitated in the sol of the partial hydrolyzate, excellent film strength, adhesion, protective effect and other properties are offered. The metallic compound having a hydrolyzable reaction site is selected from an organometal compound, such as a metal alkoxide, an organometal complex, and an organometal acid salt, and an inorganic metal compound, such as an inorganic metal salt. The functional film of the present invention can be utilized in a protective layer formed of, for example, magnesium oxide in a plasma display.

Abstract translation: 提供了一种即使在低温下以简单且稳定的方式通过化学方法令人满意地形成膜的涂料组合物，具有优异的膜强度，粘合性，保护效果以及功能膜形式的其它性能， 低成本的功能性膜，涂料组合物的制造方法，功能性膜以及功能膜的制造方法。 可水解的反应位点被部分水解，以制备部分水解产物的溶胶，然后将其涂布在基材上。 然后将涂层烘烤以制备相应的金属氧化物膜，由此形成薄的保护层。 由于在部分水解产物的溶胶中没有水解物析出，因此提供了优异的膜强度，粘附性，保护效果等特性。 具有可水解反应位点的金属化合物选自有机金属化合物如金属醇盐，有机金属络合物和有机金属酸盐，以及无机金属化合物如无机金属盐。 本发明的功能性膜可以用于例如等离子体显示器中的氧化镁形成的保护层。

公开(公告)号：US08617693B2

公开(公告)日：2013-12-31

申请号：US12696481

申请日：2010-01-29

Applicant: Saki Isono ,  Toshio Yoshihara

Inventor： Saki Isono ,  Toshio Yoshihara

IPC: B32B7/02 ,  G02B1/00 ,  C08K3/36 ,  C08G77/04

CPC classification number: G02B1/111 ,  G02B1/105 ,  G02B1/14 ,  G02B1/16 ,  G02B5/0247 ,  G02F1/133502 ,  Y10T428/24942 ,  Y10T428/249971 ,  Y10T428/249974 ,  Y10T428/259 ,  Y10T428/265 ,  Y10T428/2995

Abstract: An antireflection laminate for use mainly in displays such as LCDs and PDPs, which has a refractive index layer that has, while comprising hollow and solid particles, excellent abrasion resistance, a refractive index of 1.45 or less, and low reflectivity is disclosed. The refractive index layer is obtained by irradiating a refractive index layer forming composition with ionizing radiation, the composition including an ionizing radiation curable resin, a crosslinkable hollow particle having an inside that is porous or hollow and is covered with an outer shell layer and having a surface that is modified with a crosslinkable group(s), and a crosslinkable solid particle having an inside that is neither porous nor hollow and having a surface that is modified with a crosslinkable group(s). The crosslinkable groups comprise an ionizing radiation curable group each and have an identical structure or a very similar structure.

Abstract translation: 公开了一种主要用于LCD和PDP的显示器中的抗反射层压板，其具有折射率层，同时包含中空和固体颗粒，优异的耐磨性，折射率为1.45以下，反射率低。 折射率层是通过用折射率层形成组合物照射电离辐射获得的，该组合物包括电离辐射固化树脂，具有多孔或中空的内部的可交联的中空颗粒，并被外壳层覆盖，并具有 用可交联基团改性的表面，以及具有内部既不是多孔的也不是中空的且具有用可交联基团改性的表面的可交联固体颗粒。 可交联基团各自具有电离辐射可固化基团，并且具有相同的结构或非常相似的结构。

公开(公告)号：US08482750B2

公开(公告)日：2013-07-09

申请号：US11934422

申请日：2007-11-02

Applicant: Toshio Yoshihara

Inventor： Toshio Yoshihara

IPC: G06F15/00 ,  G06K1/00

CPC classification number: G06F3/1204 ,  G06F3/1213 ,  G06F3/1226 ,  G06F3/1263 ,  G06F3/1285 ,  H04L63/083 ,  H04L67/327 ,  H04N1/00915 ,  H04N1/32502

Abstract: A processing apparatus which is capable of releasing priority use of apparatuses that are reserved for priority use but are not actually used, even when a plurality of apparatuses are used by priority during a particular time period. Reservation records about reservations for priority use of apparatuses are stored in a master machine. In the master machine, it is determined whether or not all the apparatuses on a reservation cooperation list are exclusively reserved during the same time period, by referring to the reservation records. When all the apparatuses which are reserved for priority use during the same time period, the master machine sends an exclusive release permission command to each subordinate machine reserved for priority use during the same time period among all the apparatuses.

Abstract translation: 即使在特定时间段内优先使用多个装置的情况下，能够释放为了优先使用而没有实际使用的装置的优先使用的处理装置。 关于优先使用设备的预约的预约记录存储在主机中。 在主机中，通过参照预约记录来确定预留合作列表中的所有装置是否在同一时间段内被专门保留。 当在同一时间段内保留优先使用的所有设备时，主机在所有设备之间的相同时间段内向保留优先使用的每个下级机器发送排他性许可命令。

公开(公告)号：US08354162B2

公开(公告)日：2013-01-15

申请号：US12532680

申请日：2008-03-25

Applicant: Toshio Yoshihara ,  Akinobu Ushiyama ,  Ai Shinkai

Inventor： Toshio Yoshihara ,  Akinobu Ushiyama ,  Ai Shinkai

IPC: B32B3/00 ,  B32B5/16

CPC classification number: G02B1/10 ,  G02B5/0221 ,  G02B5/0242 ,  G02B5/0278 ,  Y10T428/24479 ,  Y10T428/24612 ,  Y10T428/25

Abstract: An anti-glare film having the following: an anti-glare layer which is provided on a transparent substrate film, has a concavo-convex shape on the outermost surface thereof, and has at least a concavo-convex layer formed by curing a curable resin composition, which composition has optically-transparent fine particles A that have an average particle diameter of 1 μm or more and 10 μm or less, reactive inorganic fine particles B that have an average particle diameter of 30 nm or more and 100 nm or less and reactive functional groups b on the surface thereof, and a binder component C that has reactive functional groups c; a skin layer which has a small number of the reactive inorganic fine particles B in an interface on the side opposite to the transparent substrate film side and in the vicinity of the interface; and a region which is situated nearer the transparent substrate film than the skin layer, in which the fine particles B are uniformly dispersed.

Abstract translation: 具有以下的防眩光膜：设置在透明基材膜上的防眩光层在其最外表面具有凹凸形状，并且至少具有通过固化可固化树脂形成的凹凸层 该组合物具有平均粒径为1μm以上且10μm以下的光学透明性微粒A，平均粒径为30nm以上且100nm以下的活性无机微粒B，以及 其表面上具有反应性官能团b和具有反应性官能团c的粘合剂组分C; 在与透明基板膜侧相反一侧并且在界面附近的界面中具有少量反应性无机微粒B的表皮层; 以及位于比透明基材膜更靠近微细颗粒B均匀分散的表皮层的区域。