Reclamation of alkanolamine solutions
    51.
    发明授权
    Reclamation of alkanolamine solutions 失效
    链烷醇胺溶液的回收

    公开(公告)号:US5108551A

    公开(公告)日:1992-04-28

    申请号:US628975

    申请日:1990-12-17

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    IPC分类号: C07C213/10

    CPC分类号: C07C213/10

    摘要: The present invention provides a method for purifying alkanolamine solutions which have lost at least a portion of their acid gas sorption capacity due to degradation of the alkanolamine into heat stable salts. Particularly, it has been found that the alkanolamine solution may be rejuvenated by charging the solution to the feed zone of a distillation column reactor at temperatures above about 160.degree. C. and pressure of less than about 2000 mm Hg.

    摘要翻译: 本发明提供一种纯化烷醇胺溶液的方法,该方法由于将链烷醇胺降解为热稳定盐而损失了其酸性气体吸附容量的至少一部分。 特别地,已经发现,通过在高于约160℃的温度和小于约2000mm Hg的压力下将溶液装入蒸馏塔反应器的进料区,可以使链烷醇胺溶液恢复活力。

    Catalytic visbreaking process
    52.
    发明授权
    Catalytic visbreaking process 失效
    催化减粘裂化工艺

    公开(公告)号:US5057204A

    公开(公告)日:1991-10-15

    申请号:US527673

    申请日:1990-05-21

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    摘要: The severity of visbreaking of an oil is increased without increasing the instability of the product by incorporating into the feedstock a catalyst preferably supported on a porous substrate. The catalyst is the elemental form or compound of an element selected from the group consisting of selenium, tellurium and sulfur.

    摘要翻译: 增加油的减粘裂化的严重性,而不会通过将优选负载在多孔基材上的催化剂引入原料而增加产物的不稳定性。 催化剂是选自硒,碲和硫的元素的元素形式或化合物。

    Catalytic cracking of heavy oils
    54.
    发明授权
    Catalytic cracking of heavy oils 失效
    重油催化裂化

    公开(公告)号:US4980049A

    公开(公告)日:1990-12-25

    申请号:US206237

    申请日:1988-06-10

    摘要: A catalytic cracking process operates with a getter additive present where hot catalyst meets heavy metals laden crude. The getter additive is a material which is selective for metals, and has a particle size/density such that the getter additive remains in the FCC unit for no more than 24 hours, and preferably is removed within one hour or less. Addition of 1-5 weight percent alumina having an average particle size of 10-40 microns will remove much of the metal content from the feed, and the metals laden additive will itself be rapidly removed from the FCC unit preventing migration of metal or degradation of the cracking operation due to the presence of metal. Preferably the additive is fine particles which are mixed with the hydrocarbon feed to the unit.

    摘要翻译: 催化裂化工艺与存在的吸附剂添加剂相结合,其中热催化剂满足载有重金属的原油。 吸气剂添加剂是对金属有选择性的材料,并且具有使吸附剂添加剂保留在FCC单元中不超过24小时的粒度/密度,优选在1小时以内除去。 加入平均粒径为10-40微米的1-5重量%的氧化铝将从进料中除去大部分金属含量,并且载有金属的添加剂本身将迅速从FCC装置中除去,从而防止金属的迁移或降解 由于存在金属而导致的开裂操作。 优选地,添加剂是与烃进料混合到该单元的细颗粒。

    Method for removing mercury from hydrocarbon oil by high temperature
reactive adsorption
    55.
    发明授权
    Method for removing mercury from hydrocarbon oil by high temperature reactive adsorption 失效
    通过高温反应吸附从烃油中去除汞的方法

    公开(公告)号:US4909926A

    公开(公告)日:1990-03-20

    申请号:US304635

    申请日:1989-02-01

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    摘要: A method is provided for removing mercury from hydrocarbon fluids by high temperature reactive adsorption. A hydrocarbon feed passed through an adsorbent mass including a reactive adsorbent such as silver or copper sulfide on an alumina support. The optimum temperature of the feed to be treated depends upon the 90% boiling points corresponding to heavier feeds. A hydrocarbon condensate feed may be drawn from a stabilizer column in a natural gas processing plant at a temperature in excess of 400.degree. F. If a metallic silver/alumina adsorbent is employed, the adsorbent may be regenerated through high temperature oxidation. Once oxidation is complete, the temperature is lowered in a reducing or inert atmosphere.

    Simultaneous removal of mercury and water from fluids
    56.
    发明授权
    Simultaneous removal of mercury and water from fluids 失效
    同时从流体中去除汞和水

    公开(公告)号:US4892567A

    公开(公告)日:1990-01-09

    申请号:US232194

    申请日:1988-08-15

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    摘要: A regenerable molecular sieve comprises 0.001-15% elemental silver or gold in or on zeolite A. The molecular sieve is capable of simultaneously removing mercury and water from a fluid. A method for impregenating zeolite A with elemental silver or gold comprising treating the zeolite A with a solution of a silver or gold salt of a carboxylic acid and heating the impregnated zeolite A at a temperature sufficient to decompose the salt is also provided. A method for simultaneously and repeatedly removing mercury and water from a hydrocarbon fluid by contacting the fluid with an effective amount of a molecular sieve comprising zeolite A and 0.001-15% elemental silver or gold and regenerating the zeolite A at elevated temperatures is also provided.

    摘要翻译: 可再生分子筛在沸石A中或沸石A上含有0.001-15%元素的银或金。分子筛能够同时从流体中除去汞和水。 还提供了用元素银或金来分解沸石A的方法,包括用羧酸银或金盐的溶液处理沸石A,并在足以分解盐的温度下加热浸渍的沸石A. 还提供了通过使流体与有效量的包含沸石A和0.001-15%元素银或金的分子筛接触并同时且重复地从烃流体中除去汞和水的方法,并在升高的温度下再生沸石A.

    Catalytic cracking of hydrocarbons
    57.
    发明授权
    Catalytic cracking of hydrocarbons 失效
    碳氢化合物的催化裂化

    公开(公告)号:US4828680A

    公开(公告)日:1989-05-09

    申请号:US145952

    申请日:1988-01-20

    IPC分类号: C10G11/18

    摘要: Combustible carbonaceous particles such as particles of sponge coke or coal are incorporated with the circulating inventory of cracking catalyst in a fluid catalytic cracking unit. The carbonaceous particles selectively sorb metal contaminants in the feed, thereby extending catalyst life, and they also serve to reduce NO.sub.x emissions in certain instances. The sorbed metals values may be recovered as the carbonaceous particles are burned.

    摘要翻译: 可燃的碳质颗粒如海绵焦炭或煤的颗粒与流化催化裂化装置中的裂解催化剂的循环库存结合。 碳质颗粒选择性地吸附进料中的金属污染物,从而延长催化剂寿命,并且它们还用于在某些情况下减少NOx排放。 当碳质颗粒燃烧时,可以回收吸附的金属值。

    Process for removing mercury vapor and chemisorbent composition therefor
    58.
    发明授权
    Process for removing mercury vapor and chemisorbent composition therefor 失效
    去除汞蒸汽及其化学吸附剂组合物的方法

    公开(公告)号:US4814152A

    公开(公告)日:1989-03-21

    申请号:US107739

    申请日:1987-10-13

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    IPC分类号: B01D53/86 C10G25/00 B01D53/34

    CPC分类号: B01D53/8665 C10G25/003

    摘要: A process and composition for removing elemental mercury vapor from a gas such as natural gas is disclosed. The mercury-containing gas is contacted with a solid support such as carbon containing elemental sulfur and at least one metal which catalyzes the reaction: 2 Hg+S.sub.2 .revreaction.2 HgS.

    摘要翻译: 公开了一种用于从天然气等气体中除去元素汞蒸汽的方法和组合物。 含汞气体与固体载体如含碳元素硫和至少一种催化反应的金属接触:2 Hg + S2 - > <-2 HgS。