公开(公告)号：US07098289B2

公开(公告)日：2006-08-29

申请号：US10613457

申请日：2003-07-03

Applicant: Hans-Josef Laas ,  Reinhard Halpaap ,  Frank Richter ,  Jürgen Köcher

Inventor： Hans-Josef Laas ,  Reinhard Halpaap ,  Frank Richter ,  Jürgen Köcher

IPC: C08G18/20

CPC classification number: C08G18/2036 ,  C07D229/00 ,  C08G18/027 ,  C08G2150/00 ,  C08G2150/20

Abstract: The invention relates to novel compounds containing uretdione groups, to a process for preparing them by dimerizing aliphatic and/or cycloaliphatic isocyanates containing exclusively secondary and/or tertiary isocyanate groups and also to the use of uretdione polyisocyanates obtainable by this process from diisocyanates containing exclusively secondary and/or tertiary isocyanate groups as a starting component for polyurethane polymers, in particular as an isocyanate component in the preparation of uretdione powder coating crosslinkers.

Abstract translation: 本发明涉及含有脲二酮基团的新化合物，其通过二元化仅含有仲和/或叔异氰酸酯基团的脂族和/或脂环族异氰酸酯制备它们的方法，还涉及使用通过该方法获得的脲二酮多异氰酸酯，该二异氰酸酯仅含有二级 和/或叔异氰酸酯基团作为聚氨酯聚合物的起始组分，特别是作为脲二酮粉末涂料交联剂制备中的异氰酸酯组分。

公开(公告)号：US07087676B2

公开(公告)日：2006-08-08

申请号：US10874716

申请日：2004-06-23

Applicant: Jan Mazanek ,  Reinhard Halpaap ,  Markus Mechtel ,  Thomas Klimmasch ,  Christoph Thiebes

Inventor： Jan Mazanek ,  Reinhard Halpaap ,  Markus Mechtel ,  Thomas Klimmasch ,  Christoph Thiebes

IPC: C08G18/80 ,  C07C275/08 ,  C07C275/12 ,  C07C275/14 ,  C07C275/16

CPC classification number: C08G18/6216 ,  C08G18/792 ,  C08G18/807 ,  C09D175/04

Abstract: Blocked polyisocyanates and one-component stoving systems containing these blocked polyisocyanates, and the preparation thereof and their use for the preparation of lacquers, paints, adhesives and elastomers, wherein blocked polyisocyanates are prepared by reacting polyisocyanates with secondary amines corresponding to the formula wherein R1—R4 can be identical or different and denote hydrogen, C1–C6-alkyl or cycloalkyl, R5 denotes C1–C10-alkyl, C3–C10-cycloalkyl, y denotes a number from 2 to 8, and B represents wherein R6–R8 can be identical or different and independently of one another denote C1–6-alkyl and/or C3–C6-cycloalkyl, R9 denotes hydrogen or C1–6-alkyl or C3–C6-cycloalkyl.

Abstract translation: 封闭的多异氰酸酯和含有这些封端的多异氰酸酯的单组分烘烤系统及其制备及其用于制备漆，油漆，粘合剂和弹性体的用途，其中封端的多异氰酸酯是通过使多异氰酸酯与对应于下式的仲胺反应来制备的： 可以相同或不同，表示氢，C 1 -C 6 - 烷基或环烷基， R 5表示C 1 -C 10 - 烷基，C 3 -C 10烷基，C 3 -C 10 - 烷基，C 3 -C 10 - > - 环烷基，y表示2至8的数，B表示其中R 6 -R 8可以相同或不同，并且彼此独立地表示C _{表示氢或C 1 -C 6 - 烷基或C 3 -C 6 - 环烷基。}

公开(公告)号：US20060173152A1

公开(公告)日：2006-08-03

申请号：US11333575

申请日：2006-01-17

Applicant: Frank Richter ,  Hans-Josef Laas ,  Reinhard Halpaap ,  Andreas Hecking

Inventor： Frank Richter ,  Hans-Josef Laas ,  Reinhard Halpaap ,  Andreas Hecking

IPC: C08G18/16

CPC classification number: C08G18/027 ,  C08G18/0852

Abstract: The invention relates to a process for preparing polyisocyanates having a high uretdione group content by phosphine-catalysed isocyanate oligomerization in the presence of organic carbonates and/or nitriles.

Abstract translation: 本发明涉及在有机碳酸酯和/或腈的存在下通过膦催化的异氰酸酯低聚制备具有高的脲二酮基含量的多异氰酸酯的方法。

公开(公告)号：US07067654B2

公开(公告)日：2006-06-27

申请号：US10719175

申请日：2003-11-21

Applicant: Frank Richter ,  Reinhard Halpaap ,  Hans-Josef Laas ,  Andreas Hecking

Inventor： Frank Richter ,  Reinhard Halpaap ,  Hans-Josef Laas ,  Andreas Hecking

IPC: C07D229/00

CPC classification number: C08G18/027 ,  C07D229/00 ,  C08G18/168

Abstract: The invention relates to the use of cycloalkylphosphines as catalysts for isocyanate dimerization and to a process for preparing polyisocyanates containing uretdione groups.

Abstract translation: 本发明涉及环烷基膦用作异氰酸酯二聚化的催化剂以及制备含有脲二酮基团的多异氰酸酯的方法。

公开(公告)号：US20050107565A1

公开(公告)日：2005-05-19

申请号：US10966792

申请日：2004-10-15

Applicant: Christoph Thiebes ,  Reinhard Halpaap ,  Beate Baumbach ,  Dieter Mager ,  Christian Fussel

Inventor： Christoph Thiebes ,  Reinhard Halpaap ,  Beate Baumbach ,  Dieter Mager ,  Christian Fussel

IPC: C07C275/62 ,  C07B61/00 ,  C07C211/02 ,  C07C263/18 ,  C07C265/14 ,  C07C275/00 ,  C08G18/00 ,  C08G18/02 ,  C08G18/28 ,  C08G18/32 ,  C08G18/78 ,  C08G18/79 ,  C08G18/80 ,  C08J7/04 ,  C09D175/04 ,  C09D175/12

CPC classification number: C08G18/7887 ,  C08G18/281 ,  C08G18/2865 ,  C08G18/7831 ,  C08G18/792 ,  C08G18/808

Abstract: Storage-stable blocked polyisocyanates prepared by reacting one or more polyisocyanates with one or more biuretizing agents and optionally, catalysts such that in the blocked end product there are 5-45 equivalent percent of biuret groups according to formula (I) based on the sum total of all free and blocked NCO groups; optionally modifying the resulting biuret polyisocyanates with the aid of isocyanate-reactive compounds and/or catalysts, with further reaction of free NCO groups; and subsequently blocking at least 95 mol percent of the remaining free NCO groups with a blocking agent according to the formula R1R2NH, where R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals. The blocked polyisocyanates can be used to make polyurethane polymers and coating compositions, which can be used to coat substrates.

Abstract translation: 通过使一种或多种多异氰酸酯与一种或多种缩二脲化试剂和任选的催化剂反应制备的储存稳定的封端多异氰酸酯，使得在封端产物中，根据式（I），基于总计的总数为5-45当量的缩二脲基团 的所有自由和封闭的NCO团体; 任选地在异氰酸酯反应性化合物和/或催化剂的帮助下改性所得缩二脲多异氰酸酯，进一步反应游离NCO基团; 随后用封闭剂将根据式R 1 R 2 NH封闭至少95mol％剩余的游离NCO基团，其中R 1， 各自独立地是脂族或脂环族C 1 -C 12烷基。 封端的多异氰酸酯可用于制备可用于涂覆基材的聚氨酯聚合物和涂料组合物。

公开(公告)号：US06713556B2

公开(公告)日：2004-03-30

申请号：US10275088

申请日：2002-11-01

Applicant: Eberhard König ,  Reinhard Halpaap ,  Thomas Klimmasch ,  Hans-Ulrich Meier-Westhues ,  Harald Mertes ,  Joachim Schüll ,  Bernd Steinhilber

Inventor： Eberhard König ,  Reinhard Halpaap ,  Thomas Klimmasch ,  Hans-Ulrich Meier-Westhues ,  Harald Mertes ,  Joachim Schüll ,  Bernd Steinhilber

IPC: C08J300

CPC classification number: C08G18/807 ,  C09D175/04 ,  C08L2666/16

Abstract: The invention relates to particular mixtures of polyisocyanates which are blocked with 3,5-dimethylpyrazole, and to the use thereof as crosslinking component in single-component stoving lacquers, especially automotive clear lacquers.

Abstract translation: 本发明涉及用3,5-二甲基吡唑封端的特定的多异氰酸酯混合物，以及其作为单组分烘烤漆中的交联组分的用途，特别是汽车清漆。

公开(公告)号：US06590098B2

公开(公告)日：2003-07-08

申请号：US10144643

申请日：2002-05-13

Applicant: Frank Richter ,  Reinhard Halpaap ,  Jürgen Köcher ,  Hans-Josef Laas

Inventor： Frank Richter ,  Reinhard Halpaap ,  Jürgen Köcher ,  Hans-Josef Laas

IPC: C07D25134

CPC classification number: C08G18/027 ,  C08G18/022 ,  C08G18/2036 ,  C08G18/807

Abstract: The invention relates to a method of preparing an aliphatic polyisocyanate by conversion of an aliphatic diisocyanate to a polyisocyanates in the presence of a catalyst, wherein the catalyst contains a saline compound having 5 to 97.1 wt. % of a 1,2,3- and/or a 1,2,4-triazolate (calculated as C2N3, molecular weight 66) in the anion, the isocyanates thus prepared and the polyurethane paints and coatings containing them.

公开(公告)号：US06426414B1

公开(公告)日：2002-07-30

申请号：US09312180

申请日：1999-05-14

Applicant: Hans-Josef Laas ,  Reinhard Halpaap ,  Christian Wamprecht

Inventor： Hans-Josef Laas ,  Reinhard Halpaap ,  Christian Wamprecht

IPC: C07C27166

CPC classification number: C09D175/04 ,  C08G18/222 ,  C08G18/283 ,  C08G18/6254 ,  C08G18/706 ,  C08G18/7837 ,  C08G18/792

Abstract: The present invention relates to water dispersible polyisocyanate mixtures prepared from aliphatic, cycloaliphatic, araliphatic and/or aromatic diisocyanates and having a) an average isocyanate functionality of at least 2.0, b) a content of 5.0 to 25.0 wt. %, based on resin solids, of isocyanate groups (calculated as NCO; molecular weight=42) and c) a content of 2 to 50 wt. %, based on resin solids, of ethylene oxide units calculated as C2H2O; molecular weight 44) incorporated within polyether chains containing an average of 5 to 35 ethylene oxide units, wherein at least 60 mole % of the polyether chains are connected via allophanate groups to two polyisocyanate molecules which are each prepared from at least two diisocyanate molecules. The present invention also relates to a process for the preparation of these water dispersible polyisocyanate.

Abstract translation: 本发明涉及由脂族，脂环族，芳脂族和/或芳族二异氰酸酯制备的水分散性多异氰酸酯混合物，并且具有至少2.0的平均异氰酸酯官能度，b）5.0至25.0重量％的含量。 ％，基于树脂固体的异氰酸酯基团（以NCO计算;分子量= 42），和c）2〜50重量％的含量。 ％，基于树脂固体，以C 2 H 2 O计算的环氧乙烷单元; 分子量44），其包含平均5至35个环氧乙烷单元的聚醚链，其中至少60摩尔％的聚醚链通过脲基甲酸酯基团连接到两个由至少两个二异氰酸酯分子制备的多异氰酸酯分子。 本发明还涉及制备这些水分散性多异氰酸酯的方法。

公开(公告)号：US06222066B1

公开(公告)日：2001-04-24

申请号：US09532259

申请日：2000-03-22

Applicant: Karsten Danielmeier ,  Harald Leps ,  Dieter Mager ,  Reinhard Halpaap ,  Martin Brahm ,  Reinhold Klipper ,  Andreas Hauner

Inventor： Karsten Danielmeier ,  Harald Leps ,  Dieter Mager ,  Reinhard Halpaap ,  Martin Brahm ,  Reinhold Klipper ,  Andreas Hauner

IPC: C07C24900

CPC classification number: C07C263/20 ,  C07C265/14

Abstract: A process for the purification of organic isocyanates or isocyanate mixtures in which the amount of chlorine compound(s) present is reduced by mixing the isocyanate(s) or isocyanate mixtures with a gel-type or macroporous, anion-exchanging organic material having tertiary and/or quaternary amino groups. The process renders possible a purification of the isocyanates from chlorine-containing compounds which is milder than in conventional processes and is therefore particularly suitable for temperature-sensitive isocyanates.

Abstract translation: 有机异氰酸酯或异氰酸酯混合物的纯化方法，其中存在的氯化合物的量通过将异氰酸酯或异氰酸酯混合物与凝胶型或大孔阴离子交换有机材料混合而降低，所述有机异氰酸酯或异氰酸酯混合物具有叔和 /或季氨基。 该方法可以从含氯化合物中纯化异氰酸酯，其比常规方法温和，因此特别适用于温度敏感的异氰酸酯。

公开(公告)号：US5852101A

公开(公告)日：1998-12-22

申请号：US958227

申请日：1997-10-27

Applicant: Reinhard Halpaap ,  Christian Wamprecht ,  Hans-Joachim Kreuder ,  Wolfgang Schultz ,  Manfred Bock ,  Rainer Rettig

Inventor： Reinhard Halpaap ,  Christian Wamprecht ,  Hans-Joachim Kreuder ,  Wolfgang Schultz ,  Manfred Bock ,  Rainer Rettig

IPC: C08G18/62 ,  C08G18/75 ,  C08G18/78 ,  C08G18/80 ,  C09D5/03 ,  C09D5/46 ,  C09D175/00 ,  C09D175/04 ,  C08J3/00 ,  C08F8/30 ,  C08K3/00 ,  C08L75/00

CPC classification number: C08G18/8074 ,  C08G18/6229 ,  C08G18/6254 ,  C08G18/758 ,  C08G18/8016 ,  C08G2150/20 ,  Y10T428/31551

Abstract: The present invention relates to a powder coating composition for the production of non-yellowing flexible coatings which is solid below 30.degree. C. and liquid above 120.degree. C. and contains a mixture of A) a polyisocyanate component which i) has a content of blocked isocyanate groups (expressed as NCO, molecular weight=42) of 3.0 to 14.0% by weight, ii) has a functionality, based on the blocked isocyanate groups, of 1.9 to 2.3 and iii) and contains at least one .epsilon.-caprolactam-blocked polyisocyanate based on the reaction product of 4,4'-diisocyanatodicyclohexyl methane with a polyol component having an average molecular weight of 90 to 400 and containing at least 50% by weight, based on the weight of the polyol component, of one or more (cyclo)aliphatic diols containing 4 to 12 carbon atoms, B) a polyol component containing at least one polyhydroxy polyacrylate having an OH number of 40 to 120 and C) an organotin catalyst for the reaction between hydroxyl groups and blocked isocyanate groups, wherein components A) and B) are present in quantities which correspond to an equivalent ratio of blocked polyisocyanate groups to hydroxyl groups of 0.5:1 to 1.2:1. The present invention also relates to the a heat-resistant substrate which is coated with this powder coating composition.

Abstract translation: 本发明涉及一种粉末涂料组合物，用于生产低于30℃的固体和高于120℃的液体的非黄变柔性涂层，并且含有A）多异氰酸酯组分的混合物，i）多异氰酸酯组分的含量 封闭的异氰酸酯基团（表示为NCO，分子量= 42）为3.0至14.0重量％，ii）基于封端异氰酸酯基团的官能度为1.9至2.3和iii）并且包含至少一个ε-己内酰胺 - 封端的多异氰酸酯基于4,4'-二异氰酸二环己基甲烷与平均分子量为90至400的多元醇组分的反应产物和基于多元醇组分重量的至少50重量％的一种或多种 含有4至12个碳原子的（环）脂族二醇，B）含有至少一种羟值为40至120的多羟基聚丙烯酸酯的多元醇组分，C）用于羟基与封端异氰酸酯反应的有机锡催化剂 te基团，其中组分A）和B）以对应于封端多异氰酸酯基团与羟基的当量比为0.5:1至1.2:1的量存在。 本发明还涉及涂覆有该粉末涂料组合物的耐热基材。