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    Production of middle distillate range hydrocarbons by light olefin upgrading
    64.
    发明授权
    Production of middle distillate range hydrocarbons by light olefin upgrading 失效
    通过轻烯烃升级生产中间馏分烃类

    公开(公告)号：US5073351A

    公开(公告)日：1991-12-17

    申请号：US322263

    申请日：1989-03-13

    申请人： James H. Beech, Jr. ,  Hartley Owen ,  Michael P. Ramage ,  Samuel A. Tabak

    发明人： James H. Beech, Jr. ,  Hartley Owen ,  Michael P. Ramage ,  Samuel A. Tabak

    IPC分类号： F02B3/06

    CPC分类号： F02B3/06 ,  Y10S203/06

    摘要： An oligomerization system is provided for upgrading lower olefins to distillate hydrocarbons, especially useful as high quality jet or diesel fuels. The olefinic feedstock is reacted over a shape selective acid zeolite, such as ZSM-5, to oligomerize feedstock olefins and further convert recycled hydrocarbons. Reactor effluent is fractionated to recover a light-middle distillate range product stream and to obtain gasoline and heavy hydrocarbon streams for recycle.

    摘要翻译： 提供了一种低聚体系，用于将低级烯烃升级成馏分烃，特别适用于高质量的喷气或柴油燃料。 烯烃原料在诸如ZSM-5的形状选择性酸性沸石上反应以使原料烯烃低聚并进一步转化回收的烃。 将反应器流出物分馏以回收轻 - 中馏分范围的产物流并获得用于再循环的汽油和重烃流。

    Process for the production of ether and alcohol
    65.
    发明授权
    Process for the production of ether and alcohol 失效
    醚和酒精生产工艺

    公开(公告)号：US4857664A

    公开(公告)日：1989-08-15

    申请号：US265324

    申请日：1988-10-27

    申请人： Tracy J. Huang ,  Rene B. LaPierre ,  Samuel A. Tabak

    发明人： Tracy J. Huang ,  Rene B. LaPierre ,  Samuel A. Tabak

    IPC分类号： C07C41/06 ,  C07C41/09 ,  C07C41/42

    CPC分类号： C07C41/42 ,  C07C41/06 ,  C07C41/09

    摘要： Olefin undergoes conversion in the presence of water to a mixture of alcohol and ether which is then subjected to various downstream operations including distillation and decantation to provide an ether-rich product containing little if any water. If desired the ether can be combined in any predetermined ratio with co-produced alcohol to provide alcohol/ether mixtures of desired composition. The foregoing process is especially suitable to the conversion of propylene and propylene-containing streams to diisopropyl ether and mixtures of isopropyl alcohol and diisopropyl ether which are useful, inter alia, as octane improves for gasoline.

    摘要翻译： 烯烃在水的存在下经历转化为醇和醚的混合物，然后将其进行各种下游操作，包括蒸馏和倾析，以提供含有少量的含有醚的产物。 如果需要，醚可以以任何预定比例与共同产生的醇组合以提供所需组合物的醇/醚混合物。 上述方法特别适用于将丙烯和含丙烯的物流转化为二异丙基醚以及异丙醇和二异丙醚的混合物，特别是对于汽油而言辛烷值改善。

    Fluidized bed process for upgrading diene-containing light olefins
    66.
    发明授权
    Fluidized bed process for upgrading diene-containing light olefins 失效
    用于升级含二烯烃的轻质烯烃的流化床方法

    公开(公告)号：US4855521A

    公开(公告)日：1989-08-08

    申请号：US186526

    申请日：1988-04-27

    申请人： Amos A. Avidan ,  Fritz A. Smith ,  Samuel A. Tabak

    发明人： Amos A. Avidan ,  Fritz A. Smith ,  Samuel A. Tabak

    IPC分类号： C07C2/00

    CPC分类号： C07C2/00 ,  C07C2529/40

    摘要： An improved fluidized bed process for upgrading olefinic hydrocarbon feedstock by contacting the feedstock with acidic siliceous zeolite conversion catalyst particles at elevated temperature under exothermic conditions to produce heavier hydrocarbons including gasoline range hydrocarbons. The improvement comprises maintaining a turbulent fluidized bed of catalyst particles by flowing hydrocarbon-containing vapor upwardly through said bed at less than transport velocity; and introducing liquid olefinic feedstock comprising at least one C.sub.4 -C.sub.6 diene component into the fluidized catalyst bed in a lower portion thereof by rapidly atomizing and vaporizing the liquid feedstock, thus converting feedstock to heavier hydrocarbon without substantial thermal diene degradation thereof prior to contacting conversion catalyst particles in the fluidized bed. A predominantly liquid product is recovered containing C.sub.4 -C.sub.9 hydrocarbons rich in olefins and aromatics.

    摘要翻译： 改进的流化床方法，用于通过使原料与酸性硅沸石转化催化剂颗粒在升高的温度下在放热条件下接触以产生包含汽油范围烃的较重的烃来提纯烯烃原料。 改进包括通过以低于运输速度将含烃蒸汽向上流动穿过所述床来维持催化剂颗粒的湍流流化床; 并且通过使液体原料快速雾化并使其加热，将包含至少一种C 4 -C 6二烯组分的液体烯烃原料引入到其下部的流化催化剂床中，从而将原料转化为较重的烃，而在转化催化剂 流化床中的颗粒。 回收含有富含烯烃和芳族化合物的C4-C9烃的主要液体产物。

    Upgrading diene-containing light olefins in a fluidized bed reactor
    67.
    发明授权
    Upgrading diene-containing light olefins in a fluidized bed reactor 失效
    在流化床反应器中升级含二烯的轻质烯烃

    公开(公告)号：US4778661A

    公开(公告)日：1988-10-18

    申请号：US6408

    申请日：1987-01-23

    申请人： Amos A. Avidan ,  Fritz A. Smith ,  Samuel A. Tabak

    发明人： Amos A. Avidan ,  Fritz A. Smith ,  Samuel A. Tabak

    IPC分类号： C07C2/00 ,  B01J8/24

    CPC分类号： C07C2/00 ,  C07C2529/40

    摘要： An improved fluidized bed process for upgrading olefinic hydrocarbon feedstock by contacting the feedstock with acidic siliceous zeolite conversion catalyst particles at elevated temperature under exothermic conditions to produce heavier hydrocarbons including gasoline range hydrocarbons. The improvement comprises maintaining a turbulent fluidized bed of catalyst particles by flowing hydrocarbon-containing vapor upwardly through said bed at less than transport velocity; and introducing liquid olefinic feedstock comprising at least one C.sub.4 -C.sub.6 diene component into the fluidized catalyst bed in a lower portion thereof by rapidly atomizing and vaporizing the liquid feedstock, thus converting feedstock to heavier hydrocarbon without substantial thermal diene degradation thereof prior to contacting conversion catalyst particles in the fluidized bed. Reaction severity conditions may be maintained by controlling catalyst acidity, reaction temperature and reactant contact time to produce reaction efluent containing propane and propene in the ratio of about 0.2:1 to 200:1. A predominantly liquid product is recovered containing C.sub.4 -C.sub.9 hydrocarbons rich in olefins and aromatics.

    摘要翻译： 改进的流化床方法，用于通过使原料与酸性硅沸石转化催化剂颗粒在升高的温度下在放热条件下接触以产生包含汽油范围烃的较重烃来提纯烯烃原料。 改进包括通过以低于运输速度将含烃蒸汽向上流动穿过所述床来维持催化剂颗粒的湍流流化床; 并通过快速雾化和蒸发液体原料将包含至少一种C 4 -C 6二烯组分的液体烯烃原料引入到其下部的流化催化剂床中，从而在接触转化催化剂之前将原料转化成较重的烃，而不会发生相当的热二烯降解 流化床中的颗粒。 可以通过控制催化剂酸度，反应温度和反应物接触时间来维持反应强度条件，以产生约0.2:1至200:1的丙烷和丙烯的反应液。 回收含有富含烯烃和芳族化合物的C4-C9烃的主要液体产物。

    Integration of paraffin dehydrogenation with MOGD to minimize compression and gas plant separation
    68.
    发明授权
    Integration of paraffin dehydrogenation with MOGD to minimize compression and gas plant separation 失效
    石蜡脱氢与MOGD的整合使压缩和气体分离最小化

    公开(公告)号：US4749820A

    公开(公告)日：1988-06-07

    申请号：US650594

    申请日：1984-09-14

    申请人： James C. Kuo ,  Samuel A. Tabak

    发明人： James C. Kuo ,  Samuel A. Tabak

    IPC分类号： C07C11/02 ,  C10G50/00 ,  C07C5/00 ,  C07C1/00

    CPC分类号： C10G50/00 ,  C07C11/02 ,  Y02P30/48

    摘要： Disclosed is a method and apparatus for producing gasoline and distillate grade products which employs integrating catalytic (or thermal) dehydrogenation of paraffins with MOGD to minimize interstage compression and gas plant separation cost. The process cascades the product from a low temperature propane or butane dehydrogenation zone into a first catalytic reactor zone which operates at low pressure and contains zeolite oligomerization catalysts, where the low molecular weight olefins are reacted to primarily gasoline range materials. These gasoline range materials can then be pressurized to the pressure required for reacting to distillate in a second catalytic reactor zone operating at high pressure and containing zeolite oligomerization catalyst. The first catalytic reactor zone also acts to remove the olefins from the dehydrogenation reactor effluent to allow recycle of the unreacted paraffins.

    摘要翻译： 公开了用于生产汽油和馏出物级产物的方法和装置，其采用将链烷烃的催化（或热）脱氢与MOGD整合，以最小化级间压缩和气体分离成本。 该方法将产物从低温丙烷或丁烷脱氢区级联到在低压下操作并含有沸石低聚催化剂的第一催化反应器区，其中低分子量烯烃主要与汽油范围材料反应。 然后可以将这些汽油范围的材料加压至在高压下操作并含有沸石低聚催化剂的第二催化反应器区域中与馏出物反应所需的压力。 第一催化反应器区还用于从脱氢反应器流出物中除去烯烃以允许未反应的链烷烃的再循环。

    Upgrading light olefins in a turbulent fluidized catalyst bed reactor
    69.
    发明授权
    Upgrading light olefins in a turbulent fluidized catalyst bed reactor 失效
    在湍流流化催化剂床反应器中升级轻质烯烃

    公开(公告)号：US4746762A

    公开(公告)日：1988-05-24

    申请号：US6407

    申请日：1987-01-23

    申请人： Amos A. Avidan ,  Tai-Sheng Chou ,  Hartley Owen ,  Jorge L. Soto ,  Samuel A. Tabak

    发明人： Amos A. Avidan ,  Tai-Sheng Chou ,  Hartley Owen ,  Jorge L. Soto ,  Samuel A. Tabak

    IPC分类号： B01J8/24 ,  B01J29/40 ,  C07C1/20 ,  C07C2/00 ,  C10G3/00 ,  C10G35/095 ,  C10G50/00 ,  C10G57/02 ,  C07C2/12

    CPC分类号： C07C1/20 ,  B01J29/40 ,  C07C2/00 ,  C10G50/00 ,  B01J2208/00265 ,  B01J2229/42 ,  C07C2529/40 ,  C10G2300/1092 ,  C10G2300/4081 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P30/20

    摘要： A fluidized bed catalytic process for conversion of light olefinic gas feedstock containing ethene to produce hydrocarbons rich in C.sub.5.sup.+ liquids, comprising the steps of maintaining a fluidized bed of zeolite catalyst particles in a turbulent reactor bed at a temperature of about 315.degree. to 510.degree. C., said catalyst having an apparent particle density of about 0.9 to 1.6 g/cm.sup.3 and a size range of about 1 to 150 microns, and average catalyst particles size of about 20 to 100 microns containing about 10 to 25 weight percent of fine particles having a particle size less than 32 microns; passing hot feedstock vapor upwardly through the fluidized catalyst bed under turbulent flow conditions; maintaining turbulent fluidized bed conditions through the reactor bed between transition velocity and transport velocity at a superficial fluid velocity of about 0.3 to 2 meters per second; and recovering hydrocarbon product containing a major amount of C.sub.5.sup.+ hydrocarbons and containing C.sub.3 -C.sub.5 alkanes and alkenes in the ratio of about 0.2:1 to 5:1.

    摘要翻译： 一种用于转化含有乙烯的轻质烯烃气体原料以产生富含C5 +液体的烃的流化床催化方法，包括以下步骤：将沸石催化剂颗粒的流化床在约315℃至510℃的温度下保持在湍流反应器床中 所述催化剂具有约0.9至1.6g / cm 3的表观颗粒密度和约1至150微米的尺寸范围，以及约20至100微米的平均催化剂颗粒尺寸，其含有约10至25重量％的具有 粒度小于32微米; 在湍流条件下将热原料蒸气向上通过流化催化剂床; 保持湍流流化床条件通过反应器床在过渡速度和运输速度之间以约0.3至2米/秒的表面流体速度; 并以约0.2:1至5:1的比例回收含有大量C 5+烃并含有C 3 -C 5烷烃和烯烃的烃产物。

    Process for coverting methanol to alkyl ethers
    70.
    发明授权
    Process for coverting methanol to alkyl ethers 失效
    将甲醇覆盖至烷基醚的方法

    公开(公告)号：US4746761A

    公开(公告)日：1988-05-24

    申请号：US65775

    申请日：1987-07-02

    申请人： Amos A. Avidan ,  Frederick J. Krambeck ,  Samuel A. Tabak

    发明人： Amos A. Avidan ,  Frederick J. Krambeck ,  Samuel A. Tabak

    IPC分类号： C07C1/20 ,  C07C9/16 ,  C07C41/06 ,  C10G3/00 ,  C10G29/20 ,  C10L1/02 ,  C07C2/00

    CPC分类号： C07C41/06 ,  C07C1/20 ,  C07C9/16 ,  C10G29/205 ,  C10G3/49 ,  C10L1/023 ,  C07C2529/40 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42

    摘要： A multistage process for producing isoalkyl ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in contact with zeolite catalyst to predominantly C.sub.2 -C.sub.7 lower olefins comprising isobutylene and isoamylene, by-product water and a minor amount of C.sub.8.sup.+ hydrocarbons, followed by fractionation of the C.sub.2 -C.sub.7 olefins to recover a C.sub.2 -C.sub.3 -rich recycle stream for further catalytic conversion in the primary stage. C.sub.4 -C.sub.7 olefins are passed to a second catalytic etherification stage for reaction of isoalkenes with methanol to produce methyl tertiary-butyl ether, methyl isoamylether and higher isoalkyl ethers. The second stage effluent may be fractionated to recover an ether product, C.sub.5.sup.+ hydrocarbon liquid product, and unreacted butenes. Advantageously, the unreacted butenes are further reacted with isoparaffin in a third catalytic stage under acid catalysis alkylation conditions, and fractionated to recover C.sub.6.sup.+ alkylate liquid, liquid hydrocarbon product. The ethers may be blended with at least one C.sub.6.sup.+ hydrocarbon to produce high octane gasoline.

    摘要翻译： 用于从低级脂族含氧化合物原料如甲醇生产异烷基醚的多阶段方法。 原料在初级催化剂阶段在升高的温度下与沸石催化剂催化转化成主要是包含异丁烯和异戊烯，副产物水和少量C 8+烃的C 2 -C 7低级烯烃，然后分馏C2-C7烯烃 以回收在初级阶段进一步催化转化的富含C2-3的再循环物流。 将C4-C7烯烃通入第二催化醚化阶段，以使异烯烃与甲醇反应，生成甲基叔丁基醚，甲基异戊醚和高级异烷基醚。 第二级流出物可以分馏以回收醚产物，C5 +烃液体产物和未反应的丁烯。 有利地，在酸催化烷基化条件下，在第三催化阶段中，未反应的丁烯进一步与异链烷烃反应，并分馏以回收C6 +烷基化液体液体烃产物。 醚可以与至少一种C6 +烃混合以产生高辛烷值汽油。