Titanovanadosilicalites as epoxidation catalysts for olefins
    61.
    发明授权
    Titanovanadosilicalites as epoxidation catalysts for olefins 失效
    作为烯烃的环氧化催化剂的钛酸铵

    公开(公告)号:US5744619A

    公开(公告)日:1998-04-28

    申请号:US818265

    申请日:1997-03-17

    IPC分类号: C07D301/03 C07D301/12

    CPC分类号: C07D301/12

    摘要: Titanovanadosilicalites have been found to be very selective, active catalysts in the epoxidation of olefins by peroxides. Dilute hydrogen peroxide suffices to afford high yields of the epoxide. Vanadium incorporation at levels of Si:V in the range 100-2500 effectively changes the characteristics of the titanosilicalite into which it is incorporated to give near quantitative conversion of propylene at selectivities greater than 90%.

    摘要翻译: 已经发现,在过氧化物对烯烃的环氧化中,非常有选择性的活性催化剂。 稀释过氧化氢足以提供高产率的环氧化物。 钒含量在100-2500范围内的Si:V水平有效地改变了其掺入其中的钛硅硅沸石的特性,使得选择性大于90%的丙烯接近定量转化。

    METALLOPHOSPHATE MOLECULAR SIEVES, METHODS OF PREPARATION AND USE
    64.
    发明申请
    METALLOPHOSPHATE MOLECULAR SIEVES, METHODS OF PREPARATION AND USE 有权
    金属磷酸酯分子筛,制备和使用方法

    公开(公告)号:US20140004036A1

    公开(公告)日:2014-01-02

    申请号:US13537411

    申请日:2012-06-29

    IPC分类号: C01B39/54

    摘要: A new family of crystalline microporous metallophosphates designated AlPO-59 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-59 compositions are characterized by a new unique ABC-6 net structure and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

    摘要翻译: 已经合成了一系列名为AlPO-59的结晶微孔金属磷酸盐系列。 这些金属磷酸盐由经验式R + rMm2 + EPxSiyOz表示,其中R是有机铵阳离子,例如ETMA +,M是骨架金属碱土金属或价态2+的过渡金属,E是三价骨架元素如铝或 镓。 AlPO-59组合物的特征在于新的独特的ABC-6网结构和组合物,并且具有用于进行各种烃转化方法和用于分离至少一种组分的分离性质的催化性质。

    Method of rapidly screening X-ray powder diffraction patterns
    67.
    发明授权
    Method of rapidly screening X-ray powder diffraction patterns 有权
    快速筛选X射线粉末衍射图谱的方法

    公开(公告)号:US06327334B1

    公开(公告)日:2001-12-04

    申请号:US09444352

    申请日:1999-11-18

    IPC分类号: G01N2320

    摘要: A method for rapidly screening multiple X-ray powder diffraction patterns, such as those generated through combinatorial chemistry, has been developed. The method is directed toward measuring X-ray powder diffraction patterns of a set of samples, factoring the patterns using a suitable statistical technique into a small number of discrete components or factors, determining the scores corresponding to the factors for each X-ray powder diffraction pattern, and plotting the scores. The graphs of the scores are then inspected for clusters, trends, or outliers, which may represent new material or, perhaps, faulty data.

    摘要翻译: 已经开发了用于快速筛选多个X射线粉末衍射图案的方法,例如通过组合化学产生的衍射图案。 该方法旨在测量一组样品的X射线粉末衍射图,使用合适的统计技术将图案分解成少量离散组分或因子,确定对应于每个X射线粉末衍射因子的分数 模式,并绘制分数。 然后对分数的图表进行集群,趋势或异常值的检查,这可能代表新的资料,或者可能是错误的数据。

    Crystalline manganese (II/III) phosphate compositions
    69.
    发明授权
    Crystalline manganese (II/III) phosphate compositions 有权
    结晶锰(II / III)磷酸盐组合物

    公开(公告)号:US6156931A

    公开(公告)日:2000-12-05

    申请号:US275202

    申请日:1999-03-24

    申请人: Gregory J. Lewis

    发明人: Gregory J. Lewis

    摘要: A new family of crystalline manganese phosphate compositions has been prepared. These compositions have an extended network which network can be a one-, two-, or three-dimensional network. The composition has an empirical formula of:(A.sup.3+).sub.v (Mn.sup.b+)(M.sup.c+).sub.x P.sub.y O.sub.zwhere A is a structure directing agent such as an alkali metal, M is a metal such as Al, Fe.sup.3+ and "b" is the average manganese oxidation state and varies from greater than 2.0 to a maximum of 3.0. These compositions can be used as adsorbents and as catalysts in the oxidation of hydrocarbons.

    摘要翻译: 已经制备了一种新的结晶磷酸锰组合物。 这些组合物具有扩展网络,其网络可以是一维,二维或三维网络。 该组合物具有以下经验式:(A3 +)v(Mnb +)(Mc +)xPyOz其中A是结构导向剂如碱金属,M是金属如Al,Fe3 +,“b”是平均锰氧化态 并且从大于2.0变化到最大值3.0。 这些组合物可用作烃的氧化中的吸附剂和催化剂。