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公开(公告)号：US09657625B2
公开(公告)日：2017-05-23
申请号：US12943109
申请日：2010-11-10
申请人： R. Samuel Boorse , Martin Dieterle
发明人： R. Samuel Boorse , Martin Dieterle
CPC分类号： F01N3/2066 , F01N3/0222 , F01N3/035 , F01N3/103 , F01N13/009 , F01N13/0093 , F01N2250/02 , F01N2330/06 , F01N2370/04 , F01N2510/063 , F01N2510/0682 , F01N2610/02 , Y02T10/24
摘要： Provided are selective catalytic reduction catalytic articles, emission treatment systems and methods for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalytic articles have a Selective Catalytic Reduction (SCR) catalyst uniformly coated over the outlet portion of wall flow filter walls resulting in reduction of NO2 and combustion of the soot without substantially increasing the system backpressure.
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公开(公告)号：US08293182B2
公开(公告)日：2012-10-23
申请号：US12774469
申请日：2010-05-05
IPC分类号： B01D50/00
CPC分类号： H01L23/552 , B01D53/9468 , B01D53/9472 , B01D2255/1021 , B01D2255/9022 , B01D2255/9035 , B01D2255/9155 , B01D2257/404 , B01D2257/502 , B01D2257/702 , B01J23/40 , B01J23/42 , B01J29/061 , B01J29/072 , B01J29/763 , B01J35/0006 , B01J35/04 , B01J37/024 , B01J37/0244 , B01J37/0246 , F01N3/035 , F01N3/103 , F01N3/106 , F01N3/2066 , F01N13/0097 , F01N2510/0682 , F01N2510/0684 , F01N2570/18 , H01L2924/0002 , Y02T10/24 , H01L2924/00
摘要： Catalysts and catalytic articles for treating exhaust gas streams are described. In one or more embodiments, a catalyst system includes a first zone to abate nitrogen oxides by selective catalytic reduction, a second zone to oxidize ammonia and a third zone to oxidize carbon monoxide and hydrocarbons. Methods for treating the exhaust gas stream are also provided. Methods of making and using such catalysts and catalytic articles are also described.
摘要翻译： 描述了用于处理废气流的催化剂和催化制品。 在一个或多个实施方案中，催化剂体系包括通过选择性催化还原来消除氮氧化物的第一区域，用于氧化氨的第二区域和用于氧化一氧化碳和烃的第三区域。 还提供了处理废气流的方法。 还描述了制备和使用这些催化剂和催化剂的方法。
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公开(公告)号：US20110271664A1
公开(公告)日：2011-11-10
申请号：US12774469
申请日：2010-05-05
CPC分类号： H01L23/552 , B01D53/9468 , B01D53/9472 , B01D2255/1021 , B01D2255/9022 , B01D2255/9035 , B01D2255/9155 , B01D2257/404 , B01D2257/502 , B01D2257/702 , B01J23/40 , B01J23/42 , B01J29/061 , B01J29/072 , B01J29/763 , B01J35/0006 , B01J35/04 , B01J37/024 , B01J37/0244 , B01J37/0246 , F01N3/035 , F01N3/103 , F01N3/106 , F01N3/2066 , F01N13/0097 , F01N2510/0682 , F01N2510/0684 , F01N2570/18 , H01L2924/0002 , Y02T10/24 , H01L2924/00
摘要： Catalysts and catalytic articles for treating exhaust gas streams are described. In one or more embodiments, a catalyst system includes a first zone to abate nitrogen oxides by selective catalytic reduction, a second zone to oxidize ammonia and a third zone to oxidize carbon monoxide and hydrocarbons. Methods for treating the exhaust gas stream are also provided. Methods of making and using such catalysts and catalytic articles are also described.
摘要翻译： 描述了用于处理废气流的催化剂和催化制品。 在一个或多个实施方案中，催化剂体系包括通过选择性催化还原来消除氮氧化物的第一区，用于氧化氨的第二区和用于氧化一氧化碳和烃的第三区。 还提供了处理废气流的方法。 还描述了制备和使用这些催化剂和催化剂的方法。
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公开(公告)号：US20110078997A1
公开(公告)日：2011-04-07
申请号：US12572730
申请日：2009-10-02
申请人： R. Samuel Boorse , Martin Dieterle
发明人： R. Samuel Boorse , Martin Dieterle
CPC分类号： F01N3/035 , B01D53/9445 , B01D53/9472 , B01D2251/2067 , B01D2255/1023 , B01D2255/20761 , B01D2255/2092 , B01D2255/50 , B01D2255/9032 , B01D2255/9155 , B01D2258/012 , B01J23/44 , B01J29/763 , B01J37/0244 , B01J37/0246 , B01J37/0248 , F01N3/103 , F01N3/2066 , F01N2510/06 , F01N2510/0682 , Y02A50/2341 , Y02T10/22 , Y02T10/24
摘要： Provided are catalyst articles, emission treatment systems and methods for simultaneously remediating the carbon monoxide, nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The emission treatment system of specific embodiment effectively treats diesel engine exhaust with a single catalyst article.
摘要翻译： 提供了催化剂制品，排放处理系统和同时修复柴油机排气流中存在的一氧化碳，氮氧化物（NOx），颗粒物质和气态烃的方法。 特定实施例的排放处理系统用单一催化剂制品有效地处理柴油发动机排气。
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65.发明申请PARTIAL FILTER SUBSTRATES CONTAINING SCR CATALYSTS AND METHODS AND EMISSIONS TREATMENT SYSTEMS 有权含有SCR催化剂的部分过滤器底物和方法和排放处理系统公开(公告)号：US20100269491A1
公开(公告)日：2010-10-28
申请号：US12765441
申请日：2010-04-22
CPC分类号： B01D53/9431 , B01D53/944 , B01D53/9477 , B01D2255/20738 , B01D2255/502 , B01D2255/915 , B01D2257/404 , B01D2258/012 , F01N3/022 , F01N3/035 , F01N3/2066 , F01N2250/02 , F01N2330/02 , F01N2330/22 , Y02T10/24
摘要： Catalytic articles, methods and emissions treatment systems for treating an engine exhaust gas stream containing NOx and particulate matter are disclosed and include a particulate filter comprising a first SCR catalyst for NOx conversion disposed downstream of the injector. The particulate filter is a partial filter with a particle filtration efficiency between about 30% and 60% and an SCR catalyst loading in the range of 0.1 g/in3-3.5 g/in3.
摘要翻译： 公开了用于处理含有NOx和颗粒物质的发动机废气流的催化制品，方法和排放物处理系统，并且包括一种颗粒过滤器，其包括设置在喷射器下游的用于NOx转化的第一SCR催化剂。 颗粒过滤器是颗粒过滤效率在约30％至60％之间的部分过滤器，SCR催化剂负载量在0.1g / in3-3.5g / in3的范围内。
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公开(公告)号：US20100111796A1
公开(公告)日：2010-05-06
申请号：US12263871
申请日：2008-11-03
CPC分类号： B01D53/9468 , B01D53/9418 , B01D53/9436 , B01D2251/2062 , B01D2255/102 , B01D2255/104 , B01D2255/106 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2258/012 , B01J23/42 , B01J29/72 , B01J29/7615 , B01J35/0006 , B01J35/04 , B01J37/0225 , B01J37/0244 , B01J37/0246 , Y02A50/2325 , Y02C20/10 , Y02T10/24 , Y10T428/24149
摘要： Catalysts, methods of preparing catalyst, and methods for treating exhaust gas streams are described. In one or more embodiments, a catalyst system includes an upstream zone effective to catalyze the conversion of a mixture of NOx and NH3 to N2, and a downstream zone effective for the conversion of ammonia to N2 in the presence or absence of NOx. In an embodiment, a method for preparing a catalyst system includes: first coating one end of a substrate along at least 5% of its length with an undercoat washcoat layer containing a material composition effective to catalyze the removal of ammonia; second coating with an overcoat layer containing a material composition effective to catalyze the conversion of a mixture of NOx and NH3 to N2. A method for treating the exhaust gas stream is provided, which includes injecting ammonia or an ammonia precursor into an exhaust gas stream of a vehicle, passing the engine exhaust gas stream containing NOx and NH3 through the upstream zone of a catalyst system to remove NOx and then passing the exhaust gas stream through the downstream zone of the catalyst system to remove NH3, as well as other oxidizable species such as hydrocarbons and CO.
摘要翻译： 描述了催化剂，制备催化剂的方法和处理废气流的方法。 在一个或多个实施方案中，催化剂体系包括有效催化NOx和NH 3的混合物转化为N 2的上游区，以及在存在或不存在NO x的情况下有效地将氨转化为N 2的下游区。 在一个实施方案中，制备催化剂体系的方法包括：首先用至少5％长度的基材的一端涂覆含有有效催化去除氨的材料组合物的底涂层涂层; 第二次涂覆，其中包含有效催化NOx和NH 3的混合物转化为N 2的材料组合物的外涂层。 提供了一种处理废气流的方法，其包括将氨或氨前体注入车辆的废气流中，使含有NOx和NH 3的发动机废气流通过催化剂系统的上游区以除去NOx和 然后使废气流通过催化剂体系的下游区以除去NH 3，以及其它可氧化物质如烃和CO。
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67.发明申请公开(公告)号：US20070123732A1
公开(公告)日：2007-05-31
申请号：US11555474
申请日：2006-11-01
CPC分类号： C07C45/35 , B01J8/0469 , B01J2208/00274 , B01J2208/00495 , C07C45/33 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for stably operating a continuous preparation process for obtaining acrolein or acrylic acid or a mixture thereof from propane, in which the feed rate of fresh propane to the process is utilized as a correcting element for stable steady-state operation.
摘要翻译： 用于稳定操作从丙烷得到丙烯醛或丙烯酸或其混合物的连续制备方法，其中将新鲜丙烷进料至该方法的进料速率用作稳定稳态操作的校正元件。
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68.发明申请PROCESS FOR PREPARING ACROLEIN OR ACRYLIC ACID OR A MIXTURE THEREOF FROM PROPANE 有权制备丙烯酸或丙烯酸或其混合物的方法公开(公告)号：US20070088092A1
公开(公告)日：2007-04-19
申请号：US11533177
申请日：2006-09-19
申请人： Catharina Klanner , Martin Dieterle , Gotz-Peter Schindler , Tsung-Chieh Cheng , Klaus Muller-Engel
发明人： Catharina Klanner , Martin Dieterle , Gotz-Peter Schindler , Tsung-Chieh Cheng , Klaus Muller-Engel
IPC分类号： C07B63/02
CPC分类号： B01J8/067 , B01J8/0415 , B01J2208/00814 , B01J2208/00849 , B01J2208/025 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing acrolein or acrylic acid or a mixture thereof from propane, in which propane is dehydrogenated under heterogeneous catalysis in a reaction zone A and the propylene formed is partially oxidized heterogeneously in a reaction zone, reaction zone A being operated in loop mode and reaction gas mixture input stream A fed to the reaction zone A comprising added molecular hydrogen which is added to this input stream as late as possible.
摘要翻译： 由丙烷制备丙烯醛或丙烯酸或其混合物的方法，其中丙烷在反应区A中在非均相催化下脱氢，形成的丙烯在反应区中部分氧化，反应区A以循环模式操作， 反应气体混合物输入流A，其进料到反应区A，其包含加入的分子氢，其尽可能晚地加入到该输入流中。
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69.发明申请Process for preparing at least one target product by partial oxidation and/or ammoxidation of propylene 有权通过丙烯的部分氧化和/或氨氧化制备至少一种目标产物的方法公开(公告)号：US20060258529A1
公开(公告)日：2006-11-16
申请号：US11411882
申请日：2006-04-27
IPC分类号： B01J23/00
CPC分类号： C07C51/43 , B01J23/002 , B01J23/8876 , B01J23/8885 , B01J35/0006 , B01J2523/00 , C07C45/33 , C07C45/35 , C07C51/25 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C47/22 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69 , C07C255/08 , B01J2523/36
摘要： A process for preparing at least one target product by partial oxidation and/or ammoxidation of propylene, in which the propylene source used is a propane dehydrogenation, the propane used therein being obtained by a rectificative prepurification of crude propane.
摘要翻译： 通过丙烯的部分氧化和/或氨氧化制备至少一种目标产物的方法，其中使用的丙烯源是丙烷脱氢，其中使用的丙烷是通过粗丙烷的精馏预纯化获得的。
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公开(公告)号：US20060199977A1
公开(公告)日：2006-09-07
申请号：US11357975
申请日：2006-02-22
IPC分类号： C07C51/42
摘要： A process for removing methacrolein from liquid phase P comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component in which the removal is effected by crystallization, the acrylic acid accumulating in the crystals formed and the methacrolein in the remaining mother liquor.
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