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    Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical polymerization
    62.
    发明授权
    Thermosetting compositions containing epoxy-functional polymers prepared using atom transfer radical polymerization 有权
    含有使用原子转移自由基聚合制备的环氧官能聚合物的热固性组合物

    公开(公告)号：US06319967B1

    公开(公告)日：2001-11-20

    申请号：US09375021

    申请日：1999-08-16

    申请人： Simion Coca ,  Dennis A. Simpson ,  James B. O'Dwyer ,  Kurt G. Olson

    发明人： Simion Coca ,  Dennis A. Simpson ,  James B. O'Dwyer ,  Kurt G. Olson

    IPC分类号： C08G5932

    CPC分类号： C08L53/00 ,  C08F8/26 ,  C08F293/005 ,  C08F2438/01 ,  C08G59/3209 ,  C08K5/0025 ,  C09D153/00 ,  Y10T428/31511 ,  C08L33/12 ,  C08L2666/02

    摘要： A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with epoxides; and (b) a non-gelled, epoxy functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x—or —{(G)q—(M)p}x— wherein M is a residue, that is free of epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has epoxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the epoxy functional polymer has a number average molecular weight of at least 250. Also provided by the present invention are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.

    摘要翻译： 提供一种热固性组合物，其包括：（a）具有至少两个与环氧化物反应的官能团的交联剂; 和（b）在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的环氧官能聚合物。 聚合物含有至少一种以下聚合物链结构：其中M是至少一种烯属不饱和可自由基聚合单体的残基，不含环氧官能团; G是具有至少一个烯属不饱和自由基聚合单体的具有环氧官能度的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得环氧官能聚合物的数均分子量至少为250.本发明还提供了使用本发明的组合物涂覆底物的方法和 通过这些方法涂覆的基材，以及彩色 - 透明复合涂层。

    Thermosetting compositions containing epoxy functional polymers prepared by atom transfer radical polymerization
    64.
    发明授权
    Thermosetting compositions containing epoxy functional polymers prepared by atom transfer radical polymerization 失效
    含有通过原子转移自由基聚合制备的环氧官能聚合物的热固性组合物

    公开(公告)号：US06268433B1

    公开(公告)日：2001-07-31

    申请号：US09375013

    申请日：1999-08-16

    申请人： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

    发明人： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

    IPC分类号： C08L3314

    CPC分类号： C08G59/3209 ,  C08G59/4207 ,  Y10T428/31699 ,  Y10T428/31928

    摘要： A thermosetting composition useful as a powder coating comprises a co-reactable solid, particulate mixture of (a) an epoxy functional polymer containing at least one of the polymer chain structures -[(M)p-(G)q]x- or -[(G)q-(M)p]x- wherein M is an oxirane-free residue of at least one ethylenically unsaturated monomer, G is a glycidyl-functional ethylenically unsaturated monomer, p and q each independently has a value of 0 to typically less than 100, and x has a value of at least 1 to typically less than 100, the total value of p, q and x selected such that said epoxy functional polymer has a number average molecular weight of at least 250, and (b) a co-reactant having functional groups reactive with the epoxy groups of (a), e.g., dodecanedioic acid. The epoxy functional polymer is prepared by atom transfer radical polymerization and a polydispersity index of less than 2.5.

    摘要翻译： 可用作粉末涂料的热固性组合物包含（a）包含至少一种聚合物链结构 - [（M）p-（G）q] x - 或 - 的聚环氧官能聚合物的可共反应的固体颗粒混合物， [（G）q-（M）p] x-其中M是至少一种烯键式不饱和单体的不含环氧乙烷的残基，G是缩水甘油基官能的烯属不饱和单体，p和q各自独立地为0至 通常小于100，并且x具有至少1至通常小于100的值，选择p，q和x的总值使得所述环氧官能聚合物的数均分子量为至少250，并且（b ）具有与（a）的环氧基反应的官能团的共反应物，例如十二烷二酸。 环氧官能聚合物通过原子转移自由基聚合和小于2.5的多分散指数制备。

    Low gloss powder coating composition
    67.
    发明授权
    Low gloss powder coating composition 失效
    低光泽粉末涂料组合物

    公开(公告)号：US07166675B2

    公开(公告)日：2007-01-23

    申请号：US10769148

    申请日：2004-01-30

    申请人： Kristin M. Bartlett ,  Simion Coca ,  Anthony M. Chasser

    发明人： Kristin M. Bartlett ,  Simion Coca ,  Anthony M. Chasser

    IPC分类号： C08L35/00

    CPC分类号： C09D133/08 ,  C08L2666/14

    摘要： A thermosetting protective and/or decorative coating composition that includes a co-reactable solid, particulate mixture of a film-forming material that includes a copolymer containing functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the copolymer. The film-forming material makes up from 20 to 95 wt. % and the crosslinking agent makes up from 5 to 80 wt. % of the composition. The composition is applied as a coating and cured, forming a bicontinuous morphology where the film-forming material and the crosslinking agent form separate phases resulting in a low gloss coating as indicated by a specular gloss measurement of not more than 10 gloss units measured at 60° with an appropriate instrument. A method of coating a substrate using the composition, substrates coated using the method, and a multi-component composite coating composition that includes the composition are disclosed.

    摘要翻译： 一种热固性保护和/或装饰性涂料组合物，其包含可共反应的固体，成膜材料的颗粒混合物，其包含含有官能团的共聚物和具有至少两个与官能团反应的官能团的交联剂 共聚物。 成膜材料占20〜95wt。 ％，交联剂占5〜80wt。 ％的组成。 该组合物作为涂层施用并固化，形成双连续形态，其中成膜材料和交联剂形成分离相，导致低光泽涂层，如通过在60℃下测量的不超过10个光泽度单位的镜面光泽度测量所指示的 °与适当的仪器。 公开了使用该组合物涂布基材的方法，使用该方法涂布的基材和包含该组合物的多组分复合涂料组合物。

    Acrylic-halogenated polyolefin copolymer adhesion promoters
    70.
    发明授权
    Acrylic-halogenated polyolefin copolymer adhesion promoters 有权
    丙烯酸卤化聚烯烃共聚物粘合促进剂

    公开(公告)号：US06965000B2

    公开(公告)日：2005-11-15

    申请号：US10864978

    申请日：2004-06-10

    申请人： Simion Coca ,  Brian K. Rearick ,  James B. O'Dwyer

    发明人： Simion Coca ,  Brian K. Rearick ,  James B. O'Dwyer

    IPC分类号： C08F4/00 ,  C08F293/00

    CPC分类号： C08F4/00 ,  C08F293/005 ,  C08F2438/01

    摘要： The present invention is directed to a method for producing a copolymer and a copolymer product of the method. The copolymer is prepared by a controlled radical polymerization process, typically an atom transfer radical polymerization process, in which polymerizable alkene monomers are polymerized in the presence of a halogenated polyolefin macroinitiator. The copolymer product of this process is useful in a film-forming composition that adheres strongly to polyolefinic substrates and to which non-polyolefinic film-forming compositions strongly adhere. The copolymer can be applied to a substrate in an adhesion-promoting layer or can be incorporated into a film-forming composition, such as a primer, that contains additional resinous compounds.

    摘要翻译： 本发明涉及一种制备该方法的共聚物和共聚物的方法。 共聚物通过受控自由基聚合方法制备，通常是原子转移自由基聚合方法，其中可聚合烯烃单体在卤代聚烯烃大分子引发剂存在下聚合。 该方法的共聚物产物可用于强烈粘附到聚烯烃基材上并且非聚烯烃成膜组合物强烈粘附的成膜组合物。 共聚物可以施加到粘合促进层中的基材上，或者可以加入到含有另外的树脂化合物的成膜组合物如引物中。