HYDROGEN STORAGE METHOD AND SYSTEM
    65.
    发明申请
    HYDROGEN STORAGE METHOD AND SYSTEM 有权
    氢储存方法和系统

    公开(公告)号:US20110305515A1

    公开(公告)日:2011-12-15

    申请号:US12797955

    申请日:2010-06-10

    IPC分类号: B65G5/00 F17D1/07

    摘要: A method and system for storing and supplying hydrogen to a hydrogen pipeline in which a compressed hydrogen feed stream is introduced into a salt cavern for storage and a stored hydrogen stream is retrieved from the salt cavern and reintroduced into the hydrogen pipeline. A minimum quantity of stored hydrogen is maintained in the salt cavern to produce a stagnant layer having a carbon dioxide content along the cavern wall and the top of a residual brine layer located within the salt cavern. The compressed hydrogen feed stream is introduced into the salt cavern and the stored hydrogen stream is withdrawn without disturbing the stagnant layer to prevent carbon dioxide contamination from being drawn into the stored hydrogen stream being reintroduced into the hydrogen pipeline. This allows the stored hydrogen stream to be reintroduced into the hydrogen pipeline without carbon dioxide removal.

    摘要翻译: 一种用于储存和供应氢气到氢气管道的方法和系统,其中将压缩的氢气进料流引入到盐穴中用于储存和储存的氢气流从盐穴中取出并重新引入到氢气管道中。 在盐穴中保留最少量的储存的氢气以产生沿着洞穴壁具有二氧化碳含量的滞留层,以及位于盐穴内的残留盐水层的顶部。 将压缩的氢气进料流引入盐穴中,并且收集储存的氢气流而不扰乱停滞层,以防止二氧化碳污染物被吸入被重新引入到氢气管道中的储存的氢气流中。 这允许将储存的氢气流重新引入氢气管道中,而不需要除去二氧化碳。

    Integrated olefin recovery and hydrogen production from refinery off-gases
    68.
    发明授权
    Integrated olefin recovery and hydrogen production from refinery off-gases 有权
    炼油厂废气中的烯烃回收和氢气的综合回收

    公开(公告)号:US07041271B2

    公开(公告)日:2006-05-09

    申请号:US10267840

    申请日:2002-10-10

    IPC分类号: C01B3/02 C01B3/22

    摘要: A method is disclosed a method for recovering olefins and for producing hydrogen from a refinery off-gas stream in which such stream is conventionally pretreated and separated to obtain a light ends stream that contains nitrogen, hydrogen and carbon monoxide and a heavy ends stream that contains the olefins. The light ends stream is subjected to reforming and a water gas shift reactions after addition of a natural gas stream. The addition of the natural gas increases the hydrogen recovery from the light ends and also stabilizes the hydrocarbon content in the stream to be subjected to the reforming and water gas shift reactions. The heavy ends can be further treated to recover olefins such as ethylene and propylene. The rate of natural gas addition is controlled so that the concentration of the nitrogen in a stream exiting the water gas shift reactor is less than about 5 percent by volume so that hydrogen separation from such stream becomes practical.

    摘要翻译: 公开了一种方法,用于回收烯烃和从精炼厂废气流中生产氢气的方法,其中这种流通常被预处理和分离,以获得含有氮,氢和一氧化碳的轻馏分物流和含有 烯烃。 轻馏分料流在加入天然气流之后进行重整和水煤气变换反应。 天然气的添加增加了从轻馏分出来的氢气回收,并且使流中的烃含量稳定以进行重整和水煤气变换反应。 可以进一步处理重的末端以回收烯烃如乙烯和丙烯。 控制天然气加入速率使得离开水煤气变换反应器的物流中的氮浓度小于约5体积%,从而使得从这种物流中分离氢变得实用。