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公开(公告)号：US20100038628A1
公开(公告)日：2010-02-18
申请号：US12551310
申请日：2009-08-31
申请人： Ali Afzali-Ardakani , Phaedon Avouris , Jia Chen , Christian Klinke , Christopher B. Murray , Dmitri V. Talapin
发明人： Ali Afzali-Ardakani , Phaedon Avouris , Jia Chen , Christian Klinke , Christopher B. Murray , Dmitri V. Talapin
IPC分类号： H01L29/66 , H01L21/336
CPC分类号： H01L21/22 , B82Y10/00 , H01L51/002 , H01L51/0048 , Y10S977/742 , Y10S977/938
摘要： A method is provided for doping nano-components, including nanotubes, nanocrystals and nanowires, by exposing the nano-components to an organic amine-containing dopant. A method is also provided for forming a field effect transistor comprising a nano-component that has been doped using such a dopant.
摘要翻译： 提供了一种通过将纳米组分暴露于含有机胺的掺杂剂来掺杂包括纳米管，纳米晶体和纳米线的纳米组分的方法。 还提供了一种用于形成包含已经使用这种掺杂剂掺杂的纳米成分的场效应晶体管的方法。
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62.发明申请MOLECULAR MANIPULATOR, A METHOD OF MAKING THE SAME, AND A METHOD OF MOVING A NANOSTRUCTURE 审中-公开分子操纵器，其制造方法和移动纳米结构的方法公开(公告)号：US20090312529A1
公开(公告)日：2009-12-17
申请号：US12544899
申请日：2009-08-20
IPC分类号： C09B31/02
CPC分类号： G02B21/34 , C07C323/48
摘要： A molecular manipulator includes a light-sensitive molecule, including a double bond, which changes a cis-trans configuration of the double bond in response to illumination by light of a selected wavelength, and a probe, for example, a probe of a scanned-proximity probe microscope, to which the light-sensitive molecule is attached. A method of making the molecular manipulator includes covalently bonding the light-sensitive molecule to the probe. A method of moving a nanostructure includes controllably grasping, moving, and releasing the nanostructure with the molecular manipulator.
摘要翻译： 分子操纵器包括包含双键的光敏分子，其响应于所选波长的光的照射而改变双键的顺式 - 反式构型，以及探针，例如扫描型探针的探针， 邻近探针显微镜，光敏分子附着于其上。 制造分子操纵器的方法包括将光敏分子共价键合到探针。 移动纳米结构的方法包括用分子操纵器可控地掌握，移动和释放纳米结构。
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公开(公告)号：US07521091B2
公开(公告)日：2009-04-21
申请号：US11477664
申请日：2006-06-30
CPC分类号： H01L51/0595 , B05D1/185 , B05D7/52 , B82Y10/00 , B82Y30/00 , B82Y40/00 , H01L51/0035 , H01L51/0036 , H01L51/0038 , H01L51/004 , H01L51/0041 , H01L51/0068 , H01L51/0077 , H01L51/0512
摘要： A method for preparing an extended conjugated molecular assembly includes applying onto a surface of a substrate a first molecular compound G1-Molecule1-G2, where G1 includes a first functional group, G2 includes a second functional group, and Molecule1 includes a conjugated organic group bonded to G1 and G2, reacting the first molecular compound with a second molecular compound G3-Molecule2-G4, where G3 includes a third functional group, G4 includes a fourth function group, and Molecule 2 includes a conjugated organic group bonded to G3 and G4, to form on the substrate an extended conjugated molecule G1-Molecule1-Molecule2-G4, and reacting the extended conjugated molecule with an additional molecular compound at least once to further extend the molecular assembly, the fourth functional group G4 interacting with the additional molecular compound.
摘要翻译： 制备延伸的共轭分子组件的方法包括将第一分子化合物G1-Molecule1-G2（其中G1包括第一官能团）施加到基材的表面上，G2包括第二官能团，并且分子1包括键合的共轭有机基团 对于G1和G2，使第一分子化合物与第二分子化合物G3-Molecule2-G4反应，其中G3包括第三官能团，G4包括第四官能团，分子2包括键合到G3和G4的共轭有机基团， 在基底上形成延伸的共轭分子G1-Molecule1-Molecule2-G4，并使延伸的共轭分子与另外的分子化合物反应至少一次以进一步延长分子组装，第四官能团G4与另外的分子化合物相互作用。
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64.发明授权公开(公告)号：US07514063B1
公开(公告)日：2009-04-07
申请号：US12028149
申请日：2008-02-08
IPC分类号： C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/17 , C01B32/174 , C01B2202/02 , C01B2202/22 , Y10S977/748 , Y10S977/751 , Y10S977/842 , Y10S977/845 , Y10S977/847
摘要： A method of obtaining purified semiconducting SWCNTs from a bulk mixture of metallic SWCNTs and semiconducting SWCNTs by first creating an aqueous solution containing the bulk mixture and adding a functionalized particle or nanoparticle to the solution, whereby the functionalized particle or nanoparticle reacts chemically with the metallic SWCNTs to form a high density particle-nanotube composite that can be physically separated by centrifugation.
摘要翻译： 通过首先产生含有本体混合物的水溶液并向该溶液中加入官能化的颗粒或纳米颗粒，从金属SWCNT和半导体SWCNT的主体混合物中获得纯化的半导体SWCNT的方法，由此官能化的颗粒或纳米颗粒与金属SWCNTs化学反应 以形成可以通过离心物理分离的高密度颗粒 - 纳米管复合物。
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公开(公告)号：US07504132B2
公开(公告)日：2009-03-17
申请号：US11044885
申请日：2005-01-27
IPC分类号： B05D5/00
摘要： The present invention provides a method for the selective placement of carbon nanotubes on a particular surface. In particular, the present invention provides a method in which self-assembled monolayers formed on an unpatterned or patterned metal oxide surface are used to attract or repel carbon nanotubes from a dispersion containing the same. In accordance with the present invention, the carbon nanotubes can be attracted to the self-assembled monolayers so as to be attached to the metal oxide surface, or they can be repelled by the self-assembled monolayers bonding to a predetermined surface other than the metal oxide surface containing the self-assembled monolayers.
摘要翻译： 本发明提供了一种在特定表面上选择性地放置碳纳米管的方法。 特别地，本发明提供了一种方法，其中形成在未图案化或图案化的金属氧化物表面上的自组装单层被用于从含有该碳纳米管的分散体吸引或排斥碳纳米管。 根据本发明，碳纳米管可以被吸引到自组装单层上以便附着到金属氧化物表面，或者它们可以被结合到除了金属之外的预定表面的自组装单层排斥 含有自组装单层的氧化物表面。
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66.发明授权Hetero diels-alder adducts of pentacene as soluble precursors of pentacene 有权并五苯作为并五苯的可溶性前体的异狄氏al醛加成物公开(公告)号：US07381585B2
公开(公告)日：2008-06-03
申请号：US11526943
申请日：2006-09-26
IPC分类号： H01L51/40
CPC分类号： C07D495/08 , C07D487/08 , C07D513/08 , H01L51/0003 , H01L51/0055 , H01L51/0545
摘要： The present invention describes organic solvent-soluble Diels-Alder adducts of polycyclic aromatic compounds, such as, oligothiophene, perylene, benzo[ghi]perylene, coronene and polyacenes, with variety of dienophiles containing at least one heteroatom and in some cases two heteroatoms bonded to aromatic moiety, such as, thioxomalonates, azodicarboxylates, thialdehyde, acylnitroso and N-sulfinylamides. The Diels-Alder adducts are prepared by a simple, one step cycloaddition reaction of the polycyclic aromatic compounds, such as, pentacene, or other fused aromatic compounds, with heterodienophiles. The Diels-Alder adducts according to the present invention all form soluble adducts with pentacene and can be converted back to pentacene by retro-Diels-Alder reaction at moderate (60-250° C.) temperatures both in bulk, in solution or as thin-films.
摘要翻译： 本发明描述了多环芳族化合物如低聚噻吩，苝，苯并[g]二萘嵌苯，苯并芘和多烯烃的有机溶剂可溶性狄尔斯 - 阿尔德加合物，其中含有至少一个杂原子的多种亲烯体，在一些情况下，两个杂原子键合 芳族部分，例如硫代孕酮，偶氮二羧酸酯，脯氨酸，酰基亚硝基和N-亚磺酰胺。 Diels-Alder加合物通过多环芳族化合物如并五苯或其它稠合芳族化合物与异源二烯体的简单的一步环加成反应来制备。 根据本发明的狄尔斯 - 阿尔德加合物全部形成与并五苯的可溶性加合物，并且可以在中等（60-250℃）温度下以体积，溶液或薄的方式通过逆狄尔斯 - 阿尔德反应转化回并五苯 薄膜
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67.发明授权Organic field-effect transistor and method of making same based on polymerizable self-assembled monolayers 有权有机场效应晶体管及其制备方法基于可聚合的自组装单层膜公开(公告)号：US07301183B2
公开(公告)日：2007-11-27
申请号：US11329072
申请日：2006-01-11
IPC分类号： H01L27/148
CPC分类号： H01L51/0068 , B82Y10/00 , B82Y30/00 , H01L51/0006 , H01L51/0036 , H01L51/0038 , H01L51/0076 , H01L51/0094 , H01L51/0533 , H01L51/0541 , H01L51/0545
摘要： An organic field-effect transistor and a method of making the same include a self-assembled monolayer (SAM) of bifunctional molecules disposed between a pair of electrodes as a channel material. The pair of electrodes and the SAM of bifunctional molecules are formed above an insulating layer, in which each of the bifunctional molecules comprises a functionality at a first end that covalently bonds to the insulating layer, and an end-cap functionality at a second end that includes a conjugated bond. The SAM of bifunctional molecules may be polymerized SAM to form a conjugated polymer strand extending between the pair of electrodes.
摘要翻译： 有机场效应晶体管及其制造方法包括设置在作为沟道材料的一对电极之间的双功能分子的自组装单层（SAM）。 双功能分子的一对电极和SAM形成在绝缘层上方，其中每个双功能分子在第一端包含与绝缘层共价键合的官能团，以及在第二端的端帽功能， 包括共轭键。 双功能分子的SAM可以聚合SAM以形成在该对电极之间延伸的共轭聚合物链。
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公开(公告)号：US07166327B2
公开(公告)日：2007-01-23
申请号：US10392977
申请日：2003-03-21
IPC分类号： B05D3/10
CPC分类号： H01L51/0595 , B05D1/185 , B05D7/52 , B82Y10/00 , B82Y30/00 , B82Y40/00 , H01L51/0035 , H01L51/0036 , H01L51/0038 , H01L51/004 , H01L51/0041 , H01L51/0068 , H01L51/0077 , H01L51/0512
摘要： A method for preparing an extended conjugated molecular assembly includes applying onto a surface of a substrate a first molecular compound G1-Molecule1-G2, where G1 includes a first functional group, G2 includes a second functional group, and Molecule1 includes a conjugated organic group bonded to G1 and G2, and reacting the first molecular compound with a second molecular compound G3-Molecule2-G4, where G3 includes a third functional group. G4 includes a fourth function group, and Molecule 2 includes a conjugated organic group bonded to G3 and G4, to form on the substrate an extended conjugated molecule G1-Molecule1-Molecule2-G4.
摘要翻译： 制备延伸的共轭分子组件的方法包括将第一分子化合物G1-Molecule1-G2（其中G1包括第一官能团）施加到基材的表面上，G2包括第二官能团，并且分子1包括键合的共轭有机基团 至G1和G2，并使第一分子化合物与第二分子化合物G3-Molecule2-G4反应，其中G3包括第三官能团。 G4包括第四官能团，分子2包括与G3和G4键合的共轭有机基团，以在基底上形成延伸的共轭分子G1-Molecule1-Molecule2-G4。
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公开(公告)号：US20060165896A1
公开(公告)日：2006-07-27
申请号：US11044885
申请日：2005-01-27
申请人： Ali Afzali-Ardakani , James Hannon
发明人： Ali Afzali-Ardakani , James Hannon
IPC分类号： B05D5/00
摘要： The present invention provides a method for the selective placement of carbon nanotubes on a particular surface. In particular, the present invention provides a method in which self-assembled monolayers formed on an unpatterned or patterned metal oxide surface are used to attract or repel carbon nanotubes from a dispersion containing the same. In accordance with the present invention, the carbon nanotubes can be attracted to the self-assembled monolayers so as to be attached to the metal oxide surface, or they can be repelled by the self-assembled monolayers bonding to a predetermined surface other than the metal oxide surface containing the self-assembled monolayers.
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70.发明申请公开(公告)号：US20060105513A1
公开(公告)日：2006-05-18
申请号：US11138797
申请日：2005-05-26
IPC分类号： H01L21/8234 , H01L21/84 , H01L21/336 , H01L51/40
CPC分类号： H01L29/04 , B82Y10/00 , B82Y20/00 , B82Y30/00 , H01L29/0673 , H01L29/78684 , H01L29/7869 , H01L29/78696 , H01L51/0049 , H01L51/0545 , H01L2251/5369 , Y10S977/938
摘要： A device comprising a doped semiconductor nano-component and a method of forming the device are disclosed. The nano-component is one of a nanotube, nanowire or a nanocrystal film, which may be doped by exposure to an organic amine-containing dopant. Illustrative examples are given for field effect transistors with channels comprising a lead selenide nanowire or nanocrystal film and methods of forming these devices.
摘要翻译： 公开了一种包括掺杂半导体纳米元件的器件和形成器件的方法。 纳米组分是纳米管，纳米线或纳米晶体膜之一，其可以通过暴露于含有机胺的掺杂剂掺杂。 给出了具有包含铅硒化物纳米线或纳米晶体膜的通道的场效应晶体管的示例性实例以及形成这些器件的方法。
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