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    PHOTOACID GENERATING MONOMER AND PRECURSOR THEREOF
    64.
    发明申请
    PHOTOACID GENERATING MONOMER AND PRECURSOR THEREOF 有权
    光电发生单体及其前身

    公开(公告)号：US20120172555A1

    公开(公告)日：2012-07-05

    申请号：US13340088

    申请日：2011-12-29

    申请人： Suzanne M. Coley ,  David R. Wilson ,  Francis J. Timmers

    发明人： Suzanne M. Coley ,  David R. Wilson ,  Francis J. Timmers

    IPC分类号： C07C69/54 ,  C08F20/38 ,  C07D327/04 ,  C07D327/00 ,  C07D333/76 ,  C07D327/06

    CPC分类号： G03F7/0046 ,  C07C309/12 ,  C07C381/12 ,  C07D333/76 ,  C08F220/38 ,  G03F7/0045 ,  G03F7/0397

    摘要： A monomer compound has the formula (I): where each R1, R2, and R3 is independently H, F, C1-10 alkyl, fluoro-substituted C1-10 alkyl, C1-10 cycloalkyl, or fluoro-substituted C1-10 cycloalkyl, provided that at least one of R1, R2, or R3 is F; n is an integer of from 1 to 10, A is a halogenated or non-halogenated C2-30 olefin-containing polymerizable group, and G+ is an organic or inorganic cation. The monomer is the reaction product of a sultone precursor and the oxyanion of a hydroxy-containing halogenated or non-halogenated C2-30 olefin-containing compound. A polymer includes the monomer of formula (I).

    摘要翻译： 单体化合物具有式（I）：其中每个R 1，R 2和R 3独立地为H，F，C 1-10烷基，氟取代的C 1-10烷基，C 1-10环烷基或氟取代的C 1-10环烷基 条件是R 1，R 2或R 3中的至少一个为F; n为1〜10的整数，A为卤化或非卤化的含C2-30烯烃的聚合性基团，G +为有机或无机阳离子。 单体是磺内酯前体与含羟基的卤代或非卤代C 2-30烯烃化合物的氧阴离子的反应产物。 聚合物包括式（I）的单体。

    Metathesis Process For Preparing An Alpha, Omega-Functionalized Olefin
    66.
    发明申请
    Metathesis Process For Preparing An Alpha, Omega-Functionalized Olefin 有权
    用于制备α，ω-官能化烯烃的复分解方法

    公开(公告)号：US20080228017A1

    公开(公告)日：2008-09-18

    申请号：US11915794

    申请日：2006-06-02

    申请人： Kenneth A. Burdett ,  Francis J. Timmers ,  Morteza Mokhtarzadeh

    发明人： Kenneth A. Burdett ,  Francis J. Timmers ,  Morteza Mokhtarzadeh

    IPC分类号： C07C5/00

    CPC分类号： C07C6/04 ,  C07C67/333 ,  C07C2531/24 ,  C07C11/02 ,  C07C69/533

    摘要： A cross-metathesis process for preparing an α,ω-functionalized olefin, such as methyl 9-decenoate, and an α-olefin having three or more carbon atoms, such as 1-decene. The process involves contacting in a first reaction zone an α-functionalized internal olefin, such as methyl oleate, and an α-olefinic monomer having three or more carbon atoms, such as 1-decene, with a first metathesis catalyst to prepare an effluent stream containing the α,ω-functionalized olefin, such as methyl 9-decenoate, an unfunctionalized internal olefin, such as 9-octadecene, unconverted reactant olefins, and optionally, an α,ω-difunctionalized internal olefinic dimer, such as dimethyl 9-octadecen-1,18-dioate; separating said effluent streams; then contacting in a second reaction zone the unfunctionalized internal olefin with ethylene in the presence of a second metathesis catalyst to obtain a second product effluent containing the α-olefinic monomer having three or more carbon atoms; and cycling a portion of the α-olefinic monomer stream(s) to the first zone.

    摘要翻译： 用于制备α，ω-官能化烯烃（例如9-癸烯酸甲酯）和具有三个或更多个碳原子的α-烯烃（例如1-癸烯）的交叉复分解方法。 该方法包括在第一反应区中使第一复分解催化剂与α-官能化的内烯烃（例如油酸甲酯）和具有三个或更多个碳原子的α-烯烃单体（例如1-癸烯）接触以制备流出物流 含有α，ω官能化的烯烃，如9-癸烯酸甲酯，未官能化的内烯烃，如9-十八碳烯，未转化的反应物烯烃，以及任选的α，ω-二官能化的内烯烃二聚体，如二甲基9-十八碳烯 -1,18-二酸 分离所述流出物流; 然后在第二反应区域中，在第二复分解催化剂的存在下使未官能化的内烯烃与乙烯接触，得到含有具有三个或更多个碳原子的α-烯烃单体的第二产物流出物; 以及将一部分所述α-烯烃单体流循环到所述第一区。