摘要:
The present systems and methods utilize a polyamic acid solution as a precursor to form a polyimide bead having desired properties. The polyamic acid solution may be formed into a polyamic acid droplet. The polyamic acid droplet is then processed to form a polyamic acid bead, such as by extraction of solvent to concentrate the polyamic acid or by partial chemical imidization of the polyamic acid. The polyamic acid bead is then better able to retain its shape during subsequent processing steps, such as drying and pressurizing, before final thermal imidization.
摘要:
An adsorption-desorption material, in particular, crosslinked vinylepoxide-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear vinylepoxide-amine polymeric materials having an Mw from about 140 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear vinylepoxide-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the vinylepoxide materials.
摘要:
An adsorption-desorption material, in particular, crosslinked organo-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear organo-amine polymeric materials having an Mw from about 160 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear organo-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the adsorption-desorption materials.
摘要:
This invention relates to a polymeric membrane composition comprising an associating polymer. The polymer coating is characterized as having hard and soft segments where the hard segment comprises TMPA, combined with HDPA. The membrane may utilize a porous substrate.
摘要:
A method and system for drilling a wellbore is described. The system includes a wellbore with a variable density drilling mud, drilling pipe, a bottom hole assembly disposed in the wellbore and a drilling mud processing unit in fluid communication with the wellbore. The variable density drilling mud has compressible particles and drilling fluid. The bottom hole assembly is coupled to the drilling pipe while the drilling mud processing unit is configured to separate the compressible particles from the variable density drilling mud. The compressible particles in this embodiment may include compressible hollow objects filled with pressurized gas an configured to maintain the mud weight between the fracture pressure gradient and the pore pressure gradient. In addition, the system and method may also manage the use of compressible particles having different characteristics, such as size, during the drilling operations.
摘要:
This invention relates to the composition of an integrally-layered polymeric membrane and a process for utilizing the integrally-layered polymeric membrane components of a feedstream. More particularly, but not by way of limitation, this invention relates to the composition of an integrally-layered polymeric membrane and a process for utilizing the integrally-layered polymeric membrane in the separation of aromatics from a hydrocarbon based feedstream. The polymeric membranes of the present invention are fabricated by chemically crosslinking adjacent polymer membrane layers of the same or differing copolymer solutions to produce an integrally-layered polymeric membrane with improved separations properties.
摘要:
The present invention relates to a latex comprising water and a layered material intercalated with a polymer. The invention also relates to a nanocomposite material comprising a layered material intercalated with a polymer. The latex can be produced by forming a dispersion of layered material in water, adding surfactant, polymerizable monomer or monomers, and a polymerization initiator to the mixture and then polymerizing the monomer to form a latex. The latex can also be formed from preformed polymers. Composite materials formed from latexes produced by either method have improved mechanical properties and reduced air permeability.
摘要:
A water soluble and brine soluble rod-like polymer having recurring any units of the formula: ##STR1## wherein n is a 2 to 22 straight chained or branched chained alkyl or cycloalkyl group and the level of sulfonation is about 20 to about 100 mole %, and M is a tertiary amine or a metal cation selected from the group consisting of aluminum, iron, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements.
摘要:
The synthesis, preparation and utilization of cationic viscoelastic monomer fluids mixed with cationic-alkyl containing copolymers are described. These fluid mixtures possess dramatic rheological behavior at very low concentrations as compared to the two individual components or even in comparison with most conventional water soluble polymers. Marked changes in solution properties are exhibited with minor modifications in the structure of the polymers, monomer structure, and monomer stoichometry.
摘要:
A homogeneous free radical copolymerization process for the formation of a copolymer of acrylamide and a cationic hydrogen-bonding alkoxypropyl which comprises the steps of:(a) forming a mixture of monomer and the acrylamide-monomer under a nitrogen atmosphere;(b) adding deoxygenated water to said mixture to form a homogeneous reaction solution;(c) adding a free radical initiator to said homogeneous reaction solution to initiate polymerization of said acrylamide monomer and said cationic hydrogen-bonding alkoxypropyl monomer; and(d) copolymerizing said acrylamide monomer and said monomer at a sufficient temperature and for a sufficient period of time to form said copolymer of acrylamide monomer and without the formation of substantial amounts of particulates or phase separation occurring, said copolymer having an intrinsic viscosity of about 1 to about 10 dl/g. said copolymer having the formula: ##STR1## wherein n is 6 to 22 straight chained or branched alkyl or cycloalkyl group. X is about 90 to about 99.9 mole % and y is about 0.1 to about 10.0 mole %.