公开(公告)号：US11424185B2

公开(公告)日：2022-08-23

申请号：US16945595

申请日：2020-07-31

Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.

Inventor： Cheng-Wei Chang ,  Chia-Hung Chu ,  Kao-Feng Lin ,  Hsu-Kai Chang ,  Shuen-Shin Liang ,  Sung-Li Wang ,  Yi-Ying Liu ,  Po-Nan Yeh ,  Yu Shih Wang ,  U-Ting Chiu ,  Chun-Neng Lin ,  Ming-Hsi Yeh

IPC: H01L23/532 ,  H01L23/522 ,  H01L21/768 ,  H01L21/285 ,  H01L21/02

Abstract: A semiconductor device includes a gate electrode, a source/drain structure, a lower contact contacting either of the gate electrode or the source/drain structure, and an upper contact disposed in an opening formed in an interlayer dielectric (ILD) layer and in direct contact with the lower contact. The upper contact is in direct contact with the ILD layer without an interposing conductive barrier layer, and the upper contact includes ruthenium.

公开(公告)号：US11276571B2

公开(公告)日：2022-03-15

申请号：US16907634

申请日：2020-06-22

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yu Shih Wang ,  Hong-Jie Yang ,  Chia-Ying Lee ,  Po-Nan Yeh ,  U-Ting Chiu ,  Chun-Neng Lin ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/027 ,  H01L21/8234 ,  H01L29/78 ,  H01L29/66 ,  H01L21/308

Abstract: A photo resist layer is used to protect a dielectric layer and conductive elements embedded in the dielectric layer when patterning an etch stop layer underlying the dielectric layer. The photo resist layer may further be used to etch another dielectric layer underlying the etch stop layer, where etching the next dielectric layer exposes a contact, such as a gate contact. The bottom layer can be used to protect the conductive elements embedded in the dielectric layer from a wet etchant used to etch the etch stop layer.

公开(公告)号：US11257924B2

公开(公告)日：2022-02-22

申请号：US16746097

申请日：2020-01-17

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Chun-Sheng Liang ,  Ming-Chi Huang ,  Ming-Hsi Yeh ,  Ying-Liang Chuang ,  Hsin-Che Chiang

IPC: H01L29/66 ,  H01L29/78 ,  H01L21/311 ,  H01L21/3213 ,  H01L21/8234 ,  H01L21/321 ,  H01L21/3105 ,  H01L21/02 ,  H01L21/027

Abstract: Methods for, and structures formed by, wet process assisted approaches implemented in a replacement gate process are provided. Generally, in some examples, a wet etch process for removing a capping layer can form a first monolayer on the underlying layer as an adhesion layer and a second monolayer on, e.g., an interfacial dielectric layer between a gate spacer and a fin as an etch protection mechanism. Generally, in some examples, a wet process can form a monolayer on a metal layer, like a barrier layer of a work function tuning layer, as a hardmask for patterning of the metal layer.

公开(公告)号：US20210375677A1

公开(公告)日：2021-12-02

申请号：US16887316

申请日：2020-05-29

Applicant: Taiwan Semiconductor Manufacturing Co. Ltd.

Inventor： Yu Shih Wang ,  Kuo-Bin Huang ,  Ming-Hsi Yeh ,  Po-Nan Yeh

IPC: H01L21/768 ,  H01L21/8238 ,  H01L29/66 ,  H01L21/28 ,  H01L21/3213 ,  H01L27/092 ,  H01L29/08 ,  H01L29/49 ,  H01L23/535

Abstract: A method for forming a semiconductor device includes forming a metal contact on a substrate, forming a first dielectric on the metal contact, forming a first opening in the first dielectric, and performing a wet etch on a bottom surface of the first opening through a first etch stop layer (ESL) over the metal contact. The wet etch forms a first recess in a top surface of the metal contact. An upper width of the first recess is smaller than a lower width of the first recess. A first conductive feature is formed in the first recess and the first opening.

公开(公告)号：US11189714B2

公开(公告)日：2021-11-30

申请号：US16928423

申请日：2020-07-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ming-Chi Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L29/66 ,  H01L29/78 ,  H01L21/285 ,  H01L29/06 ,  H01L21/02 ,  H01L21/8234 ,  H01L21/3115 ,  H01L21/311 ,  H01L29/49 ,  H01L29/08 ,  H01L29/165 ,  H01L29/51

Abstract: Embodiments of the present disclosure provide a method of cleaning a lanthanum containing substrate without formation of undesired lanthanum compounds during processing. In one embodiment, the cleaning method includes treating the lanthanum containing substrate with an acidic solution prior to cleaning the lanthanum containing substrate with a HF solution. The cleaning method permits using lanthanum doped high-k dielectric layer to modulate effective work function of the gate stack, thus, improving device performance.

公开(公告)号：US20210193469A1

公开(公告)日：2021-06-24

申请号：US17187176

申请日：2021-02-26

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/28 ,  H01L27/092 ,  H01L29/49 ,  H01L29/51 ,  H01L21/8238 ,  H01L29/66 ,  H01L21/3213

Abstract: Semiconductor device structures having metal gate structures with tunable work function values are provided. In one example, a first gate structure and a second gate structure formed on a substrate, wherein the first gate structure includes a first work function metal having a first material, and the second gate structure includes a second work function metal having a second material, the first material being different from the second material, wherein the first gate structure further includes a gate dielectric layer, a self-protective layer having metal phosphate, and the first work function metal on the self-protective layer.

公开(公告)号：US11031302B2

公开(公告)日：2021-06-08

申请号：US16517767

申请日：2019-07-22

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ju-Li Huang ,  Chih-Long Chiang ,  Kuo Bin Huang ,  Ming-Hsi Yeh ,  Ying-Liang Chuang

IPC: H01L21/8238 ,  H01L29/51 ,  H01L27/088 ,  H01L21/28 ,  H01L21/8234 ,  H01L21/311 ,  H01L21/02 ,  H01L21/3105 ,  H01L29/49

Abstract: Embodiments of the present disclosure provide wet process based methods for modifying threshold value (Vt) of high-k metal gate using self-assembled monolayer (SAM) on dedicated transistor. In one embodiment, the method includes forming a gate structure over a substrate, the gate structure comprising a gate dielectric layer, a barrier layer formed over the gate dielectric layer, and an oxide layer formed over the barrier layer, and forming a self-assembled monolayer on the oxide layer by exposing the oxide layer to an aqueous solution containing metal oxides in a metal dissolving acid.

公开(公告)号：US20210134662A1

公开(公告)日：2021-05-06

申请号：US17120668

申请日：2020-12-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Yu Shih Wang ,  Shian Wei Mao ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L21/768 ,  H01L23/522

Abstract: In one exemplary aspect, a method comprises providing a semiconductor structure having a substrate, one or more first dielectric layers over the substrate, a first metal plug in the one or more first dielectric layers, and one or more second dielectric layers over the one or more first dielectric layers and the first metal plug. The method further comprises etching a via hole into the one or more second dielectric layers to expose the first metal plug, etching a top surface of the first metal plug to create a recess thereon, and applying a metal corrosion protectant comprising a metal corrosion inhibitor to the top surface of the first metal plug.

公开(公告)号：US10283503B2

公开(公告)日：2019-05-07

申请号：US15799555

申请日：2017-10-31

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Ming-Chi Huang ,  Ying-Liang Chuang ,  Ming-Hsi Yeh ,  Kuo-Bin Huang

IPC: H01L27/088 ,  H01L21/8234 ,  H01L21/311 ,  H01L21/3213 ,  H01L29/66 ,  H01L29/49 ,  H01L29/51 ,  H01L29/06 ,  H01L29/423

Abstract: Provided is a metal gate structure and related methods that include performing a metal gate cut process. The metal gate cut process includes a plurality of etching steps. For example, a first anisotropic dry etch is performed, a second isotropic dry etch is performed, and a third wet etch is performed. In some embodiments, the second isotropic etch removes a residual portion of a metal gate layer including a metal containing layer. In some embodiments, the third etch removes a residual portion of a dielectric layer.

公开(公告)号：US12278288B2

公开(公告)日：2025-04-15

申请号：US18673615

申请日：2024-05-24

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chun-Neng Lin ,  Ming-Hsi Yeh ,  Hung-Chin Chung ,  Hsin-Yun Hsu

IPC: H01L29/78 ,  H01L21/8238 ,  H01L27/092 ,  H01L29/66

Abstract: A semiconductor device includes a first fin, a second fin, and a third fin protruding above a substrate, where the third fin is between the first fin and the second fin; a gate dielectric layer over the first fin, the second fin, and the third fin; a first work function layer over and contacting the gate dielectric layer, where the first work function layer extends along first sidewalls and a first upper surface of the first fin; a second work function layer over and contacting the gate dielectric layer, where the second work function layer extends along second sidewalls and a second upper surface of the second fin, where the first work function layer and the second work function layer comprise different materials; and a first gate electrode over the first fin, a second gate electrode over the second fin, and a third gate electrode over the third fin.