公开(公告)号：US08461276B2

公开(公告)日：2013-06-11

申请号：US13525443

申请日：2012-06-18

Applicant: Tim Coffy ,  Kenneth Blackmon ,  Joseph Thorman ,  David Rauscher ,  Jun Tian ,  William Gauthier ,  Nathan Williams

Inventor： Tim Coffy ,  Kenneth Blackmon ,  Joseph Thorman ,  David Rauscher ,  Jun Tian ,  William Gauthier ,  Nathan Williams

IPC: C08F4/6592 ,  C08F4/60 ,  C08F4/603 ,  C08F4/606 ,  C08F4/653

CPC classification number: C08F10/06 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/06 ,  C08F2/00 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/65904

Abstract: Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.

Abstract translation: 本文描述了丙烯聚合方法，由其形成的聚合物和膜。 丙烯聚合方法通常包括在聚合反应容器内将丙烯和一定量的乙烯与第一茂金属催化剂和第二茂金属催化剂接触以形成丙烯基聚合物，其中该量是有效形成基于丙烯的聚合物的量，包括 约2重量％ ％至约6wt。 ％乙烯，第二茂金属催化剂能够比第一茂金属催化剂在丙烯基聚合物中引入更多量的乙烯，并且其中第一茂金属催化剂能够形成丙烯/乙烯无规共聚物，其表现出大于 由第二茂金属催化剂形成的丙烯/乙烯无规共聚物。

公开(公告)号：US20130131415A1

公开(公告)日：2013-05-23

申请号：US13302526

申请日：2011-11-22

Applicant: James R. Butler ,  Aspen Texada ,  William Sheets

Inventor： James R. Butler ,  Aspen Texada ,  William Sheets

IPC: C07C2/66

CPC classification number: C07C2/864 ,  B01J29/088 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/7088 ,  B01J29/90 ,  C07C5/321 ,  C07C6/126 ,  C07C2523/10 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073 ,  C07C15/46

Abstract: A method of producing an alkylaromatic by the alkylation of an aromatic with ethanol, such as producing ethylbenzene by an alkylation reaction of benzene, is disclosed.

Abstract translation: 公开了通过用乙醇烷基化芳族化合物制备烷基芳族化合物的方法，例如通过苯的烷基化反应生产乙苯。

公开(公告)号：US08440319B2

公开(公告)日：2013-05-14

申请号：US11801536

申请日：2007-05-10

Applicant: Rodolfo Mier ,  Mark Miller

Inventor： Rodolfo Mier ,  Mark Miller

IPC: C08G64/00 ,  C08G63/02

CPC classification number: B32B27/32 ,  B32B27/08 ,  B32B2250/03 ,  B32B2250/242 ,  B32B2307/306 ,  B32B2307/558 ,  B32B2307/581 ,  B32B2307/5825 ,  B32B2307/704 ,  B32B2439/00 ,  B32B2553/00 ,  C08J5/18 ,  C08J2323/12 ,  Y10T428/31909

Abstract: A heat resistant film that comprises at least one layer that comprises a high crystallinity propylene polymer having a melt flow rate of from 0.5 g/10 min. to 15 g/10 min. and a xylene solubles of less than 3.5%. The propylene polymer may have a melting point above 158° C. The heat resistant film may further comprise at least a second layer, which may be a heterophasic random copolymer. The heat resistant film may be, for example, a blown film, a cast film, or an oriented film, and may be used in such articles of manufacture as construction films, retort packaging, and laminated articles.

Abstract translation: 一种耐热膜，其包含至少一层包含熔体流动速率为0.5g / 10min的高结晶度丙烯聚合物。 至15g / 10min。 和二甲苯可溶物少于3.5％。 丙烯聚合物可以具有高于158℃的熔点。耐热膜可以进一步包含至少第二层，其可以是多相无规共聚物。 耐热膜可以是例如吹塑薄膜，流延薄膜或取向薄膜，并且可以用于制造制造例如建筑薄膜，蒸煮包装和层压制品。

公开(公告)号：US08436112B2

公开(公告)日：2013-05-07

申请号：US12013774

申请日：2008-01-14

Applicant: Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

Inventor： Jun Tian ,  William Gauthier ,  David Rauscher ,  Shady Henry

IPC: C08F4/52 ,  C08F4/64 ,  C08F4/76

CPC classification number: C08F4/76 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  Y10T428/2982 ,  C08F4/65916 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24 ,  C08F2500/15

Abstract: The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.

Abstract translation: 本发明涉及一种茂金属催化剂体系，其包含惰性二氧化硅载体，其具有在孔直径约250埃至约350埃之间具有大于约0.115mL / g的峰孔体积的孔，以及铝氧烷活化剂与茂金属 在整个支撑体上大体上被束缚。 将活化剂在甲苯的回流温度下在溶剂中接枝到载体上，得到二氧化硅上的铝氧烷，并加入金属茂组分以制备茂金属负载量为约2重量％的MCS。 这促进了催化活性增加的茂金属催化剂体系的生产，其催化活性比之前所公认的高约1％（重量），其中活化剂在室温下接枝到载体上的金属茂负载量的催化活性高至少约20％。

公开(公告)号：US08426661B2

公开(公告)日：2013-04-23

申请号：US13024602

申请日：2011-02-10

Applicant: James R. Butler

Inventor： James R. Butler

IPC: C07C2/66 ,  C07C6/12

CPC classification number: C07C2/66 ,  C07C2523/10 ,  C07C2529/08 ,  C07C2529/70 ,  C07C15/073

Abstract: Methods of forming ethylbenzene are described herein. In one embodiment, the method includes contacting dilute ethylene with benzene in the presence of an alkylation catalyst to form ethylbenzene, wherein such contact occurs in a liquid phase reaction zone and recovering ethylbenzene from the reaction zone.

Abstract translation: 本文描述了形成乙苯的方法。 在一个实施方案中，该方法包括在烷基化催化剂存在下使稀乙烯与苯接触以形成乙苯，其中这种接触发生在液相反应区中并从反应区回收乙苯。

公开(公告)号：US08399726B2

公开(公告)日：2013-03-19

申请号：US12763233

申请日：2010-04-20

Applicant: Sivadinarayana Chinta ,  Joseph Thorman

Inventor： Sivadinarayana Chinta ,  Joseph Thorman

IPC: C07C2/66

CPC classification number: C07C2/84 ,  B01J8/02 ,  B01J8/18 ,  B01J19/02 ,  B01J23/002 ,  B01J23/02 ,  B01J23/34 ,  B01J37/0201 ,  B01J37/031 ,  B01J2219/00006 ,  B01J2219/0209 ,  B01J2219/0218 ,  B01J2219/025 ,  B01J2523/00 ,  C07C2/64 ,  C07C5/327 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/30 ,  C07C2523/34 ,  Y02P20/52 ,  B01J2523/12 ,  B01J2523/22 ,  B01J2523/69 ,  B01J2523/72 ,  C07C15/46

Abstract: A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst.

公开(公告)号：US08389636B2

公开(公告)日：2013-03-05

申请号：US13530212

申请日：2012-06-22

Applicant: Camille Grossetete ,  David W. Knoeppel ,  Jose M. Sosa ,  Shane Steagall ,  Carlos Corletto

Inventor： Camille Grossetete ,  David W. Knoeppel ,  Jose M. Sosa ,  Shane Steagall ,  Carlos Corletto

IPC: C08L25/02

CPC classification number: C08L25/06 ,  C08L2205/02 ,  C08L2207/20

Abstract: A method of preparing a polystyrene blend that includes combining a first polystyrene composition having a first melt flow index with a second polystyrene composition having a second melt flow index and forming a polystyrene blend, the second melt flow index being at least 2 dg/min higher that the first melt flow index. The polystyrene blend has an observed tensile strength value greater than 3% above the expected tensile strength value. The second polystyrene composition can include a recycled polystyrene material, which can include expanded polystyrene. An alternate method of preparing the polystyrene blend includes combining a polystyrene composition with a styrene monomer to form a reaction mixture, polymerizing the reaction mixture and obtaining a polystyrene blend, where the polystyrene containing composition has a melt flow index at least 2 dg/min higher than the melt flow index of the styrene monomer after it has been polymerized.

Abstract translation: 一种制备聚苯乙烯共混物的方法，其包括将具有第一熔体流动指数的第一聚苯乙烯组合物与具有第二熔体流动指数的第二聚苯乙烯组合物组合并形成聚苯乙烯共混物，所述第二熔体流动指数至少为2dg / min 第一个熔体流动指数。 聚苯乙烯共混物的观测拉伸强度值大于预期拉伸强度值的3％以上。 第二聚苯乙烯组合物可以包括再循环的聚苯乙烯材料，其可以包括发泡聚苯乙烯。 制备聚苯乙烯共混物的替代方法包括将聚苯乙烯组合物与苯乙烯单体组合以形成反应混合物，使反应混合物聚合并获得聚苯乙烯共混物，其中含聚苯乙烯的组合物的熔体流动指数至少为2dg / min 比苯乙烯单体聚合后的熔体流动指数高。

公开(公告)号：US20120296136A1

公开(公告)日：2012-11-22

申请号：US13457494

申请日：2012-04-27

Applicant: Sivadinarayana Chinta

Inventor： Sivadinarayana Chinta

IPC: C07C2/88

CPC classification number: B01J8/0465 ,  B01J8/0488 ,  B01J2219/00006 ,  B01J2219/00038 ,  B01J2219/0004 ,  C07C2/864 ,  C07C2/865 ,  C07C2/867 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/12 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/28 ,  C07C2523/34 ,  C07C2523/50 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2529/08 ,  C07C15/46

Abstract: A process is disclosed for making styrene and/or ethylbenzene by reacting toluene with a C1 source over a catalyst in at least one radial reactor to form a product stream comprising styrene and/or ethylbenzene.

Abstract translation: 公开了通过在至少一个径向反应器中的催化剂上使甲苯与C1源反应以形成包含苯乙烯和/或乙苯的产物流来制备苯乙烯和/或乙苯的方法。

公开(公告)号：US20120296133A1

公开(公告)日：2012-11-22

申请号：US13557398

申请日：2012-07-25

Applicant: James R. Butler

Inventor： James R. Butler

IPC: C07C2/64 ,  B01J14/00 ,  B23P23/00 ,  B01J10/00

CPC classification number: C07C15/46 ,  B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00862 ,  B01J2219/00873 ,  C07C2/66 ,  C07C2/84 ,  C07C5/48 ,  Y10S585/921 ,  Y10S585/943 ,  Y10T29/49716 ,  C07C15/073

Abstract: A process for making ethylbenzene and/or styrene by reacting toluene with methane in one or more microreactors is disclosed. In one embodiment a method of revamping an existing styrene production facility by adding one or more microreactors capable of reacting toluene with methane to produce a product stream comprising ethylbenzene and/or styrene is disclosed.

公开(公告)号：US20120296044A1

公开(公告)日：2012-11-22

申请号：US13562096

申请日：2012-07-30

Applicant: Fengkui Li ,  Tim J. Coffy ,  Michel Daumerie

Inventor： Fengkui Li ,  Tim J. Coffy ,  Michel Daumerie

IPC: C08L23/16 ,  C08L67/04

CPC classification number: C08L67/00 ,  B29C45/0001 ,  B29K2105/0088 ,  B29K2623/10 ,  B29K2667/046 ,  C08J5/18 ,  C08J2323/10 ,  C08J2467/04 ,  C08L9/00 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L51/06 ,  C08L67/04 ,  C08L2205/03 ,  Y10T428/24 ,  Y10T428/269 ,  C08L2666/18

Abstract: A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.