公开(公告)号：US4208347A

公开(公告)日：1980-06-17

申请号：US901816

申请日：1978-05-01

申请人： Giorgio Pagani

发明人： Giorgio Pagani

IPC分类号： C07C67/00 ,  C07C239/00 ,  C07C273/04 ,  C07C126/02

CPC分类号： C07C273/04

摘要： An improved isobaric double-recycle process is disclosed for synthesizing urea with the formation of ammonium carbamate as an intermediate, comprising effecting reaction between ammonia and carbon dioxide at high NH.sub.3 :CO.sub.2 molar ratios, a heat-treatment of the synthesis product at substantially the same pressure as that of the synthesis step and in the presence of a stripping gas, and two distinct isobaric recycles of the residual substances and of the substances in excess released from said synthesis product, said process being characterized in that:(a) said heat-treatment of the synthesis product is carried out in two consecutive stages which are isobaric or substantially isobaric with respect to the synthesis step, in the first of which stages said synthesis product is heated, whereby substantially all the residual ammonium carbamate is decomposed and the decomposition products are displaced together with part of the excess NH.sub.3, while in the second stage the remaining part of the NH.sub.3 excess is displaced by supplying supplemental heat and by injecting thereto a CO.sub.2 stream; and(b) the gas phase stripped in the first stage is immediately recycled to the synthesis step and the gas phase stripped in the second stage is subjected to a condensation and to a residual gas purge and then recycled, in the liquid state, to the synthesis step.The synthesis temperature may range from 170.degree. to 205.degree. C., the synthesis pressure from between 100 and 250 Kg/cm.sup.2, and the NH.sub.3 :CO.sub.2 molar ratio during the synthesis from 2.5:1 to 10:1.Suitable apparatus for carrying out the process is also disclosed.

摘要翻译： 公开了一种改进的等压双重循环方法，用于合成尿素形成氨基甲酸铵作为中间体，其包括在高NH 3 :CO 2摩尔比下进行氨和二氧化碳之间的反应，合成产物的热处理基本相同 所述方法的特征在于：（a）所述热处理工序，其特征在于：（a）在所述合成步骤中， 合成产物的处理在相对于合成步骤的等压或基本上同位压的两个连续阶段中进行，其中第一步是将所述合成产物加热，从而基本上所有残留的氨基甲酸铵分解，分解产物 与一部分过量的NH 3一起置换，而在第二阶段NH 3的剩余部分 通过提供补充热量并通过向其中注入二氧化碳流而使多余的物质流离失所; 和（b）将在第一阶段中汽提的气相立即循环到合成步骤，并将在第二阶段中汽提的气相进行冷凝和残留气体吹扫，然后以液态循环至 合成步骤。 合成温度范围为170〜205℃，合成压力为100〜250Kg / cm2，合成时的NH 3 :CO 2摩尔比为2.5:1〜10:1。 还公开了用于执行该方法的合适装置。

公开(公告)号：US4203882A

公开(公告)日：1980-05-20

申请号：US954206

申请日：1978-10-24

申请人： Guido Bertelli ,  Pierpaolo Roma ,  Renato Locatelli

发明人： Guido Bertelli ,  Pierpaolo Roma ,  Renato Locatelli

IPC分类号： C08K3/26 ,  C08K5/34 ,  C08K13/02 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L51/00 ,  C08L51/02 ,  C08L53/00 ,  C08L77/00 ,  C08L101/00 ,  C08L91/00

CPC分类号： C08K3/26 ,  C08K13/02 ,  C08L53/00

摘要： The invention concerns impact resistant polymeric compositions having flame-resistance properties and comprising:(1) a blend of (a) 95-80% by weight of a thermoplastic block propylene-ethylene copolymer containing from 3 to 20% by weight of copolymerized ethylene, and(b) 5-20% by weight of an elastomeric ethylene-propylene copolymer containing from 50 to 70% by weight of copolymerized ethylene;(2) 0.5-5% of basic bismuth carbonate (BiO).sub.2 CO.sub.3 ;(3) 0.3-1.3% of a triazine compound selected from the group consisting of melamine, ammeline, ammelide, acetoguanamine, benzoguanamine and isocyanuric acid;(4) 2-10% of a chlorinated paraffin wax; and(5) 0.5-10% of a bromine containing organic compound selected from the group consisting of decabromodiphenyl oxide, octabromodiphenyl oxide, pentabromodiphenyl oxide, 1,2-bis(2.4.6-tribromophenoxy)ethane, pentabromophenol, pentabromotoluene and ethyl-pentabromobenzene;all percentages of anti-flame additives being referred to the total weight of the composition.The foregoing compositions are useful in the manufacture of motor vehicles.

摘要翻译： 本发明涉及具有阻燃性能的耐冲击聚合物组合物，其包含：（a）95-80重量％的含有3-20重量％共聚乙烯的热塑性嵌段丙烯 - 乙烯共聚物的共混物， 和（b）5-20重量％的含有50至70重量％共聚乙烯的弹性体乙烯 - 丙烯共聚物; （2）0.5-5％的碱式碳酸铋（BiO）2CO3; （3）0.3-1.3％的三嗪化合物，选自三聚氰胺，ammeline，ammelide，acetoguanamine，benzoguanamine和异氰脲酸; （4）2-10％的氯化石蜡; 和（5）选自十溴二苯醚，八溴二苯醚，五溴二苯氧基，1,2-双（2.4.6-三溴苯氧基）乙烷，五溴苯酚，五溴甲苯和乙基五溴苯的0.5-10％的含溴有机化合物 ; 所有百分比的抗火焰添加剂都是指组合物的总重量。 上述组合物可用于制造机动车辆。

公开(公告)号：US4198313A

公开(公告)日：1980-04-15

申请号：US860084

申请日：1977-12-13

申请人： Gianangelo Bargigia ,  Gerardo Caporiccio ,  Giuliano Carniselli

发明人： Gianangelo Bargigia ,  Gerardo Caporiccio ,  Giuliano Carniselli

IPC分类号： A61K8/00 ,  A61K8/31 ,  A61L9/01 ,  A61Q5/06 ,  C09K3/30 ,  A61L9/04

CPC分类号： C09K3/30

摘要： The present invention concerns new propellant compositions for aerosols. More particularly, the propellant compositions of this invention consist of a mixture of one or more propelling hydrocarbon substances selected from the group consisting of propane, n-butane, isobutane, pentane and isopentanes with one or more halogenated organic compounds selected from the group consisting of CBrF.sub.3, CBrClF.sub.2 and CBrF.sub.2 -CBrF.sub.2.

摘要翻译： 本发明涉及用于气溶胶的新的推进剂组合物。 更具体地，本发明的推进剂组合物由选自丙烷，正丁烷，异丁烷，戊烷和异戊烷的一种或多种推进烃物质与一种或多种选自以下的卤化有机化合物的混合物组成： CBrF3，CBrClF2和CBrF2-CBrF2。

公开(公告)号：US4189441A

公开(公告)日：1980-02-19

申请号：US818857

申请日：1977-07-25

申请人： Giuseppe Braca ,  Glauco Sbrana ,  Guglielmo Gregorio

发明人： Giuseppe Braca ,  Glauco Sbrana ,  Guglielmo Gregorio

IPC分类号： C07C67/36 ,  B01J31/00 ,  C07B61/00 ,  C07C69/00 ,  H01J25/04 ,  C07C67/28 ,  C07C67/37

CPC分类号： C07C69/00 ,  H01J25/04

摘要： A process is disclosed for preparing esters having the general formulae:RCOOCH.sub.2 R'andR'COOCH.sub.2 Rwherein R and R' are linear or branched alkyl radicals either like or unlike each other, and containing from 1 to 16 carbon atoms, or considered together, forming a cycloaliphatic ring having up to 7 carbon atoms, wherein carbon monoxide and hydrogen are reacted, at temperatures ranging from 150.degree. to 350.degree. C. and at pressures ranging from 50 to 1000 atmospheres, with an ether of formula R O R' or esters of formula RCOOR' and R'COOR, in which R and R' have the same meanings as specified hereinabove, and in the presence of a catalyst system comprising a ruthenium carbonyl and a promoter selected from the class consisting of hydroiodic acid, carboxylic acid solutions of inorganic or tetraalkylammonium bromides and iodides, and mixtures of these promoters.

摘要翻译： 公开了一种制备具有以下通式的酯的方法：RCOOCH2R'和R'COOCH2R，其中R和R'是直链或支链烷基，或者彼此相同或不同，含有1至16个碳原子，或一起考虑，形成 具有至多7个碳原子的脂环族环，其中一氧化碳和氢气在150℃至350℃的温度和50至1000个大气压的压力下反应，与式ROR'的醚或式 RCOOR'和R'COOR，其中R和R'具有与上文相同的含义，并且在包含羰基钌的催化剂体系和选自下列的助催化剂存在下，所述助催化剂选自氢碘酸，无机羧酸溶液 或四烷基溴化铵和碘化物，以及这些促进剂的混合物。

公开(公告)号：US4188470A

公开(公告)日：1980-02-12

申请号：US868618

申请日：1978-01-11

申请人： Amilcare Collina ,  Arrigo Soverini ,  Francesco Rosati

发明人： Amilcare Collina ,  Arrigo Soverini ,  Francesco Rosati

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F110/02 ,  C08F4/02 ,  C08F10/02

CPC分类号： C08F110/02 ,  Y10S526/901 ,  Y10S526/904

摘要： Ethylene is polymerized in a gaseous phase and in contact with a Ziegler/Natta type solid catalyst capable of producing polyethylene in the form of granules having an easily controllable and homogeneous granulometric size, the polymerization being conducted in a tubular reactor in which the catalyst and the polymer granules which are formed are carried along the reactor by the flow of the gas.

摘要翻译： 乙烯在气相中聚合并与能够生产具有容易控制和均匀的粒度尺寸的颗粒形式的聚乙烯的齐格勒/纳塔型固体催化剂接触，聚合在管式反应器中进行，其中催化剂和 形成的聚合物颗粒通过气体的流动沿反应器携带。

公开(公告)号：US4187218A

公开(公告)日：1980-02-05

申请号：US886943

申请日：1978-03-15

申请人： Fabrizio Merlo ,  Giorgio Bornengo ,  Camillo Paffoni

发明人： Fabrizio Merlo ,  Giorgio Bornengo ,  Camillo Paffoni

IPC分类号： C09B29/08 ,  C09B31/04 ,  C09B31/047 ,  D06P1/06 ,  C09B29/36 ,  C09B29/06

CPC分类号： C09B31/047 ,  C09B29/08 ,  C09B29/0803 ,  C09B31/04 ,  D06P1/06

摘要： This invention relates to a class of water-soluble acid azo dyes, containing at least a sulphonic group, having formula (I): ##STR1## wherein the symbols have the following meanings: A is a residue of a diazotizable aromatic or heterocyclic amine, optionally substituted;R is selected from the group consisting of H, CH.sub.3, OCH.sub.3 and OC.sub.2 H.sub.5 ;R.sub.1 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5 ;R.sub.2 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5.The dyes which are the object of the present invention exhibit shades varying from yellow to blue and are useful for dyeing and printing natural polyamide fibres (wool and silk) and synthetic fibres (nylon). They possess an excellent affinity in both an acid bath and a neutral bath and an excellent tinting power. The dyes obtained are characterized by a remarkable purity of shade, by an excellent stability to sunlight, to washing and to sweat, as well as by a good equalizing power on nylon.

摘要翻译： 本发明涉及一类含有至少一个具有式（I）的磺酸基的水溶性酸偶氮染料：其中符号具有以下含义：A是可重氮化芳族的残基或 杂环胺，任选取代的; R选自H，CH 3，OCH 3和OC 2 H 5; R1选自CH3和C2H5; R2选自CH3和C2H5。 作为本发明的目的的染料显示从黄色到蓝色的色调，并且可用于染色和印刷天然聚酰胺纤维（羊毛和丝绸）和合成纤维（尼龙）。 它们在酸浴和中性浴中都具有极好的亲和力，并具有优异的着色力。 所得到的染料的特征在于，通过对阳光的良好的稳定性，洗涤和汗水以及通过尼龙的良好的均衡功率，具有显着的阴影纯度。

公开(公告)号：US4186180A

公开(公告)日：1980-01-29

申请号：US897741

申请日：1978-04-17

申请人： Alberto Di Gioacchino ,  Giulio Tommasi ,  Mario de Manuele

发明人： Alberto Di Gioacchino ,  Giulio Tommasi ,  Mario de Manuele

IPC分类号： C01B17/45 ,  C01B17/46

CPC分类号： C01B17/453

摘要： Process and apparatus are disclosed for the preparation of sulphur hexafluoride of high purity, starting from elemental fluorine and sulphur, both in gaseous phase, and operating with an excess of fluorine, characterized in that the fluorine is fed into a reaction chamber through inlets in a metal plate, maintained at between 30.degree. and 70.degree. C., while the sulphur is fed in through the nozzle of a burner, by regulating a current of an inert gas which is saturated with sulphur by passing same through a zone containing molten sulphur at a temperature between 250.degree. and 500.degree. C., and subsequently superheating the inert gas thus saturated with sulphur to a temperature between 300.degree. and 550.degree. C., and introducing a separate current of the same inert gas between the plate and the burner so as to ensure that the flame that develops when the sulphur and the fluorine come into reactive contact with each other shall be kept insulated from the nozzle, and recovering and purifying the resulting sulphur hexafluoride.

摘要翻译： 公开了用于制备高纯度六氟化硫的方法和装置，从元素氟和硫开始，两者在气相中，并且与过量的氟一起操作，其特征在于，氟通过入口中的入口进料到反应室中 金属板保持在30℃和70℃之间，而硫通过燃烧器的喷嘴进入，通过调节硫饱和的惰性气体的电流通过含有熔融硫的区域， 温度在250-500℃之间，然后将硫饱和的惰性气体过热至300-550℃，并在板和燃烧器之间引入相同惰性气体的单独电流，以便 为了确保硫和氟彼此反应接触时产生的火焰应与喷嘴保持绝缘，并回收和净化残余物 六氟化硫。

公开(公告)号：US4182893A

公开(公告)日：1980-01-08

申请号：US897853

申请日：1978-04-19

申请人： Paolo Piccardi ,  Giovanni Confalonieri ,  Pier G. Ramella ,  Lino Da Col

发明人： Paolo Piccardi ,  Giovanni Confalonieri ,  Pier G. Ramella ,  Lino Da Col

IPC分类号： A61K31/415 ,  C07D235/32

CPC分类号： A61K31/415 ,  C07D235/32

摘要： Benzimidazol(2)methylcarbamates substituted in position 5(6) are disclosed, together with a method for preparing them, and use thereof in suitable form for combatting intestinal, pulmonary and hepatic parasites, particularly Helminthes, in animals.

摘要翻译： 公开了在5（6）中被取代的苯并咪唑（2）甲基氨基甲酸酯及其制备方法及其在动物中对肠，肺和肝寄生虫特别是Helminthes的适当形式的应用。

公开(公告)号：US4180639A

公开(公告)日：1979-12-25

申请号：US821394

申请日：1977-08-03

申请人： Gerardo Caporiccio ,  Gianangelo Bargigia ,  Giampiero Guidetti

发明人： Gerardo Caporiccio ,  Gianangelo Bargigia ,  Giampiero Guidetti

IPC分类号： C10M105/72 ,  B01F17/00 ,  B29C33/00 ,  B29C43/00 ,  B29C43/50 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/32 ,  C07C309/03 ,  C07C309/06 ,  C07C309/09 ,  C07C309/10 ,  C07C309/20 ,  C07C309/65 ,  C07C309/80 ,  C07C309/82 ,  C08F8/26 ,  C08F14/00 ,  C08F14/18 ,  C08F16/24 ,  C08F214/18 ,  C08F290/00 ,  C08F299/00 ,  C08J5/22 ,  C08L27/12 ,  C09K3/00 ,  C09K3/18 ,  C10M107/46 ,  C10N40/36 ,  C23G1/08 ,  C25B13/08 ,  C25D3/04 ,  C07C143/16

CPC分类号： C25D3/04 ,  B01F17/0057 ,  C07C309/00 ,  C07C309/10 ,  C07C309/82 ,  C08F16/24 ,  C08F214/184 ,  C23G1/086 ,  C25B13/08

摘要： A new class fluorosulphonyl oxafluoroalkanes and of their derivatives is disclosed as well as a process for preparing said products. Furthermore, a new class of fluorosulphonyl olefins, copolymers thereof and a process for preparing same is also disclosed.

摘要翻译： 公开了一种新的氟磺酰基氧氟烷烃及其衍生物，以及制备所述产物的方法。 此外，还公开了一类新的氟磺酰基烯烃，其共聚物及其制备方法。

公开(公告)号：US4174295A

公开(公告)日：1979-11-13

申请号：US823152

申请日：1977-08-09

申请人： Gianangelo Bargigia ,  Gerardo Caporiccio ,  Giuliano Carniselli

发明人： Gianangelo Bargigia ,  Gerardo Caporiccio ,  Giuliano Carniselli

IPC分类号： C09K3/30 ,  A61K7/06 ,  A61K9/12 ,  A61L9/04

CPC分类号： C09K3/30 ,  Y10S424/01

摘要： The present invention concerns new propellant compositions for aerosols. More particularly, the present invention relates to propellant compositions for aerosols, characterized in that said compositions consist of a mixture of a chlorofluorocarbon or fluorocarbon (A) containing hydrogen and selected from the group consisting of CHClF.sub.2, CH.sub.2 F.sub.2 and CF.sub.3 --CH.sub.3, with a chlorofluorocarbon or fluorocarbon (B) containing hydrogen and selected from the group consisting of: CH.sub.2 ClF, CClF.sub.2 --CHClF, CF.sub.3 --CHClF, CHF.sub.2 --CClF.sub.2, CHClF--CHF.sub.2, CF.sub.3 --CH.sub.2 --Cl, CHF.sub.2 --CHF.sub.2, CF.sub.3 --CH.sub.2 F, CClF.sub.2 --CH.sub.3 and CHF.sub.2 --CH.sub.3. In addition to propellant A and propellant B, there may be included a hydrocarbon propellant so that a ternary propellant composition is provided.

摘要翻译： 本发明涉及用于气溶胶的新的推进剂组合物。 更具体地说，本发明涉及用于气溶胶的推进剂组合物，其特征在于，所述组合物由含氟氢氟烃（A）和含有氢的选自CHClF 2，CH 2 F 2和CF 3 -CH 3的混合物与氯氟烃 或碳氢化合物（B），并且选自：CH 2 ClF，CClF 2 -CHClF，CF 3 -CHClF，CHF 2 -CClF 2，CHClF-CHF 2，CF 3 -CH 2 -C 1，CHF 2 -CHF 2，CF 3 -CH 2 F，CClF 2 -CH 3 和CHF 2 -CH 3。 除了推进剂A和推进剂B之外，还可以包括烃推进剂，从而提供三元推进剂组合物。