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    Acid oxide with micro and mesoporous characteristics: ITQ-36
    61.
    发明授权
    Acid oxide with micro and mesoporous characteristics: ITQ-36 有权
    具有微孔和介孔特性的酸性氧化物：ITQ-36

    公开(公告)号：US06555090B1

    公开(公告)日：2003-04-29

    申请号：US09830819

    申请日：2001-07-06

    申请人： Antonio Chica Lara ,  Avelino Corma Canós ,  Vicente Fornés Segúi ,  Urbano Díaz Morales

    发明人： Antonio Chica Lara ,  Avelino Corma Canós ,  Vicente Fornés Segúi ,  Urbano Díaz Morales

    IPC分类号： C01B3400

    CPC分类号： C01B39/48 ,  B01J29/049 ,  B01J29/70 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42

    摘要： The invention deals with a microporous crystalline material, with a characteristic X-ray diffractogram, comprised of oxygen tetrahedra and a metal (T+4 and T+3) with the possibility of introducing surface acidity produced by the substitution in the lattice of some T+4 cations by T+3 cations, which gives rise to a structural charge deficiency that may be compensated by protons, Brönsted acidity, and/or high ratio radium charge cations, Lewis acidity; and the obtaining method thereof, based on the preparation of a gel, its hydrothermal treatment under controlled conditions and the treatment of the resulting laminar material with a solution of an organic compound, a swollen material being obtained, which is subjected to a treatment for the formation of interlaminar pillars of polymeric oxides, obtaining a pillared material that maintains the separation between the sheets, even after calcination.

    摘要翻译： 本发明涉及一种微孔结晶材料，具有由氧四面体和金属（T + 4和T + 3）组成的特征X射线衍射图，其可能性通过在一些T的晶格中引入由取代产生的表面酸度 + 4阳离子，其导致结构电荷缺陷，其可以通过质子，布朗斯台德酸度和/或高比例镭电荷阳离子，路易斯酸度; 以及其获得方法，基于凝胶的制备，其在受控条件下的水热处理，以及所得到的层状材料用有机化合物（获得的溶胀物质）的溶液进行处理， 形成聚合物氧化物的层间柱，获得即使在煅烧之后也保持片材之间的分离的柱状材料。

    Superior pillared clay catalysts for selective catalytic reduction of nitrogen oxides for power plant emission control
    63.
    发明授权
    Superior pillared clay catalysts for selective catalytic reduction of nitrogen oxides for power plant emission control 失效
    用于选择性催化还原氮氧化物用于发电厂排放控制的优质柱状粘土催化剂

    公开(公告)号：US06521559B1

    公开(公告)日：2003-02-18

    申请号：US09580382

    申请日：2000-05-26

    申请人： Ruiqiang Long ,  Ralph T. Yang ,  Kent D. Zammit

    发明人： Ruiqiang Long ,  Ralph T. Yang ,  Kent D. Zammit

    IPC分类号： B01J2116

    CPC分类号： B01J29/049 ,  B01D53/8628 ,  Y02C20/10

    摘要： The present invention provides a catalyst for selective catalytic reduction of nitrogen oxide compounds with ammonia comprising a composition of one or more pillared interlayered clays, one or more metal ions exchanged with the pillared interlayered clays, and one or more promoter ions exchanged with the pillared interlayered clays. Specifically, the pillared interlayered clay (PILC) catalysts of the present invention include Fe3+, Cr3+, Mn2+, Co2+, Cu2+, and Ni2+ exchanged Al2O3-PILC, TiO2-PILC, ZrO2-PILC or SiO2-PILC catalysts. The promoters include Ce, La, Pr, Th and Nd. These pillared clay catalysts of the present invention show remarkable activity for the SCR reaction.

    摘要翻译： 本发明提供了一种用氨选择性催化还原氮氧化合物的催化剂，包括一个或多个柱状夹层粘土的组合物，一个或多个金属离子与柱状夹层粘土交换的一种或多种金属离子，以及与柱状夹层交换的一种或多种促进剂离子 粘土 具体来说，本发明的柱状层间粘土（PILC）催化剂包括Fe3 +，Cr3 +，Mn2 +，Co2 +，Cu2 +和Ni2 +交换的Al2O3-PILC，TiO2-PILC，ZrO2-PILC或SiO2-PILC催化剂。 助催化剂包括Ce，La，Pr，Th和Nd。 本发明的这些柱状粘土催化剂对SCR反应显示出显着的活性。

    Pillared clay catalysts for heavy oil catalytic pyrolisis process and the preparation method thereof
    64.
    发明授权
    Pillared clay catalysts for heavy oil catalytic pyrolisis process and the preparation method thereof 有权
    用于重油催化热解法的悬浮粘土催化剂及其制备方法

    公开(公告)号：US06342153B1

    公开(公告)日：2002-01-29

    申请号：US09219119

    申请日：1998-12-23

    申请人： Jingjie Guan ,  Xieqing Wang ,  Zhiqing Yu ,  Zhengyu Chen ,  Qinglin Liu ,  Yi Liao

    发明人： Jingjie Guan ,  Xieqing Wang ,  Zhiqing Yu ,  Zhengyu Chen ,  Qinglin Liu ,  Yi Liao

    IPC分类号： C10G1102

    CPC分类号： C10G11/04 ,  B01J20/10 ,  B01J20/12 ,  B01J29/005 ,  B01J29/049 ,  B01J29/084 ,  B01J29/40 ,  B01J2229/186 ,  B01J2229/42

    摘要： Pillared clay catalysts for converting heavy oil or residual feedstock into maximum ethylene, propylene and butylene products comprises 30-75 wt % special pillared clays prepared by aluminum pillaring agents of high alkaline degree, 10-40 wt % inorganic oxide bonding agents, 0-30 wt % ZRP series high silicon zeolites with pentasil structure or Y-type zeolites, 0-10 wt % modified compositions of Mg, Al, K, P, Sn and polyethylene gycol, or 0-50 wt % Kaolinite matrix. The catalysts are prepared by mixing slurries, spray drying to form microspheric shapes, pillaring reaction and adding modified components. The catalysts have high catalytic activities, good light olefin selectivities and attrition resistance index. The products are suitable to be used as catalysts for hydrocarbon conversion, including CPP-catalyst for catalytic pyrolysis processes to convert heavy oil into ethylene and propylene, MIO-catalyst for yielding more isobutene and isoamylene products, and FCC-catalyst for yielding more gasoline and light cycle oil from heavy oil or residual feedstock, and also as adsorbents or catalyst carriers.

    摘要翻译： 用于将重油或残余原料转化为最大乙烯，丙烯和丁烯产品的柱状粘土催化剂包含由高碱度，10-40重量％无机氧化物粘合剂，0-30重量％的铝支撑剂制备的30-75重量％的特殊柱状粘土 wt％的具有pentasil结构的ZRP系列高硅沸石或Y型沸石，0-10wt％的Mg，Al，K，P，Sn和聚乙烯gycol的改性组合物，或0-50wt％的高岭石基质。 催化剂通过混合浆料，喷雾干燥以形成微球形状，柱反应和加入改性成分来制备。 催化剂具有高催化活性，良好的轻烯烃选择性和耐磨指数。 该产品适用于烃转化催化剂，包括用于将重油转化为乙烯和丙烯的催化裂解方法的CPP催化剂，用于产生更多异丁烯和异戊烯产物的MIO催化剂，以及用于产生更多汽油的FCC催化剂 来自重油或残余原料的轻循环油，以及作为吸附剂或催化剂载体。

    Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation
    66.
    发明授权
    Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
    介孔金属硅酸盐分子筛的催化应用及其制备方法

    公开(公告)号：US06193943B1

    公开(公告)日：2001-02-27

    申请号：US08797718

    申请日：1997-02-11

    申请人： Thomas J. Pinnavaia ,  Peter T. Tanev ,  Wenzhong Zhang ,  Jialiang Wang ,  Malama Chibwe

    发明人： Thomas J. Pinnavaia ,  Peter T. Tanev ,  Wenzhong Zhang ,  Jialiang Wang ,  Malama Chibwe

    IPC分类号： C01B3338

    CPC分类号： B01J21/04 ,  B01J21/066 ,  B01J23/14 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/046 ,  B01J29/049 ,  B01J29/89 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/036 ,  C01B33/20 ,  C01B37/00 ,  C01B37/005 ,  C01B37/02 ,  C07C46/06 ,  C07C46/08

    摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X·I+ templating pathway (Pathway 3) and mild reaction conditions. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 Å) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.

    摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合 同时通过简单的溶剂萃取提供中性模板的简便回收。 中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。 此外，已经使用介导的S + X.I +模板途径（途径3）和温和的反应条件制备了类似于MCM-41的六方晶过渡金属取代的催化剂。这些新的介孔金属硅酸盐分子筛显示出极好的催化活性 苯的过氧化羟基化和具有太大（大于6）的动力学直径的取代芳族化合物的氧化，以进入常规的微孔过渡金属取代的分子筛如钛和钒硅酸盐的孔结构。

    Process for isomerization of normal C5-C10 paraffins using bridged long-reticulate-distance dioctahedral phyllosilicate 2:1
    67.
    发明授权
    Process for isomerization of normal C5-C10 paraffins using bridged long-reticulate-distance dioctahedral phyllosilicate 2:1 失效
    使用桥接长网状距离二八面体页硅酸盐2：1异构化正常C5-C10链烷烃的方法

    公开(公告)号：US06191333B1

    公开(公告)日：2001-02-20

    申请号：US09198606

    申请日：1998-11-24

    申请人： Eric Benazzi ,  Jocelyne Brendle ,  Ronan Le Dred ,  Jacques Baron ,  Daniel Saehr

    发明人： Eric Benazzi ,  Jocelyne Brendle ,  Ronan Le Dred ,  Jacques Baron ,  Daniel Saehr

    IPC分类号： C07C513

    CPC分类号： B01J29/049 ,  B01J23/40 ,  B01J23/74 ,  C07C5/2791 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  C10G45/60 ,  C07C9/00

    摘要： This invention pertains to the use of a catalyst that contains at least one dioctahedral phyllosilicate 2:1, which is preferably synthesized in a fluoride medium in the presence of HF acid and/or another source of fluoride anions, whose reticulate distance is equal to at least 20×10−10 m (2 nm) and which includes pillars that are based on at least one oxide from the elements of groups IVB, VB, VIB, VIII, IB, IIB, IIA, IVA, or any combination of these oxides, and preferably selected from the group composed of SiO2, Al2O3, TiO2, ZrO2, and V2O5, or any combination of the latter and at least one element from group VIII, in a process for isomerization of a feedstock that contains mainly normal paraffins that carry 5 to 10 carbon atoms per molecule.

    摘要翻译： 本发明涉及使用含有至少一种双八面体页硅酸盐2:1的催化剂，其优选在HF酸和/或另一种氟化物阴离子的存在下在氟化物介质中合成，其中网状距离等于 至少20x10 -10 m（2nm），其包括基于IVB，VB，VIB，VIII，IB，IIB，IIA，IVA族元素或这些氧化物的任何组合的至少一种氧化物的柱，以及 优选选自由SiO 2，Al 2 O 3，TiO 2，ZrO 2和V 2 O 5组成的组，或者后者和来自VIII族的至少一种元素的任何组合，在主要含有主要正常链烷烃的原料异构化的方法中，其携带5至 每个分子10个碳原子。

    Pillared clay containing fluorided pillars
    70.
    发明授权
    Pillared clay containing fluorided pillars 失效
    含有氟化支柱的柱状粘土

    公开(公告)号：US5389593A

    公开(公告)日：1995-02-14

    申请号：US133939

    申请日：1993-10-12

    申请人： Jennifer S. Holmgren

    发明人： Jennifer S. Holmgren

    IPC分类号： B01J21/16 ,  B01J29/04 ,  C07C4/06 ,  C10G47/04 ,  B01J37/00

    CPC分类号： B01J29/049

    摘要： Novel pillared clay compositions have been synthesized. The clay contains pillars which are at least partially fluorided. These pillars are metal fluoro hydroxy cations where the metal can be Al, Zr, Si/Al, Ti or Cr. The clays which can be pillared with these pillars are the smectite clays which include hectorite and beidellite along with synthetically prepared smectite clays. These clays are prepared by pillaring the clay, followed by calcination and then treatment with a fluoride salt such as ammonium bifluoride. Finally, these fluorided pillared clays find applications in hydrocarbon conversion processes such as alkylation.

    摘要翻译： 已经合成了新的柱状粘土组合物。 粘土含有至少部分氟化的柱。 这些柱是金属氟羟基阳离子，其中金属可以是Al，Zr，Si / Al，Ti或Cr。 可以用这些柱子支撑的粘土是蒙脱石粘土，包括锂蒙脱石和贝得石以及合成制备的绿土粘土。 这些粘土是通过对粘土进行支撑制备的，随后煅烧，然后用氟化盐如氟化铵处理。 最后，这些氟化柱状粘土在烃转化过程如烷基化中得到应用。