摘要:
The present invention relates to stevensite or kerolite type trioctahedral phyllosilicates 2:1 containing fluorine, fluorinated in synthesis in an acid medium and modified post-synthesis to bring about Si/Al and/or Mg/Al substitutions which impart acid properties to the solid. These phyllosilicates may be incorporated in the composition of catalysts used to convert hydrocarbons, in particular for hydrocracking.
摘要:
The invention relates to dioctahedral phyllosilicates 2:1 whose basal spacing is at least equal to 2.0.times.10.sup.-9 m and which in the interlayer space comprise pillars based on at least one of the compounds that is selected from the group that is formed by SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, V.sub.2 O.sub.5, or any combination of the latter. Preferably, they contain fluorine. The invention also relates to a process for their preparation that includes treatment with a surfactant, followed by treatment with a primary or secondary amine and at least one alkoxide of an element that is selected from the group that is formed by the elements Si, Al, Zr, Ti and V. The invention also relates to a catalyst that comprises said phyllosilicate, at least one matrix, and optionally a zeolite Y. The invention also relates to a process for converting hydrocarbons with this catalyst, and in particular a hydrocracking process.
摘要翻译:本发明涉及基面间距至少等于2.0×10 -9 m的双八面体页硅酸盐2:1,其中在层间空间中包含基于选自由SiO 2形成的基团中的至少一种化合物的柱, Al 2 O 3,TiO 2,ZrO 2,V 2 O 5或后者的任意组合。 优选地,它们含有氟。 本发明还涉及一种其制备方法,其包括用表面活性剂处理,然后用伯胺或仲胺和至少一种选自下列元素的醇盐进行处理:元素Si,Al, Zr,Ti和V.本发明还涉及包含所述页硅酸盐,至少一种基质和任选的沸石Y的催化剂。本发明还涉及用该催化剂转化烃,特别是加氢裂化方法的方法。
摘要:
Described is a process for the treatment of at least one zeolite having a pore size of less than or equal to 7 Å comprising at least a) a step for dealumination of said zeolite, b) a cationic exchange step using at least one cation other than H+, c) a step for treatment of said zeolite obtained in step b) in the presence of at least one molecular compound containing at least one silicon atom, and d) at least one heat treatment step. The present invention also concerns the preparation of a catalyst containing the zeolite treated in accordance with the treatment process the subject-matter of the invention and the use of said catalyst in a process for the oligomerization of an olefinic charge containing hydrocarbon molecules having from 2 to 12 carbon atoms per molecule.
摘要翻译:描述了一种处理至少一种孔径小于或等于7的至少一种沸石的方法,该沸石至少包括a)使所述沸石脱铝的步骤,b)使用至少一种阳离子以外的阳离子交换步骤 H +,c)在至少一种含有至少一个硅原子的分子化合物的存在下,在步骤b)中得到的所述沸石的处理步骤,和d)至少一个热处理步骤。 本发明还涉及含有根据本发明主题的处理方法处理的沸石的催化剂的制备以及所述催化剂在含有烃分子的烯烃电荷低聚方法中的用途, 每个分子12个碳原子。
摘要:
A catalyst is described comprising at least one zeolite with structure type EUO, at least one zeolite with structure type NES, at least one metal selected from metals from groups IIIA, VIIB, VIIB and VIII and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
摘要:
A reaction device includes staged zones making it possible to implement strongly endothermic or exothermic reactions. The device reduces the differences in catalytic activity between these zones using an addition of fresh or regenerated catalyst at the inlet of each reaction zone and provides an integrated heat exchanger. A process of chemical conversion employs the device for gas-phase and/or liquid-phase exothermic or endothermic reactions, and in particular for the oligomerization reaction of C2 to C12 fractions for the purpose of producing a diesel fraction.
摘要:
Described is a process for the treatment of at least one zeolite having a pore size of less than or equal to 7 Å comprising at least a) a step for dealumination of said zeolite, b) a cationic exchange step using at least one cation other than H+, c) a step for treatment of said zeolite obtained in step b) in the presence of at least one molecular compound containing at least one silicon atom, and d) at least one heat treatment step. The present invention also concerns the preparation of a catalyst containing the zeolite treated in accordance with the treatment process the subject-matter of the invention and the use of said catalyst in a process for the oligomerisation of an olefinic charge containing hydrocarbon molecules having from 2 to 12 carbon atoms per molecule.
摘要:
The invention concerns a process for producing propylene, especially from a light steam cracking and/or catalytic cracking cut, preferably comprising both butenes and pentenes, said process comprising a step for moving bed catalytic cracking with a catalyst regeneration loop. The catalyst comprises at least one zeolite with a zeolitic composition with a Si/Al ratio which is preferably less than 130. The invention can produce a high conversion with a good yield of propylene at a high space velocity, meaning that the volume of catalyst can be reduced.
摘要:
A process for regeneration of a catalyst that comprises at least one EUO-structural-type zeolite in acid form and at least one hydro-dehydrogenating metal, used in a process for isomerization of a hydrocarbon feedstock that comprises aromatic compounds with eight carbon atoms, comprising at least a) a stage for eliminating a majority of the coke, deposited on said catalyst, by combustion in the presence of a gas that contains oxygen at a temperature that is less than or equal to 600° C., and b) a stage for oxychlorination of the product that is obtained from stage a), carried out between 200 and 550° C. in the presence of at least one gas mixture that contains at least oxygen, water and chlorine and/or at least one chlorinated compound, is described.
摘要:
The invention concerns a zeolite with structure type EUO comprising EUO zeolite crystals with a size of less than 5 &mgr;m, at least a portion of the EUO zeolite crystals being in the form of EUO zeolite aggregates, characterized in that the granulometry of the aggregates is such that Dv,90 is 500 &mgr;m or less. The invention also concerns the preparation of the zeolite and the use of the zeolite as a catalyst, for example in a process for isomerising aromatic compounds containing 8 carbon atoms per molecule.
摘要:
The present invention relates to a process for activating catalysts for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization and at least one passivation using ammonia.