Process for recovering sulfur while sponging light hydrocarbons from hydrodesulfurization hydrogen recycle streams
    62.
    发明申请
    Process for recovering sulfur while sponging light hydrocarbons from hydrodesulfurization hydrogen recycle streams 审中-公开
    用于从加氢脱硫氢循环流中吸收轻质烃的硫回收方法

    公开(公告)号:US20030057136A1

    公开(公告)日:2003-03-27

    申请号:US10223843

    申请日:2002-08-20

    Abstract: In a conventional hydrodesulfurization process sulfur is removed from liquid hydrocarbons by reacting the sulfur in the liquid hydrocarbons with hydrogen to form H2S. A sour hydrogen gas stream consisting of unreacted hydrogen, H2S, and undesired light hydrocarbons is then separated from the liquid hydrocarbons, and the H2S is removed to sweeten the hydrogen stream for recycling. Some of the undesired light hydrocarbons resulting from the reaction may be separated by the purging method discussed. In the present invention efficient separation of the light hydrocarbons is enabled without substantial loss of recyclable hydrogen. Both the H2S and light hydrocarbons are separated from the sour hydrogen gas stream by passing the stream through an absorber where it is reacted with a nonaqueous liquor. The light hydrocarbons are absorbed in the liquor, from which they are subsequently separated.

    Abstract translation: 在常规的加氢脱硫方法中,通过使液体烃中的硫与氢反应形成H 2 S,从液体烃中除去硫。 然后将由未反应的氢,H 2 S和不需要的轻质烃组成的酸性氢气流从液体烃中分离出来,并且除去H 2 S以使氢气流再循环。 由反应产生的一些不期望的轻烃可以通过所述的清洗方法分离。 在本发明中,轻质烃的有效分离是可以实现的,而不会显着损失可再循环的氢。 将H2S和轻质烃与酸性氢气流分离,使其流过吸收器,在其中与非水溶液反应。 轻质烃被吸收在液体中,随后将其分离。

    Flow cell for chemical reactions
    64.
    发明申请
    Flow cell for chemical reactions 失效
    用于化学反应的流通池

    公开(公告)号:US20030003504A1

    公开(公告)日:2003-01-02

    申请号:US09896596

    申请日:2001-06-29

    Abstract: Devices and methods are disclosed for synthesizing compounds on the surface of supports. The devices are flow devices, which include a housing comprising a housing chamber. The housing has an opening adapted for insertion of a support into the housing chamber. A sealing member is movably mounted in the housing chamber and adapted to engage the support to form a reagent chamber between a surface of the support and a surface of the sealing member. A mechanism is included for moving the sealing member within the housing chamber. The device has both an inlet and an outlet, which are both in fluid communication with the reagent chamber. In the methods of the invention a support is placed into a chamber of a device such as described above. The mechanism adapted to engage the support on a surface opposite the surface engaged by the sealing member is activated to urge the support toward the sealing member. The pressure-activated mechanism is activated to urge the support against the aforesaid mechanism and against an interior wall of the housing chamber to form the reagent chamber. A fluid reagent for conducting the reaction step is introduced into the reagent chamber by means of the inlet. Thereafter, the fluid reagent is removed from the reagent chamber. The pressure-activated mechanism is deactivated and the support is removed from the housing chamber. In this way the reagent chamber is formed and un-formed in situ.

    Abstract translation: 公开了用于在载体表面上合成化合物的装置和方法。 装置是流动装置,其包括包括容纳室的壳体。 壳体具有适于将支撑件插入到容纳室中的开口。 密封构件可移动地安装在容纳室中并且适于接合支撑件以在支撑件的表面和密封构件的表面之间形成试剂室。 包括用于使密封构件在壳体室内移动的机构。 该装置具有入口和出口,它们都与试剂室流体连通。 在本发明的方法中,将支撑件放置在如上所述的装置的室中。 适于将支撑件接合在与由密封构件接合的表面相对的表面上的机构被启动以将支撑件推向密封构件。 压力启动机构被启动,以推动支撑件抵靠上述机构并抵靠壳体室的内壁以形成试剂室。 用于进行反应步骤的流体试剂通过入口引入试剂室。 此后,将流体试剂从试剂室中取出。 压力启动机构被停用,并且支撑件从壳体室移除。 以这种方式,试剂室在原位形成和未形成。

    Method and apparatus for removing substances from gases
    65.
    发明申请
    Method and apparatus for removing substances from gases 审中-公开
    从气体中去除物质的方法和设备

    公开(公告)号:US20020187084A1

    公开(公告)日:2002-12-12

    申请号:US10205296

    申请日:2002-07-24

    CPC classification number: B01D53/34

    Abstract: The present invention concerns a method and an apparatus for removing substances from gases discharged from gas phase reactors. In particular, the invention provides a method for removing substances contained in gases discharged from an ALD reaction process, comprising contacting the gases with a nullsacrificialnull material having a high surface area kept at essentially the same conditions as those prevailing during the gas phase reaction process. The sacrificial material is thus subjected to surface reactions with the substances contained in the gases to form a reaction product on the surface of the sacrificial material and to remove the substances from the gases. The present invention diminishes the amount of waste produced in the gas phase process and reduces wear on the equipment.

    Abstract translation: 本发明涉及从气相反应器排出的气体中去除物质的方法和装置。 特别地,本发明提供了一种用于除去从ALD反应过程排出的气体中所含的物质的方法,包括使气体与具有高表面积的“牺牲”材料接触,所述“牺牲”材料保持在与气相反应期间基本相同的条件 处理。 因此牺牲材料与包含在气体中的物质进行表面反应,以在牺牲材料的表面上形成反应产物,并从气体中除去物质。 本发明减少了在气相工艺中产生的废物的量并减少了设备上的磨损。

    Plasma based trace metal removal apparatus and method
    66.
    发明申请
    Plasma based trace metal removal apparatus and method 失效
    等离子体微量金属去除装置及方法

    公开(公告)号:US20020166761A1

    公开(公告)日:2002-11-14

    申请号:US10133688

    申请日:2002-04-26

    Abstract: A system and method for the removal of metals such as mercury from a gas stream. The method involves contacting a gas stream containing the target metals with reactive chemical species generated in a plasma device. The metal to be removed is chemically converted into forms enabling capture in either conventional particulate removal devices or in a wet scrubber for the capture of a soluble chemical species.

    Abstract translation: 用于从气流中去除金属如汞的系统和方法。 该方法包括使含有目标金属的气流与在等离子体装置中产生的活性化学物质接触。 待除去的金属被化学转化成能够在常规的微粒去除装置或湿式洗涤器中捕获以捕获可溶化学物质的形式。

    Reactor for generating moisture
    68.
    发明申请
    Reactor for generating moisture 审中-公开
    反应器产生水分

    公开(公告)号:US20020136676A1

    公开(公告)日:2002-09-26

    申请号:US10096247

    申请日:2002-03-12

    CPC classification number: C01B5/00 B01J12/007

    Abstract: A reactor (2) for generating moisture in which the starting material gases are caused to undergo turbulence so as to increase the efficiency of the moisture-generating reaction. The reactor (2) for generating moisture comprises a first inlet-side reactor structural component (4) which is adapted to supply the starting material gases from a starting material gas feed port into the inlet side of an interior space; a second outlet-side reactor structural component (2) which is adapted to transfer generated gas to a moisture gas take-out port (30a) from a moisture gas feed passage (28); a reflector (12) clamped air-tightly between the first and second structural components (4, 20 ) and having a plurality of blowing holes (16) at predetermined locations for communicating with the inlet-side interior space (8); a reactor chamber (18) formed with a narrow gap d provided between the reflector (12) and the second structural component (20); a nozzle hole (24) formed in the second structural component (20) for communicating with the moisture gas feed passage (28); and a coating catalyst layer (21) formed on a wall surface (20a) of the reaction chamber opposing the reflector (12); wherein when hydrogen and oxygen gas fed from the starting material gas feed port flow into the reaction chamber (18) through the blowing holes (16) in the reflector (12), they react and generate moisture gas by a non-combustive pathway by the catalytic effect of the coating catalyst layer (21)

    Abstract translation: 一种用于产生水分的反应器(2),其中使起始材料气体发生湍流,以提高发生水反应的效率。 用于产生水分的反应器(2)包括第一入口侧反应器结构部件(4),其适于将起始原料气体进料口供应到内部空间的入口侧; 第二出口侧反应器结构部件(2),其适于将产生的气体从湿气供给通道(28)转移到湿气输出口(30a); 在第一和第二结构部件(4,20)之间气密地夹紧并且在预定位置具有多个吹风孔(16)的反射器(12),用于与入口侧内部空间(8)连通; 形成有设置在反射器(12)和第二结构部件(20)之间的窄间隙d的反应室(18); 形成在第二结构部件(20)中的用于与湿气供给通道(28)连通的喷嘴孔(24); 以及形成在所述反应室的与所述反射体(12)相对的壁面(20a)上的涂层催化剂层(21)。 其中当从原料气体供给口供给的氢气和氧气通过反射器(12)中的吹出孔(16)流入反应室(18)时,它们通过非燃烧途径反应并产生湿气 涂层催化剂层(21)的催化作用

    Process utilizing two zones for making single-wall carbon nanotubes
    69.
    发明申请
    Process utilizing two zones for making single-wall carbon nanotubes 审中-公开
    使用两个区域制造单壁碳纳米管的方法

    公开(公告)号:US20020102193A1

    公开(公告)日:2002-08-01

    申请号:US10059871

    申请日:2002-01-29

    Abstract: The present invention discloses a gas-phase method for producing high yields of single-wall carbon nanotubes with high purity and homogeneity. The method involves separating the step of catalyst cluster formation from initiation and growth of the single-wall carbon nanotubes. The method involves reacting catalyst precursors and forming catalyst clusters of the size desirable to promote initiation and growth of single-wall carbon nanotubes prior to mixing with a carbon-containing feedstock at a reaction temperature and pressure sufficient to produce single-wall carbon nanotubes. The catalyst cluster reactions may be initiated either by rapid heating or by photolysis by high energy electromagnetic radiation, such as a laser, or both. The carbon feedstock gas for single-wall carbon nanotube synthesis is preferably CO or methane, catalyzed by the catalyst clusters, preferably iron or a combination of iron and nickel.

    Abstract translation: 本发明公开了一种高纯度,均匀性高的单壁碳纳米管的气相法。 该方法包括将催化剂簇形成步骤与单壁碳纳米管的起始和生长分离。 该方法包括使催化剂前体反应,并在与含碳原料混合之前,在足以产生单壁碳纳米管的反应温度和压力下,使所需尺寸的催化剂簇反应形成促进单壁碳纳米管的起始和生长。 催化剂簇反应可以通过快速加热或通过高能电磁辐射例如激光或两者的光解来引发。 用于单壁碳纳米管合成的碳原料气体优选为CO或甲烷,由催化剂簇,优选铁或铁和镍的组合催化。

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