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公开(公告)号：US10221495B2
公开(公告)日：2019-03-05
申请号：US14781436
申请日：2014-04-03
Applicant: INDUSTRIE DE NORA S.P.A.
Inventor： Alessandro Fiorucci , Alice Calderara , Luciano Iacopetti , Giuseppe Faita
Abstract: The invention relates to a cell for metal electrowinning equipped with a device useful for preventing the adverse effects of dendrite growth on the cathodic deposit. The cell comprises a porous conductive screen, positioned between the anode and the cathode, capable of stopping the growth of dendrites and preventing them from reaching the anode surface.
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公开(公告)号：US20180179651A1
公开(公告)日：2018-06-28
申请号：US15738829
申请日：2016-07-22
Applicant: INDUSTRIE DE NORA S.P.A.
Inventor： Corrado MOJANA , Luciano IACOPETTI , Andrea GOZZO , Roberto PAGANO
Abstract: This invention relates to electrodic apparatus suitable for the electrodeposition of nonferrous metals, for example for the electrolytic production of copper and other nonferrous metals from solutions of ions, comprising an electrode and at least one ionpermeable screen intended for protection of the said electrode.
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公开(公告)号：US20180016684A1
公开(公告)日：2018-01-18
申请号：US15548918
申请日：2016-02-04
Applicant: Jaime Roberto SIMPSON ALVAREZ , PROTECH SPA
Inventor： Jaime Roberto SIMPSON ALVAREZ
Abstract: The invention relates to a combined electrolytic system for precipitating different types of metals (copper, zinc, nickel, cadmium, cobalt, silver, gold) and regenerating reagents for the leaching of metal sulphurs from solutions from leaching in a sulphuric-oxidising or hydrochloric-oxidising environment, including a process that permits the combining of the current reduction processes followed by oxidising processes which are complex and potentially dangerous from an environmental point of view, thereby preventing the risky transportation of dangerous substances, loading and unloading operations, storage and manipulation of toxic materials, and reducing the environmentally contaminating waste, producing a commercial-quality cathodic product and a solution that is re-used in the leaching process. The system comprises a membrane cell device (3) that is connected via ducts and valves to one or more oxidising agent tanks (7), to one or more anodic solution tanks (6) and to one or more cathodic solution tanks (2), wherein said membrane device (3) is formed by one or more cathodic compartments (4) and by one or more anode compartments (5), wherein each of the cathodic compartment(s) (4) is/are separated from each of the anode compartment(s) (5) by a membrane for selective and uni-directional ion exchange.
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公开(公告)号：US09834449B2
公开(公告)日：2017-12-05
申请号：US14714170
申请日：2015-05-15
Applicant: Alger Alternative Energy, LLC
Inventor： Stephen Harrison
IPC: C01D15/08 , C01D9/04 , C01B9/02 , C01D7/07 , C22B26/12 , C01D15/02 , C25C1/02 , C25C7/04 , C25B1/14
CPC classification number: C01D15/08 , C01B9/02 , C01D7/07 , C01D9/04 , C01D15/02 , C01P2006/80 , C22B26/12 , C25B1/14 , C25C1/02 , C25C7/04
Abstract: This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.
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公开(公告)号：US09561476B2
公开(公告)日：2017-02-07
申请号：US13672975
申请日：2012-11-09
Applicant: Jonathan A. Lane , Jamie R. Wilson , Gervase Maxwell Christie , Nathalie Petigny , Christos Sarantopoulos
Inventor： Jonathan A. Lane , Jamie R. Wilson , Gervase Maxwell Christie , Nathalie Petigny , Christos Sarantopoulos
IPC: H01M8/10 , C25B13/04 , C25C7/04 , B01D53/22 , H01M8/12 , B01D71/02 , B01D69/12 , C01B13/02 , B01J23/00 , B01J29/10 , B01J23/86 , B01J35/00 , B01J35/02 , B01J35/06 , B01J35/10 , B01J37/02 , H01M4/86 , H01M4/88 , H01M4/90
CPC classification number: B01D71/024 , B01D53/228 , B01D69/12 , B01D2325/021 , B01D2325/10 , B01J23/002 , B01J23/10 , B01J23/862 , B01J29/10 , B01J35/002 , B01J35/023 , B01J35/065 , B01J35/109 , B01J37/0201 , B01J37/0213 , B01J2523/00 , C01B13/0255 , C01B2210/0046 , H01M4/8621 , H01M4/885 , H01M4/9033 , H01M8/1246 , Y02E60/521 , Y02E60/525 , Y02P70/56 , B01J2523/24 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/375 , B01J2523/48 , B01J2523/55 , B01J2523/67 , B01J2523/842 , B01J2523/35 , B01J2523/72
Abstract: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
Abstract translation: 一种复合氧传输膜，其具有致密层，多孔载体层和位于致密层和多孔载体层之间的中间多孔层。 致密层和中间多孔层都由离子导电材料形成以导电氧离子和导电材料以导电。 由于使用PMMA孔隙形成材料或多孔载体层材料的双峰粒度分布，多孔载体层具有高渗透性，高孔隙率和显微组织显示出基本均匀的孔径分布。 被选择用于促进可燃物质的氧化的催化剂颗粒位于中间多孔层和邻近中间多孔层的多孔载体中。 可以通过将催化剂前体的溶液通过多孔载体向中间多孔层芯吸而形成催化剂颗粒。
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Patent Agency Ranking
66.发明授权公开(公告)号：US09498765B2
公开(公告)日：2016-11-22
申请号：US13508542
申请日：2010-11-05
Applicant: Adélio Miguel Magalhães Mendes
Inventor： Adélio Miguel Magalhães Mendes
IPC: C25B9/00 , C25B9/10 , C25B9/08 , C25B9/16 , C25D17/00 , C25D17/10 , C25C7/04 , C25C7/02 , B01J19/24 , C07C209/02 , H01M4/90 , H01M4/92 , H01M4/94 , H01M8/06 , H01M8/08 , H01M8/00 , H01M8/10 , H01M8/12
CPC classification number: B01J19/2475 , C07C209/02 , H01M4/9016 , H01M4/921 , H01M4/94 , H01M8/004 , H01M8/0681 , H01M8/086 , H01M8/103 , H01M2008/1293 , H01M2250/00 , Y02E60/50 , Y02E60/525 , Y02P70/56 , C07C211/46
Abstract: The disclosed subject matter includes a new type of chemical reactor, described as hydrogen or oxygen electrochemical pumping catalytic membrane reactor. This new type of reactor is suitable for increasing the selectivity and the conversion rate of dehydrogenation, hydrogenation, deoxidation and oxidation reactions and namely in the direct amination reaction of hydrocarbons. This reactor can be used for the production of several chemical compounds, such as the direct amination of hydrocarbons and in particular for the synthesis of aniline from benzene. The disclosed subject matter includes a device and process wherein hydrogen is removed by electrochemical pumping of the hydrogen formed or by oxygen pumping so, as hydrogen is formed, it is oxidized. This new reactor exhibits benzene to aniline conversion higher than 40%.
Abstract translation: 所公开的主题包括一种新型的化学反应器，描述为氢或氧电化学泵送催化膜反应器。 这种新型反应器适用于提高脱氢，氢化，脱氧和氧化反应的选择性和转化率，也适用于碳氢化合物的直接胺化反应。 该反应器可用于生产几种化合物，例如烃的直接胺化，特别是用于从苯合成苯胺。 所公开的主题包括一种装置和方法，其中通过电化学泵浦所形成的氢气或通过氧气泵送除去氢气，因此，当形成氢气时，其被氧化。 这种新型反应器显示苯对苯胺转化率高于40％。
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67.发明授权Electrochemical cell used in production of hydrogen using Cu—Cl thermochemical cycle 有权使用Cu-Cl热化学循环生产氢气的电化学电池公开(公告)号：US09447512B2
公开(公告)日：2016-09-20
申请号：US14131395
申请日：2012-07-09
Applicant: Ganapati Dadasaheb Yadav , Prakash Santoshrao Parhad , Ashwini Bhagavan Nirukhe , Parvatalu Damaraju , Anil Bhardwaj , Bantwal Narayana Prabhu , Nuzhath Joeman Thomas , Dilip Madhusudan Kale
Inventor： Ganapati Dadasaheb Yadav , Prakash Santoshrao Parhad , Ashwini Bhagavan Nirukhe , Parvatalu Damaraju , Anil Bhardwaj , Bantwal Narayana Prabhu , Nuzhath Joeman Thomas , Dilip Madhusudan Kale
Abstract: The electrochemical cell consists of hollow tube and centralized copper rod. The tubes have first and second ends. The first end cap is used to close the first open end. The anolyte inlet is extended through the first end cap in anolyte compartment and catholyte inlet is extended through the first end cap in catholyte compartment. The anolyte and catholyte compartments are separated by ion exchange membrane fixed over inner hollow tube having holes on the surface. A first Teflon gasket has provision for inlet of anolyte and catholyte tube is secured between first tubes end and first end cap. The copper rod is placed at the center of the tubes acts as cathode. The circular ring works as scrapper to take out deposited copper is provided. A second end cap is used to close the second open. A second Teflon gasket is secured between second tubes end and second end cap. The second end cap has provision for anolyte outlet and comprises a conical dome to collect the deposited copper and transport it along with catholyte. The anolyte trappers and catholyte trappers are connected through the tubes to anolyte and catholyte half cells. The anolyte and catholyte are re-circulated through peristaltic pumps, one on each side.
Abstract translation: 电化学电池由中空管和集中铜棒组成。 管具有第一和第二端。 第一个端盖用于关闭第一个开口端。 阳极电解液入口通过阳极电解液室中的第一端盖延伸，阴极电解液入口通过阴极电解液隔室中的第一端盖延伸。 阳极电解液和阴极电解质隔室被固定在表面上具有孔的内部中空管上的离子交换膜分离。 第一个特氟龙垫圈具有阳极电解液入口和阴极电解液管固定在第一管端和第一端盖之间。 铜棒放置在管的中心作为阴极。 提供圆环作为刮板取出沉积铜。 第二个端盖用于关闭第二个开口。 第二个特氟隆垫圈固定在第二管端和第二端盖之间。 第二端帽具有用于阳极电解液出口的装置，并且包括锥形圆顶以收集沉积的铜并与阴极电解液一起运输。 阳极电解液捕集器和阴极电解液捕集器通过管连接到阳极电解液和阴极电解液半电池。 阳极电解液和阴极电解液通过蠕动泵重新循环，每侧一个。
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公开(公告)号：US20160251763A1
公开(公告)日：2016-09-01
申请号：US15032701
申请日：2014-12-03
Applicant: INDUSTRIE DE NORA S.P.A.
Inventor： Mariachiara BENEDETTO
IPC: C25B9/06 , C25B9/04 , C25B11/02 , C02F1/461 , C25B11/04 , C25C1/00 , C25C7/02 , C25C7/04 , C25B1/26 , C25B11/12
CPC classification number: C25B9/066 , C02F1/46104 , C02F1/46109 , C02F1/4674 , C02F2001/46128 , C02F2001/46133 , C02F2001/46142 , C02F2001/46147 , C02F2001/46152 , C02F2001/46171 , C02F2101/30 , C02F2201/4613 , C02F2201/4615 , C02F2201/4616 , C25B1/26 , C25B1/46 , C25B9/04 , C25B9/203 , C25B11/02 , C25B11/0405 , C25B11/0415 , C25B11/0447 , C25B11/0473 , C25B11/12 , C25C1/00 , C25C7/00 , C25C7/02 , C25C7/04
Abstract: A bipolar electrolytic cell particularly useful for electrochemical processes carried out with periodic reversal of polarity is provided. The cell is equipped with a series of concentric electrode pairs, the innermost pair and the outermost pair being connected to the poles of a DC generator and the intermediate pairs acting as bipolar electrodes. The different pairs of electrodes are arranged and connected in such a way that, at each stage of the process, the overall cathodic area is equal to the anodic area.
Abstract translation: 提供特别适用于周期性反转反应进行的电化学过程的双极电解池。 该电池配备有一系列同心电极对，最内侧对和最外面的一对连接到直流发电机的极点，中间对作为双极电极。 不同的电极对被布置和连接，使得在整个过程的每个阶段，整个阴极区域等于阳极区域。
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公开(公告)号：US08323463B2
公开(公告)日：2012-12-04
申请号：US12968699
申请日：2010-12-15
Applicant: Gervase Maxwell Christie , Jamie Robyn Wilson , Bart Antonie van Hassel
CPC classification number: B01D71/024 , B01D53/228 , B01D69/12 , B01D2325/021 , B01D2325/10 , C01B13/0255 , C01B2210/0046
Abstract: A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
Abstract translation: 一种复合氧传输膜，其具有致密层，多孔载体层和位于致密层和多孔载体层之间的中间多孔层。 致密层和中间多孔层都由离子导电材料形成以导电氧离子和导电材料以导电。 多孔支撑层具有高渗透性，高孔隙率和高平均孔径，并且中间多孔层具有比多孔载体层更低的渗透性和更低的孔直径。 被选择用于促进可燃物质的氧化的催化剂颗粒位于中间多孔层和邻近中间多孔层的多孔载体中。 可以通过将催化剂前体的溶液通过多孔载体向中间多孔层芯吸而形成催化剂颗粒。
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70.发明授权公开(公告)号：US08268140B2
公开(公告)日：2012-09-18
申请号：US12793177
申请日：2010-06-03
Applicant: Giovanni Meneghini
Inventor： Giovanni Meneghini
CPC classification number: C25B1/46 , C25B13/04 , C25B13/08 , H01M8/0289 , H01M2300/0014 , Y02P70/56
Abstract: The invention relates to a synthetic diaphragm for chlor-alkali cells with improved energy consumption and gas separation characteristics. The diaphragm comprises a network of polymer fibers bound to a hydrophilic ceramic material containing zirconium chemically bound to hydroxyl groups. The ceramic material is obtained starting from ZrO2 by a process of hydration under vacuum which can be carried out directly in the cell by means of suitable equipment.
Abstract translation: 本发明涉及一种具有改善能耗和气体分离特性的氯碱电池合成隔膜。 隔膜包括与包含与羟基化学键合的锆的亲水性陶瓷材料结合的聚合物纤维网。 通过真空下水合的方法从ZrO 2开始获得陶瓷材料，其可以通过合适的设备直接在电池中进行。
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