摘要:
A polymeric composite of an organic polymer and an inorganic glassy polymer and a process for making such composites which are useful as protective coatings and as nonlinear optical elements.
摘要:
A graft copolymer, comprising a trunk polymer comprising a vinyl chloride/vinyl alcohol copolymer containing vinyl chloride and vinyl alcohol as the essential constituent monomer units, and a branch polymer comprising an organopolysiloxane grafted onto said trunk polymer, and a coating composition comprising said graft copolymer as the main component. The coating formed from the composition is excellent in slippage, water repellency and mold release properties in addition to good characteristics derived from the vinyl chloride/vinyl alcohol resin.
摘要:
In preparing bioabsorbable polyesters containing glycolic acid unit and/or lactic acid unit by the polymerization of glycolide and/or lactide, compositions comprising polyester-silicone copolymers obtained by conducting polymerization in the presence of silicones and the effect of merely mixing the above bioabsorbable polyesters with certain kind of silicones upon the modification, thereby attaining flexibility in particular, of the bioabsorbable polyesters, are disclosed.
摘要:
A preparation process of block copolymers which comprises conducting living polymerization of a (meth)acrylic ester substantially in the absence of water, by using a macromolecular compound having a functional end group represented by the formula (1): ##STR1## Wherein R is H or an n-alkyl group having from 1 to 3 carbon atoms and R' is H or an alkyl group having from 1 to 6 carbon atoms, as a polymerization initiator and in the presence of a Lewis acid or in the presence of a donor compound of an anion selected from HF.sub.2.sup.-, (CH.sub.3).sub.3 SiF.sub.2.sup.- or F.sup.-, as well as novel block copolymers prepared therefrom are disclosed.
摘要:
A two-step process for the preparation of a silicone resin-modified phenolic resin is disclosed wherein an alkoxysilane-modified phenolic resin is first prepared by reacting an alkoxysilane with a phenolic resin. In a subsequent step, the alkoxysilane-modified phenolic resin is hydrolyzed and condensed by heating and stirring it with water. The resulting silicone resin-modified phenolic resin, which is free of diorganopolysiloxane units, has excellent heat resistance and excellent electrical insulating properties.
摘要:
The invention discloses novel fluorine containing silanol polyester waxes. Compounds of the invention by virtue of (a) the polyester group, and (b) the fluorine containing terminal groups are extremely efficient lubricating materials when applied to a variety of surfaces. These materials spread out when applied and provide durable lubrication and hydrophobicity when applied to hair, skin, wood, plastic and textile fibers. The compounds of the present invention are prepared by reacting a silanol compound with a dicarboxylic acid and a fluorine containing alcohol.
摘要:
Hydrophilic polyester resin is provided by the method comprising reacting an aromatic dicarboxylic acid or diester thereof, a diol and a polysiloxane-polyether copolymer wherein the polysiloxane backbone is endblocked with a hydroxyl-substituted organic group and the polyether portion of the copolymer comprises polyoxyethylene. The resulting silicone-modified polyester is especially suited for making hydrophilic fiber and film.
摘要:
The new polyester carbonate-polysiloxane block copolymers having recurrent structural units of the following formulae ##STR1## have improved resistance to petrol compared with known polyester carbonate-polysiloxane block copolymers. They are used for the manufacture of moulded products, in particular those used under the engine bonnet of a motor vehicle or as external parts of motor vehicles.
摘要:
Novel low melt viscosity imido prepolymers, well adapted for the production of prepregs and filament wound shaped articles, are prepared by copolymerizing (a) at least one N,N'-bismaleimide with (b) at least one siloxane bismaleimide, (c) at least one aromatic diprimary diamine, (d) optionally, at least one olefinically unsaturated comonomer other than a bisimide, (e) optionally, a catalyst, and (f) either an acrylate or an unhalogenated epoxy resin.
摘要:
Disclosed herein is an epoxy resin composition for sealing a semiconductor, which contains a flexibilizer, epoxy resin, a hardener, a hardening accelerator, a filler, a mold releasing agent, a colorant and a finishing agent. The flexibilizer is prepared from silicone containing hydroxyphenyl groups on ends of and/or in its molecules, which is formed of a copolymer of denatured silicone oil A having hydroxyphenyl groups, denatured silicone oil B having epoxy groups and/or bifunctional epoxy resin having epoxy groups on both ends.In addition to heat resistance, moisture resistance, a low elastic modulus, a low thermal expansion coefficient and a high glass-transition temperature, the epoxy resin composition according to the present invention has toughness which is higher than that of a conventional one, due to fine dispersion of silicone.