摘要:
A method for the prevention of fouling of metallic surfaces exposed to reactive alpha-olefin gases during the production of polymeric resins which comprise coating such metallic surfaces with an amino silicone fluid and thereafter curing said coating by hydrolysis to form a continuous solid coating.
摘要:
A stable polymer polyol made by the in situ polymerization of two or more monomers in a polyol blend wherein at least one monomer is a bifunctional compound containing both an isocyanate group and an ethylinically unsaturated group and wherein the polyol blend contains a base polyol and an amine terminated polyether which is more reactive with the bifunctional compound than is the base polyol.
摘要:
A catalyst composition comprising:(i) a complex comprised of V.sub.2 X.sub.3 (ED).sub.m and AlCl.sub.2 R.sub.2 whereinX=Cl, Br, or I, or mixtures thereofED=an electron donor, which is an ether, a phosphine, a ketone, an isocyanide, or an ester, said electron donor having 2 to 20 carbon atomsR=an alkyl having up to 14 carbon atomsm=an integer from 3 to 6,said complex impregnated into an inorganic oxide support;(ii) sufficient trialkylaluminum compound adsorbed on the inorganic oxide support to provide a molar ratio of adsorbed trialkylaluminum compound to vanadium of about 2.5:1 to about 10:1;(iii) a halocarbon promoter; and(iv) a hydrocarbyl aluminum cocatalyst.
摘要:
Catalyst composition for the production of methanol and higher saturated aliphatic alcohols from synthesis gas. The catalysts consist essentially of:(i) about 0.18 to about 0.81 mol fraction of copper;(ii) about 0.045 to about 0.54 mol fraction of thorium;(iii) up to about 0.54 mol fraction of zirconium; and(iv) about 0.01 to about 0.2 mol fraction of an alkali metal.
摘要:
A method for recovering a transition metal, e.g., rhodium, from a non-polar organic solution containing non-polar organic solvent-soluble and polar solvent-insoluble coordination complex of the transition metal and a non-polar organic solvent-soluble and polar solvent-insoluble ligand, e.g., an organophosphorus ligand, by contacting the non-polar organic solution with a polar solution of an ionic organophosphine ligand, the transition metal then can be transferred back into a non-polar solution for reuse. In one embodiment rhodium is rendered amenable for back-extraction by treating the polar solution with a suitable conditioning reagent.
摘要:
A sapphire orthodontic bracket with enhanced tolerance to fabrication, installation and use is fabricated such that the "r" planes of the sapphire are at substantially equal angles to the longitudinal axis of the arch wire groove of the bracket.
摘要:
Polycrystalline silicon rod capable of providing within no more than two floating zoning passes, unicrystalline silicon exhibiting a resistivity of at least 10,000 ohm-cm (donor) and a lifetime of at least about 10,000 milliseconds, exhibits a copper X-ray diffraction pattern having a peak at 26.85.degree..+-.0.25.degree. (2 theta) and has less than 15 ppta boron and less than 20 ppta phosphorus.
摘要:
Described herein are compositions suitable for photocopolymerization comprising a cyclic vinyl ether containing compound and urethane acrylates. Photocurable coatings can be prepared from such composition and such coatings have markedly improved flexibility and impact resistant properties.
摘要:
This invention relates to a method for on-line decoking of flame-cracking reactors whereby decoking is achieved without interruption of the normal operation of such reactors and without the necessity to change feed equipment and/or disassemble reactor components. While maintaining the temperature of the effluent at 1000.degree. C. to 2000.degree. C., the flow of the hydrocarbon feedstock in the reactor is periodically stopped for a time sufficient to reduce the carbon deposits to an acceptable level.
摘要:
A process and reaction vessel for producing alkyl nitrite is disclosed the process comprising (a) contacting nitric oxide, lower alcohol and oxygen in a reaction zone such that alkyl nitrite is formed, said reaction zone comprising a reactor section and a rectification section, (b) supplying a liquid scrubbing agent to an upper portion of the rectification section, (c) withdrawing a gaseous alkyl nitrite product stream from the upper portion of the rectification section, and (d) withdrawing a liquid stream from a lower portion of the reactor section. The reactor section provides intimate vapor-liquid contact sufficient to enhance the conversion of nitric oxide to alkyl nitrite and the rectification section provides sufficient vapor residence time to enhance conversion of oxygen, as well as sufficient rectification capabilities to reduce the amounts of water and nitric acid in the gaseous alkyl nitrite product stream.