POLYESTER POLYOLS MADE OF ISOPHTHALIC ACID AND/OR TEREPHTHALIC ACID AND OLIGOALKYL OXIDES
    73.
    发明申请
    POLYESTER POLYOLS MADE OF ISOPHTHALIC ACID AND/OR TEREPHTHALIC ACID AND OLIGOALKYL OXIDES 有权
    异辛酸和/或正十二酸和低聚乙烯氧化物的聚酯多元醇

    公开(公告)号:US20120123009A1

    公开(公告)日:2012-05-17

    申请号:US13322989

    申请日:2010-05-18

    IPC分类号: C08L75/06 C08J9/00 C07C69/82

    摘要: The present invention relates to a method for producing a polyester polyol having a concentration of ether groups in the range from 9.0 mol/kg of polyester polyol to 22 mol/kg polyester polyol, characterized in that (i) in a first step (A) isophthalic acid, optionally in the form of a C1-C4 alkyl ester, and/or terephthalic acid, optionally in the form of a C1-C4 alkyl ester, is reacted with (B) oligoethylene glycol of the formula H—(OCH2CH2)n—OH having a numerical average number of oxyethylene groups n in the range from 3.0 to 9.0, in the presence of at least one catalyst selected from the group made up of tin(II) salts, bismuth(II) salts, and titanium tetraalkoxylates, at a temperature in the range from 160° C. to 240° C., and at a pressure in the range from 1 to 1013 mbar, for a duration in the range from 7 to 100 hours, and (ii) in a second step the reaction mixture resulting from step (i) is reacted with (C) phthalic acid and/or phthalic acid hydride, the polyester polyols obtained according to said method, and to the use thereof for producing PUR/PIR hard foam materials

    摘要翻译: 本发明涉及一种聚酯多元醇的制造方法,所述聚酯多元醇的浓度为9.0摩尔/千克聚酯多元醇至22摩尔/千克聚酯多元醇,其特征在于,(i)在第一步骤(A) 任选呈C1-C4烷基酯形式的间苯二甲酸和/或对苯二甲酸,任选呈C1-C4烷基酯形式,与式(B)的低聚乙二醇(H 2 OCH 2 CH 2)n -OH在数均平均数为3.0至9.0的范围内,在至少一种选自锡(II)盐,铋(II)盐和四烷氧基钛酸盐的催化剂存在下, 在160℃至240℃的温度范围内和在1至1013毫巴的压力下持续7至100小时的持续时间,和(ii)在第二步骤中 由步骤(i)得到的反应混合物与(C)邻苯二甲酸和/或邻苯二甲酸氢化物反应,聚酯多元醇 根据所述方法染色,以及其用于生产PUR / PIR硬泡沫材料的用途

    THERMOPLASTICALLY PROCESSABLE POLYURETHANES BASED ON SUCCINIC ACID PROPIONATES
    75.
    发明申请
    THERMOPLASTICALLY PROCESSABLE POLYURETHANES BASED ON SUCCINIC ACID PROPIONATES 审中-公开
    基于酸性丙酸酯的热塑性加工性聚氨酯

    公开(公告)号:US20110306734A1

    公开(公告)日:2011-12-15

    申请号:US13116099

    申请日:2011-05-26

    IPC分类号: C08G18/66 C08G18/76 C08G18/75

    摘要: The present invention relates to a thermoplastically processable polyurethane elastomer having a hardness of 50 Shore A to 70 Shore D (ISO 868), which are obtained from reacting components comprising a) one or more linear polyester diols having a functionality from 1.8 to 2.2, wherein the one or more linear polyester diols comprise succinic acid 1,3-propionate and have an average molecular weight from 1,950 to 4,000 g/mol. b) one or more organic diisocyanates, and c) one or more diols having a molecular weight from 60 to 350 g/mol, wherein the components have a molar NCO:OH ratio of from 0.9:1 to 1.1:1.

    摘要翻译: 本发明涉及硬度为50肖氏A至70肖氏D(ISO 868)的热塑性加工性聚氨酯弹性体,其由包含a)一种或多种官能度为1.8至2.2的线性聚酯二醇的反应组分获得,其中 一种或多种线性聚酯二醇包括1,3-丙酸琥珀酸酯,其平均分子量为1,950至4,000g / mol。 b)一种或多种有机二异氰酸酯,和c)分子量为60至350g / mol的一种或多种二醇,其中组分的NCO:HOH摩尔比为0.9:1至1.1:1。