MORPHOLINE-SUBSTITUTED POLY(ARYLENE ETHER) AND METHOD FOR THE PREPARATION THEREOF

    公开(公告)号:US20110275766A1

    公开(公告)日:2011-11-10

    申请号:US13083696

    申请日:2011-04-11

    IPC分类号: C08G65/46 C08G65/38

    CPC分类号: C08G65/46

    摘要: A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

    Poly(arylene ether)-polysiloxane composition and method
    74.
    发明授权
    Poly(arylene ether)-polysiloxane composition and method 有权
    聚(亚芳基醚) - 聚硅氧烷组合物和方法

    公开(公告)号:US08017697B2

    公开(公告)日:2011-09-13

    申请号:US12277835

    申请日:2008-11-25

    IPC分类号: C08G65/48

    摘要: A thermoplastic composition includes a poly(arylene ether) and a poly(arylene ether)-polysiloxane block copolymer. The thermoplastic composition is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The method is simpler than prior methods of preparing poly(arylene ether)-polysiloxane block copolymers by linking pre-formed poly(arylene ether) and polysiloxane blocks. The method is also produces greater incorporation of polysiloxane into the poly(arylene ether)-polysiloxane block copolymer than prior methods of copolymerizing monohydric phenols and hydroxyaryl-terminated polysiloxane.

    摘要翻译: 热塑性组合物包括聚(亚芳基醚)和聚(亚芳基醚) - 聚硅氧烷嵌段共聚物。 热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 该方法比通过连接预形成的聚(亚芳基醚)和聚硅氧烷嵌段制备聚(亚芳基醚) - 聚硅氧烷嵌段共聚物的现有方法更简单。 与先前的一元酚和羟基芳基封端的聚硅氧烷的共聚方法相比,该方法还可以使聚硅氧烷更好地引入聚(亚芳基醚) - 聚硅氧烷嵌段共聚物中。

    Composite-forming method, composites formed thereby, and printed circuit boards incorporating them
    75.
    发明授权
    Composite-forming method, composites formed thereby, and printed circuit boards incorporating them 有权
    复合成型方法,由此形成的复合材料,以及包含它们的印刷电路板

    公开(公告)号:US07655278B2

    公开(公告)日:2010-02-02

    申请号:US11670813

    申请日:2007-02-02

    IPC分类号: B05D5/00

    摘要: A composite-forming process includes impregnating a reinforcing structure with a curable composition at a temperature of about 10 to about 40° C. The curable composition includes specific amounts of an epoxy resin, a poly(arylene ether), a solvent, and a curing promoter. The poly(arylene ether) includes, on average, about 1.6 to about 2.4 phenolic hydroxy groups per molecule, and it has a polydispersity index less than or equal to 2.2 and an intrinsic viscosity of about 0.03 to about 0.2 deciliter per gram. These characteristics substantially improve the solubility of the poly(arylene ether) in the curable composition and allow the curable composition to be formed and used at or near room temperature. Composites formed by the process and circuit boards including the composites are also described.

    摘要翻译: 复合成型方法包括在约10至约40℃的温度下用可固化组合物浸渍增强结构。可固化组合物包括特定量的环氧树脂,聚(亚芳基醚),溶剂和固化 启动子。 聚(亚芳基醚)每分子平均包含约1.6至约2.4个酚羟基,并且其分子量指数小于或等于2.2,特性粘度为约0.03至约0.2分升每克。 这些特征大大提高了聚(亚芳基醚)在可固化组合物中的溶解度,并使得可固化组合物在室温或室温附近形成和使用。 还描述了由包括复合材料的工艺和电路板形成的复合材料。

    POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD
    76.
    发明申请
    POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD 有权
    聚(亚乙基醚) - 聚硅氧烷组合物和方法

    公开(公告)号:US20090318635A1

    公开(公告)日:2009-12-24

    申请号:US12277835

    申请日:2008-11-25

    IPC分类号: C08L83/12

    摘要: A thermoplastic composition includes a poly(arylene ether) and a poly(arylene ether)-polysiloxane block copolymer. The thermoplastic composition is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The method is simpler than prior methods of preparing poly(arylene ether)-polysiloxane block copolymers by linking pre-formed poly(arylene ether) and polysiloxane blocks. The method is also produces greater incorporation of polysiloxane into the poly(arylene ether)-polysiloxane block copolymer than prior methods of copolymerizing monohydric phenols and hydroxyaryl-terminated polysiloxane.

    摘要翻译: 热塑性组合物包括聚(亚芳基醚)和聚(亚芳基醚) - 聚硅氧烷嵌段共聚物。 热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 该方法比通过连接预形成的聚(亚芳基醚)和聚硅氧烷嵌段制备聚(亚芳基醚) - 聚硅氧烷嵌段共聚物的现有方法更简单。 与先前的一元酚和羟基芳基封端的聚硅氧烷的共聚方法相比,该方法还可以使聚硅氧烷更好地引入聚(亚芳基醚) - 聚硅氧烷嵌段共聚物中。

    POLY(ARYLENE ETHER) COPOLYMER
    78.
    发明申请
    POLY(ARYLENE ETHER) COPOLYMER 有权
    POLY(ARYLENE ETHER)COPOLYMER

    公开(公告)号:US20090247724A1

    公开(公告)日:2009-10-01

    申请号:US12414856

    申请日:2009-03-31

    IPC分类号: C08G65/44 C08G65/38

    CPC分类号: C08G65/44 H05K1/0326

    摘要: A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol. It has an intrinsic viscosity of about 0.04 to about 0.15 deciliter per gram and, on average, about 1.8 to about 2 hydroxyl groups per molecule. The poly(arylene ether) copolymer is enriched in low molecular weight copolymer chains and copolymer chains that include a terminal unit derived from the dihydric phenol.

    摘要翻译: 聚(亚芳基醚)共聚物是包括一元酚和二元酚的单体的氧化共聚的产物。 其特性粘度为约0.04至约0.15分升每克,平均每分子约1.8至约2个羟基。 聚(亚芳基醚)共聚物富含低分子量共聚物链和共聚物链,其包括源自二元酚的末端单元。

    Poly(arylene ether) preparation method
    79.
    发明授权
    Poly(arylene ether) preparation method 有权
    聚(亚芳基醚)的制备方法

    公开(公告)号:US07595367B2

    公开(公告)日:2009-09-29

    申请号:US11845823

    申请日:2007-08-28

    IPC分类号: C08F283/08

    摘要: Capped poly(arylene ether)s are prepared by a method that includes reacting a poly(arylene ether) with a capping agent to form a capping reaction mixture, washing the capping reaction mixture with a concentrated basic aqueous solution, and isolating the capped poly(arylene ether) by a total isolation method. The washing method is effective for removal of capping-related impurities, and surprisingly does not result in decomposition of the capped poly(arylene ether).

    摘要翻译: 通过包括使聚(亚芳基醚)与封端剂反应形成封端反应混合物,用浓缩的碱性水溶液洗涤封端反应混合物并分离封端的聚(亚芳基醚)的聚(亚芳基醚) 亚芳基醚)。 洗涤方法对于除去封盖相关杂质是有效的,并且令人惊讶地不会导致封端的聚(亚芳基醚)的分解。