公开(公告)号：US06322606B1

公开(公告)日：2001-11-27

申请号：US09665123

申请日：2000-09-20

申请人： Haruhiko Komoriya ,  Kazuhiko Maeda ,  Masayuki Shiota ,  Yoshi Hirashima ,  Kentaro Tsutsumi ,  Mikio Ootani ,  Yukio Ikeda

发明人： Haruhiko Komoriya ,  Kazuhiko Maeda ,  Masayuki Shiota ,  Yoshi Hirashima ,  Kentaro Tsutsumi ,  Mikio Ootani ,  Yukio Ikeda

IPC分类号： C05G500

CPC分类号： C08G18/36 ,  C05G3/0029 ,  C08G18/5021 ,  C08G18/8051

摘要： The invention relates to a coated granular fertilizer having a film covering fertilizer granules. This film comprises a polyurethane resin prepared by a method comprising the steps of (a) reacting an aromatic polyisocyanate with a first polyol component (i.e., castor oil or a castor oil derivative), thereby to obtain a prepolymer having terminal isocyanate groups in the molecule; and (b) reacting the prepolymer with a second polyol component (i.e., castor oil or a castor oil derivative) and a third polyol component which is an amine having at least two hydroxyl groups in the molecule, thereby to cure the prepolymer and thus to prepare the polyurethane resin. The invention relates to another coated granular fertilizer having a film covering fertilizer granules. This film comprises a urethane resin and aqueous-fluid-absorbing particles having a particle diameter of from 1 to 200 &mgr;m. This urethane resin may be the above polyurethane resin. This coated granular fertilizer can be produced by a method comprising the steps of (a) applying an aromatic polyisocyanate, a polyol component (i.e., castor oil or a castor oil derivative), an amine, and the aqueous-fluid-absorbing particles, at the same time or separately in no special order, while the fertilizer granules are kept fluidized or rolled, thereby to form a precursory film on the fertilizer granules; and (b) curing the precursory film into the film. Each coated granular fertilizer is substantially superior in regulation of the release of plant nutrient elements therefrom.

摘要翻译： 本发明涉及具有覆盖肥料颗粒的薄膜的涂覆颗粒肥料。 该膜包括通过包括以下步骤的方法制备的聚氨酯树脂：（a）使芳族多异氰酸酯与第一多元醇组分（即蓖麻油或蓖麻油衍生物）反应，由此得到分子中具有末端异氰酸酯基团的预聚物 ; 和（b）使预聚物与第二多元醇组分（即蓖麻油或蓖麻油衍生物）和第三多元醇组分反应，所述第三多元醇组分是分子中具有至少两个羟基的胺，从而固化预聚物，从而使 制备聚氨酯树脂。 本发明涉及具有覆盖肥料颗粒的膜的另一种涂覆颗粒肥料。 该膜包含聚氨酯树脂和粒径为1〜200μm的水溶液吸收性粒子。 该聚氨酯树脂可以是上述聚氨酯树脂。 该涂覆的颗粒肥料可以通过以下方法制备：（a）将芳族多异氰酸酯，多元醇组分（即蓖麻油或蓖麻油衍生物），胺和水性流体吸收颗粒施用于 同时或以特殊顺序分开，同时将肥料颗粒保持流化或滚动，从而在肥料颗粒上形成前体膜; 和（b）将前体膜固化成膜。 每个涂覆的颗粒肥料在调节植物营养元素的释放方面基本上都是优异的。

公开(公告)号：US6166141A

公开(公告)日：2000-12-26

申请号：US873231

申请日：1997-06-11

申请人： Kazuhiko Maeda ,  Yukio Ikeda ,  Kentaro Tsutsumi ,  Seiji Hasegawa

发明人： Kazuhiko Maeda ,  Yukio Ikeda ,  Kentaro Tsutsumi ,  Seiji Hasegawa

IPC分类号： C08F259/08 ,  C08L51/00 ,  C09D127/16 ,  C09D151/00 ,  C08L27/12 ,  C08F214/18

CPC分类号： C09D151/003 ,  C08F259/08 ,  C08L51/003 ,  C09D127/16 ,  C08L2666/24

摘要： The invention relates to a fluorine-containing resin (graft copolymer) used for preparing a paint. This resin is prepared by a graft copolymerization of a fluorine-containing copolymer with a first monomer composition. The fluorine-containing copolymer comprises a first constitutional unit derived from a fluoroolefin and at least one of second and third constitutional units. The second constitutional unit is derived from a particular carboxylic acid vinyl ester represented by a general formula of R--C(.dbd.O)OCH.dbd.CH.sub.2 where R is a special group. The third constitutional unit is derived from a first monomer which is at least one compound selected from vinyl ethers and allyl ethers. The first monomer is represented by a general formula of R--O--(CH.sub.2)n--CH.dbd.CH.sub.2. The first monomer composition for preparing the resin contains a second monomer which is at least one compound selected from methacrylic acid esters and acrylic esters. The second monomer is represented by a general formula of CH.sub.2 .dbd.C(--R')C(.dbd.O)O--R where R' is hydrogen atom or methyl group. A composition prepared by mixing the resin with vinylidene fluoride resin or with a combination of vinylidene fluoride resin and acrylic resin is capable of providing a coated film having high gloss, high weather resistance, and good results in bending test for a long time. Another composition prepared by mixing the resin with a hardener is capable of providing a coated film having high hardness, good adhesion to various other coated films, high weather resistance, and high stain resistance.

摘要翻译： 本发明涉及用于制备涂料的含氟树脂（接枝共聚物）。 该树脂通过含氟共聚物与第一单体组合物的接枝共聚而制备。 含氟共聚物包含衍生自氟代烯烃的第一结构单元和第二和第三结构单元中的至少一个。 第二结构单元衍生自由通式R-C（= O）OCH = CH 2表示的特定羧酸乙烯基酯，其中R是特殊基团。 第三结构单元衍生自作为至少一种选自乙烯基醚和烯丙基醚的化合物的第一单体。 第一单体由通式R-O-（CH 2）n -CH = CH 2表示。 用于制备树脂的第一单体组合物含有作为至少一种选自甲基丙烯酸酯和丙烯酸酯的化合物的第二单体。 第二单体由通式CH 2 = C（-R'）C（= O）O-R表示，其中R'是氢原子或甲基。 通过将树脂与偏氟乙烯树脂或偏二氟乙烯树脂和丙烯酸树脂的组合混合而制备的组合物能够提供长时间具有高光泽，高耐候性和良好的弯曲试验结果的涂膜。 通过将树脂与硬化剂混​​合而制备的另一组合物能够提供具有高硬度，对各种其它涂膜的良好粘附性，高耐候性和高耐污性的涂膜。

公开(公告)号：US5859123A

公开(公告)日：1999-01-12

申请号：US749698

申请日：1996-11-15

申请人： Satoru Kobayashi ,  Kazuhiko Maeda ,  Yoshi Hirashima ,  Seiji Hasegawa ,  Kentaro Tsutsumi

发明人： Satoru Kobayashi ,  Kazuhiko Maeda ,  Yoshi Hirashima ,  Seiji Hasegawa ,  Kentaro Tsutsumi

IPC分类号： C08F214/18 ,  C08F214/24 ,  C08F214/26 ,  C09D143/04 ,  C08L27/12

CPC分类号： C08F214/18 ,  C08F214/245 ,  C08F214/265 ,  C09D143/04 ,  C08L2201/52

摘要： The present invention relates to a water-based fluorine-containing emulsion. This emulsion contains a fluorine-containing copolymer in a disperse phase thereof This copolymer is prepared by copolymerizing: (A) a fluoroolefin, (B) an organosilicon compound containing an olefinic unsaturated bond and an alkoxysilyl group, (C) an unsaturated carboxylic acid represented by a general formula of CH.sub.2 .dbd.CH--(CH.sub.2).sub.n --COOH where n is an integer of from 3 to 15, and (D) at least one other copolymerizable monomer. A paint prepared from the emulsion is superior in storage stability and mechanical stability, although this paint belongs to a one-package paint. A coated film formed by applying the paint is superior in water resistance in its early stages, stain resistance, and weather resistance.

摘要翻译： 本发明涉及水性含氟乳液。 该乳液在分散相中含有含氟共聚物。该共聚物通过共聚以下物质制备：（A）氟烯烃，（B）含有烯属不饱和键的有机硅化合物和烷氧基甲硅烷基，（C）不饱和羧酸 通式为CH 2 = CH-（CH 2）n -COOH，其中n为3至15的整数，和（D）至少一种其它可共聚单体。 由乳液制备的油漆在储存稳定性和机械稳定性方面是优异的，尽管这种油漆属于单组分涂料。 通过涂覆涂料形成的涂膜在其早期的耐水性，耐污染性和耐候性方面都是优异的。

公开(公告)号：US5684074A

公开(公告)日：1997-11-04

申请号：US548062

申请日：1995-10-25

申请人： Yoshi Hirashima ,  Kazuhiko Maeda ,  Kentaro Tsutsumi

发明人： Yoshi Hirashima ,  Kazuhiko Maeda ,  Kentaro Tsutsumi

IPC分类号： C08K5/5415 ,  C08K5/54

CPC分类号： C08K5/5415

摘要： The invention provides a novel coating composition comprising a first component (i.e. 100 parts by weight of a fluorine-containing copolymer), a second component (i.e. 0.1-20 parts by weight of an alkyl silicate), and a third component (i.e. 0.05-3 parts by weight of a water-soluble polyether-modified silicone oil and/or 1-25 parts by weight of a polyoxytetramethylene glycol). The fluorine-containing copolymer has a hydroxyl value of 80-200 mg KOH per 1g thereof and is prepared by copolymerizing 40-65 mol % of a fluoroolefin, 14-50 mo1% of a copolymerizable vinyl-containing compound, 12-25 mol % of a polymerizable hydroxyl-containing compound, and 0.1-12 mol % of at least one other copolymerizable compound. A cured coated film prepared from the coating composition is superior in elasticity and weathering and stain resistances.

摘要翻译： 本发明提供一种新型涂料组合物，其包含第一组分（即100重量份的含氟共聚物），第二组分（即0.1-20重量份的烷基硅酸盐）和第三组分（即0.05- 3重量份水溶性聚醚改性硅油和/或1-25重量份聚氧四亚甲基二醇）。 含氟共聚物的羟值为每1g 1g的80-200mg KOH，通过使40-65mol％的氟烯烃，14-50mol％的可共聚的含乙烯基化合物，12-25mol％ 的可聚合羟基化合物和0.1-12mol％的至少一种其它可共聚的化合物。 由涂料组合物制备的固化涂膜具有优异的弹性和耐候性和耐污染性。

公开(公告)号：US20130260313A1

公开(公告)日：2013-10-03

申请号：US13436881

申请日：2012-03-31

申请人： Robert David Allen ,  Phillip Joe Brock ,  Masaki Fujiwara ,  Kazuhiko Maeda ,  Hoa D. Truong

发明人： Robert David Allen ,  Phillip Joe Brock ,  Masaki Fujiwara ,  Kazuhiko Maeda ,  Hoa D. Truong

IPC分类号： G03F7/20 ,  G03F7/004 ,  C08F228/02

CPC分类号： G03F7/0397 ,  C08F228/02 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/11 ,  G03F7/2041

摘要： A photoacid generating polymer (PAG polymer) comprises i) a first repeat unit of capable of reacting with a photogenerated acid to form a carboxylic acid containing repeat unit, ii) a second repeat unit of capable of forming the photogenerated acid, and iii) a third repeat unit comprising a norbornyl ester, wherein a norbornyl ring of the norbornyl ester comprises a monovalent substituent having the formula *-L′-C(CF3)2(OH). L′ is a divalent linking group comprising at least one carbon and the starred bond of L′ is linked to the norbornyl ring. The first repeat unit, second repeat unit, and the third repeat unit are covalently bound repeat units of the PAG polymer.

摘要翻译： 产生光酸的聚合物（PAG聚合物）包括i）能够与光生酸反应形成含羧酸的重复单元的第一重复单元，ii）能够形成光生酸的第二重复单元，和iii） 包含降冰片基酯的第三重复单元，其中降冰片基酯的降冰片基环包含具有式* -L'-C（CF 3）2（OH）的一价取代基。 L'是包含至少一个碳的二价连接基团，L'的星形键与降冰片基环连接。 第一重复单元，第二重复单元和第三重复单元是PAG聚合物的共价键重复单元。

公开(公告)号：US20120170855A1

公开(公告)日：2012-07-05

申请号：US13496323

申请日：2011-04-14

申请人： Kazuhiko Maeda

发明人： Kazuhiko Maeda

IPC分类号： G06K9/68

CPC分类号： G06F16/583

摘要： An image management device includes an image priority calculation unit calculating image priority, an image selection unit selecting a high-priority image and a low-priority image, a feature correction unit correcting low-priority image features using the object features of objects included in the high-priority image and in the low-priority image, an image similarity calculation unit calculating image similarity using the object features of the high-priority image and the object features corrected by the feature correction unit, and an image priority correction unit correcting the priority of the low-priority image according to the calculated image similarity.

摘要翻译： 图像管理装置包括：图像优先度计算单元，计算图像优先级，选择高优先级图像和低优先级图像的图像选择单元;特征校正单元，使用包含在所述图像优先级中的对象的对象特征来校正低优先级图像特征; 高优先级图像和低优先级图像，图像相似度计算单元使用高优先级图像的对象特征和由特征校正单元校正的对象特征来计算图像相似度，以及图像优先级校正单元，其校正优先级 根据计算出的图像相似度来计算低优先级图像。

公开(公告)号：US20120064459A1

公开(公告)日：2012-03-15

申请号：US13320871

申请日：2010-05-14

申请人： Kazuhiko Maeda ,  Takamasa Kitamoto ,  Haruhiko Komoriya ,  Satoru Narizuka ,  Yoshimi Isono ,  Kazunori Mori

发明人： Kazuhiko Maeda ,  Takamasa Kitamoto ,  Haruhiko Komoriya ,  Satoru Narizuka ,  Yoshimi Isono ,  Kazunori Mori

IPC分类号： G03F7/039 ,  C08F20/22 ,  G03F7/38

CPC分类号： G03F7/20 ,  C08F20/26 ,  G03F7/0046 ,  G03F7/0397 ,  G03F7/2041

摘要： Disclosed is a water repellent additive for an immersion resist, which is composed of a fluorine-containing polymer that has a repeating unit represented by general formula (1). By adding the water repellent additive to a resist composition, the resist composition can be controlled to have high water repellency during exposure and to exhibit improved solubility in a developing solution during development. [In the formula, R1 represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; R2 represents a heat-labile protecting group; R3 represents a fluorine atom or a fluorine-containing alkyl group; and W represents a divalent linking group.]

摘要翻译： 公开了一种浸渍抗蚀剂的防水添加剂，其由具有由通式（1）表示的重复单元的含氟聚合物组成。 通过将防水添加剂添加到抗蚀剂组合物中，可以将抗蚀剂组合物控制为在曝光期间具有高的拒水性，并且在显影期间在显影液中表现出改善的溶解性。 [式中，R 1表示氢原子，氟原子，甲基或三氟甲基。 R2代表热不稳定保护基; R3表示氟原子或含氟烷基; W表示二价连接基。]

公开(公告)号：US20110196121A1

公开(公告)日：2011-08-11

申请号：US13094281

申请日：2011-04-26

申请人： Shinichi SUMIDA ,  Haruhiko Komoriya ,  Kazuhiko Maeda

发明人： Shinichi SUMIDA ,  Haruhiko Komoriya ,  Kazuhiko Maeda

IPC分类号： C08F20/22 ,  C07C69/52 ,  C07C39/10 ,  C07C69/34 ,  C07C69/62 ,  C07C43/20

CPC分类号： C08F20/30 ,  C08F14/18 ,  C08F20/28 ,  C08F216/1408 ,  C08F220/24 ,  C08F220/30 ,  C09D125/16 ,  C09D133/16 ,  Y10S430/108 ,  Y10S430/111 ,  C08F2/00

摘要： A fluorine-containing compound represented by the formula 1, where R1 is a methyl group or trifluoromethyl group, each of R2 and R3 is independently a hydrogen atom or a group containing (a) a hydrocarbon group having a straight-chain, branched or ring form and having a carbon atom number of 1-25 or (b) an aromatic hydrocarbon group, the group optionally containing at least one of a fluorine atom, an oxygen atom and a carbonyl bond, l is an integer of from 0 to 2, each of m and n is independently an integer of 1-5 to satisfy an expression of m+n≦6, and when at least one of R1, R2 and R3 is in a plural number, the at least one of R1, R2 and R3 may be identical with or different from each other.

摘要翻译： 由式1表示的含氟化合物，其中R 1为甲基或三氟甲基，R 2和R 3各自独立地为氢原子或含有（a）具有直链，支链或环的烃基的基团 形成并具有1-25的碳原子数或（b）芳族烃基，所述基团任选地含有氟原子，氧原子和羰基键中的至少一个，l是0-2的整数， m和n各自独立地为1-5的整数，以满足m + n＆nlE; 6的表达式，并且当R 1，R 2和R 3中的至少一个为多个时，R 1，R 2和 R3可以彼此相同或不同。

公开(公告)号：US20100204422A1

公开(公告)日：2010-08-12

申请号：US12765305

申请日：2010-04-22

申请人： Haruhiko Komoriya ,  Shinichi Sumida ,  Michitaka Ootani ,  Takeo Komata ,  Kazuhiko Maeda

发明人： Haruhiko Komoriya ,  Shinichi Sumida ,  Michitaka Ootani ,  Takeo Komata ,  Kazuhiko Maeda

IPC分类号： C08F214/18 ,  C07C49/573 ,  C07C33/44 ,  C07C69/54

CPC分类号： C07C33/44 ,  C07C31/44 ,  C07C49/337 ,  C07C49/573 ,  C07C69/653 ,  C07C2602/42 ,  C08F14/18 ,  C08F2/00

摘要： The present invention relates to, for example, a fluorine-containing cyclic compound represented by the following general formula (1). In the general formula (1), R1a is a C1-C25 cyclic alkyl group, cyclic alkenyl group or cyclic alkynyl group; each of R2 and R3 is independently a hydrogen atom, a halogen atom, or a C1-C25 straight-chain, branched or cyclic alkyl group; and each of R1a, R2 and R3 may contain fluorine atom, oxygen atom, sulfur atom, nitrogen atom or an atomic group containing a carbon-carbon double bond.

摘要翻译： 本发明涉及例如由以下通式（1）表示的含氟环状化合物。 在通式（1）中，R 1a是C 1 -C 25环烷基，环烯基或环炔基; R 2和R 3各自独立地为氢原子，卤素原子或C 1 -C 25直链，支链或环状烷基; R 1a，R 2和R 3可以含有氟原子，氧原子，硫原子，氮原子或含有碳 - 碳双键的原子团。

公开(公告)号：US20090103257A1

公开(公告)日：2009-04-23

申请号：US12250101

申请日：2008-10-13

申请人： Kazuhiko Maeda ,  Hiroaki Agata

发明人： Kazuhiko Maeda ,  Hiroaki Agata

IPC分类号： H05K7/00

CPC分类号： G06F1/1656 ,  G06F1/1616 ,  G06F1/1637 ,  Y10S248/917 ,  Y10S248/918

摘要： A protective casing structure of an electronic apparatus capable of keeping the apparatus compact and light is provided. A display-side block includes a display module and a display casing. The display casing is provided with frame edges at a periphery thereof, with projections formed on the frame edges. Grooves engaging with the projections are formed in a system casing. When the display-side block is closed, the projections engage with the grooves to increase rigidity against pressing from the outside in the closed state. The casing structure thereby increases the protective capability of the display module while keeping the apparatus compact and light.

摘要翻译： 能够保持设备紧凑和轻便的电子设备的保护壳体结构。 显示侧块包括显示模块和显示器壳体。 显示器壳体在其周边设置有框架边缘，突起形成在框架边缘上。 与突起接合的沟槽形成在系统壳体中。 当显示侧块关闭时，突起与凹槽接合以增加在关闭状态下从外部按压的刚性。 因此，外壳结构在保持设备紧凑且轻便的同时增加了显示模块的保护能力。